TY - GEN N2 - This book provides researchers in the fields of organic chemistry, organometallic chemistry and homogeneous catalysis with an overview of significant recent developments in the area of metal-ligand cooperativity, with a focus on pincer architectures. The various contributions highlight the widespread impact of ML co-operativity phenomena on modern organometallic chemistry and catalyst development. The development of efficient and selective catalytic transformations relies on the understanding and fine control of the various elementary reactions that constitutes a catalytic cycle. Co-operative ligands, which actively participate in bond making and bond breaking together to the metal they support, open up new avenues in this area. In particular, buttressing a weak or reactive metal-ligand bond by flanking coordinating arms in a pincer ligand design is proving a versatile strategy to access robust metal complexes that exhibit unusual and selective reactivity patterns. DO - 10.1007/978-3-030-68916-2 DO - doi AB - This book provides researchers in the fields of organic chemistry, organometallic chemistry and homogeneous catalysis with an overview of significant recent developments in the area of metal-ligand cooperativity, with a focus on pincer architectures. The various contributions highlight the widespread impact of ML co-operativity phenomena on modern organometallic chemistry and catalyst development. The development of efficient and selective catalytic transformations relies on the understanding and fine control of the various elementary reactions that constitutes a catalytic cycle. Co-operative ligands, which actively participate in bond making and bond breaking together to the metal they support, open up new avenues in this area. In particular, buttressing a weak or reactive metal-ligand bond by flanking coordinating arms in a pincer ligand design is proving a versatile strategy to access robust metal complexes that exhibit unusual and selective reactivity patterns. T1 - Metal-ligand co-operativity :catalysis and the pincer-metal platform / AU - Koten, Gerard van, AU - Kirchner, Karl, AU - Moret, Marc-Etienne, VL - 68 CN - QD474 ID - 1435373 KW - Ligands (Biochemistry) KW - Organometallic chemistry. KW - Metal catalysts. KW - Ligands (Biochimie) KW - Chimie organométallique. KW - Catalyseurs métalliques. SN - 9783030689162 SN - 3030689166 SN - 9783030689179 SN - 3030689174 SN - 9783030689186 SN - 3030689182 TI - Metal-ligand co-operativity :catalysis and the pincer-metal platform / LK - https://univsouthin.idm.oclc.org/login?url=https://link.springer.com/10.1007/978-3-030-68916-2 UR - https://univsouthin.idm.oclc.org/login?url=https://link.springer.com/10.1007/978-3-030-68916-2 ER -