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Table of Contents
1. Introduction
2. General Kinetic Rules for Chemical Reactions, Collisional, and Intramolecular Processes
2.1. Rates of Reaction, Collisional, and Spontaneous Processes. Rate Constant. Kinetic Types of Simple Processes
2.2. Chemical Equilibrium. Equilibrium Constant
2.3. Arrhenius equation
2.4. Complex Reactions
2.4.1. Consecutive Reactions. Steady-state Method
Problems
References
3. Theory of Elementary Processes
3.1. Cross-sections, Rate Constants, and Probabilities of Elementary processes
3.2. The detailed balance principle. Adiabatic approximations. Potential Energy Curves and Surfaces
3.3. Descriptions of Collisional Processes using Potential Energy Curves and Surfaces. Intramolecular Vibrational Relaxation in Polyatomic Molecules
3.4. Non-adiabatic Transitions. Perturbation theory. Probabilities of Adiabatic and Non-adiabatic Transitions
3.5. Intermolecular Interactions. Types of Intermolecular Interactions
3.6. Semiempirical Model Potentials
Problems
References
4. Photoprocesses
4.1. Primary and Secondary Gas-Phase Photoprocesses. Quantum Yields of the Gas-Phase Photoprocesses
4.2. Optical Transitions. Selection Rules for Optical Transitions. Spin-Orbit Coupling and Spin-Forbidden Radiative Transitions
4.3. Absorption. Absorption Band Intensities. Einstein Transition Probabilities. Oscillator Strength. Transition Dipole Moment. Beer-Lambert Law
4.4. Franck-Condon Principle for Bound-bound and Bound-free Optical Transitions
4.5. Luminescence. Radiative lifetime. The Relationship between Einstein Transition Probabilities and Transition Dipole Moment
4.6. Intramolecular Perturbations. Selection Rules and Franck-Condon Principle for Intramolecular Perturbation. Perturbations between Bound States. Abnormally long Radiative Lifetime
4.7. Spontaneous Predissociation of Two-, Tri- and Polyatomic Molecules. Classes of Predissociation Processes
4.8. Photodecay of Two-, Tri- and Polyatomic Molecules. Long-lived States of Polyatomic Molecules
References
5. Energy Transfer in Collisions
5.1. Translational-Translational Energy Transfer (T-T exchange)
5.2. Rotational-Translational Energy Transfer (R-T exchange)
5.3. Vibrational Energy Transfer (V-T, V-R, T Processes)
5.4. Non-adiabatic Coupling and Vibrational Energy Transfer
5.5. Collision-Induced Non-Adiabatic Transitions
5.6. Collision-Induced Predissociation
5.7. Vibrational Relaxation via Several Electronic States
5.8. Electronic Deactivation
Problems
References
6. Weakly-Bound Complexes
6.1. Hydrogen- and Halogen-Bond Complexes
6.2. Van der Waals Complexes. 6.3. Rare gas-halogen Molecule Clusters
References
7. Termolecular reactions
7.1. Termolecular recombination. Mechanism of Termolecular Recombination
References
8. Chemiluminescence
8.1. Classes of Chemiluminescence Processes. Gas-P Rate Constants
8.2. General Rules of Radiative Recombination
References
Solution of Problems
Index.
2. General Kinetic Rules for Chemical Reactions, Collisional, and Intramolecular Processes
2.1. Rates of Reaction, Collisional, and Spontaneous Processes. Rate Constant. Kinetic Types of Simple Processes
2.2. Chemical Equilibrium. Equilibrium Constant
2.3. Arrhenius equation
2.4. Complex Reactions
2.4.1. Consecutive Reactions. Steady-state Method
Problems
References
3. Theory of Elementary Processes
3.1. Cross-sections, Rate Constants, and Probabilities of Elementary processes
3.2. The detailed balance principle. Adiabatic approximations. Potential Energy Curves and Surfaces
3.3. Descriptions of Collisional Processes using Potential Energy Curves and Surfaces. Intramolecular Vibrational Relaxation in Polyatomic Molecules
3.4. Non-adiabatic Transitions. Perturbation theory. Probabilities of Adiabatic and Non-adiabatic Transitions
3.5. Intermolecular Interactions. Types of Intermolecular Interactions
3.6. Semiempirical Model Potentials
Problems
References
4. Photoprocesses
4.1. Primary and Secondary Gas-Phase Photoprocesses. Quantum Yields of the Gas-Phase Photoprocesses
4.2. Optical Transitions. Selection Rules for Optical Transitions. Spin-Orbit Coupling and Spin-Forbidden Radiative Transitions
4.3. Absorption. Absorption Band Intensities. Einstein Transition Probabilities. Oscillator Strength. Transition Dipole Moment. Beer-Lambert Law
4.4. Franck-Condon Principle for Bound-bound and Bound-free Optical Transitions
4.5. Luminescence. Radiative lifetime. The Relationship between Einstein Transition Probabilities and Transition Dipole Moment
4.6. Intramolecular Perturbations. Selection Rules and Franck-Condon Principle for Intramolecular Perturbation. Perturbations between Bound States. Abnormally long Radiative Lifetime
4.7. Spontaneous Predissociation of Two-, Tri- and Polyatomic Molecules. Classes of Predissociation Processes
4.8. Photodecay of Two-, Tri- and Polyatomic Molecules. Long-lived States of Polyatomic Molecules
References
5. Energy Transfer in Collisions
5.1. Translational-Translational Energy Transfer (T-T exchange)
5.2. Rotational-Translational Energy Transfer (R-T exchange)
5.3. Vibrational Energy Transfer (V-T, V-R, T Processes)
5.4. Non-adiabatic Coupling and Vibrational Energy Transfer
5.5. Collision-Induced Non-Adiabatic Transitions
5.6. Collision-Induced Predissociation
5.7. Vibrational Relaxation via Several Electronic States
5.8. Electronic Deactivation
Problems
References
6. Weakly-Bound Complexes
6.1. Hydrogen- and Halogen-Bond Complexes
6.2. Van der Waals Complexes. 6.3. Rare gas-halogen Molecule Clusters
References
7. Termolecular reactions
7.1. Termolecular recombination. Mechanism of Termolecular Recombination
References
8. Chemiluminescence
8.1. Classes of Chemiluminescence Processes. Gas-P Rate Constants
8.2. General Rules of Radiative Recombination
References
Solution of Problems
Index.