001435696 000__ 03677cam\a2200565\a\4500
001435696 001__ 1435696
001435696 003__ OCoLC
001435696 005__ 20230309003948.0
001435696 006__ m\\\\\o\\d\\\\\\\\
001435696 007__ cr\un\nnnunnun
001435696 008__ 210410s2021\\\\si\\\\\\ob\\\\000\0\eng\d
001435696 019__ $$a1244806482
001435696 020__ $$a9789811611636$$q(electronic bk.)
001435696 020__ $$a9811611637$$q(electronic bk.)
001435696 020__ $$z9789811611629
001435696 020__ $$z9811611629
001435696 0247_ $$a10.1007/978-981-16-1163-6$$2doi
001435696 035__ $$aSP(OCoLC)1245674790
001435696 040__ $$aEBLCP$$beng$$epn$$cEBLCP$$dGW5XE$$dOCLCO$$dEBLCP$$dYDX$$dOCLCF$$dUKAHL$$dVLB$$dOCLCQ$$dOCLCO$$dOCLCQ
001435696 049__ $$aISEA
001435696 050_4 $$aQD474$$b.E54 2021eb
001435696 08204 $$a546/.6$$223
001435696 1001_ $$aEndo, Kenichi.
001435696 24510 $$aKinetically controlled stepwise syntheses of a heterometallic complex and a tetrahedral chiral-at-metal complex /$$cKenichi Endo.
001435696 264_1 $$aSingapore :$$bSpringer,$$c2021.
001435696 264_4 $$c©2021
001435696 300__ $$a1 online resource (xv, 80 pages)
001435696 336__ $$atext$$btxt$$2rdacontent
001435696 337__ $$acomputer$$bc$$2rdamedia
001435696 338__ $$aonline resource$$bcr$$2rdacarrier
001435696 4901_ $$aSpringer Theses
001435696 500__ $$a"Doctoral thesis accepted by the University of Tokyo, Tokyo, Japan."
001435696 504__ $$aIncludes bibliographical references.
001435696 50500 $$tGeneral Introduction --$$tHeterometallic CoIINi₃II Complex --$$tTetrahedral Chiral-at-Metal ZnII Complex --$$tConclusion.
001435696 506__ $$aAccess limited to authorized users.
001435696 520__ $$aThis book describes novel synthetic methodologies for two kinds of structurally elaborate metal complexes: a heterometallic complex and a tetrahedral chiral-at-metal complex. The book provides the tools and inspiration to chemists for development of metal complexes with wide structural diversity than had previously been possible. For each of the two topics, existing synthetic methods for similar compounds are discussed first, and then new strategies are presented, followed by the demonstration of the synthesis of novel compounds supported by experimental results. Both of the final products in this research, a Co heterometallic complex covered in the first topic and a tetrahedral chiral-at-metal complex in the second one are difficult to obtain by using common synthetic methods for thermodynamic reasons. This research achieved highly selective syntheses of these compounds using newly designed strategies that enable precise kinetic control. Such an approach will be useful for synthesizing other new metal complexes. Since the last century, organic chemistry has flourished with the development of a variety of synthetic techniques that make precise kinetic control possible. Coordination chemistry of 3d or main-group transition metals has been mainly based on simple one-step reactions that yield only thermodynamic products. The publication of this book helps pave the way to kinetically controlled precise syntheses of various metal complexes.
001435696 588__ $$aDescription based on print version record.
001435696 650_0 $$aMetal complexes$$xSynthesis.
001435696 650_0 $$aChirality.
001435696 650_6 $$aComplexes métalliques$$xSynthèse.
001435696 650_6 $$aChiralité.
001435696 655_0 $$aElectronic books.
001435696 77608 $$iPrint version:$$aEndo, Kenichi.$$tKinetically Controlled Stepwise Syntheses of a Heterometallic Complex and a Tetrahedral Chiral-At-Metal Complex.$$dSingapore : Springer Singapore Pte. Limited, ©2021$$z9789811611629
001435696 830_0 $$aSpringer theses.
001435696 852__ $$bebk
001435696 85640 $$3Springer Nature$$uhttps://univsouthin.idm.oclc.org/login?url=https://link.springer.com/10.1007/978-981-16-1163-6$$zOnline Access$$91397441.1
001435696 909CO $$ooai:library.usi.edu:1435696$$pGLOBAL_SET
001435696 980__ $$aBIB
001435696 980__ $$aEBOOK
001435696 982__ $$aEbook
001435696 983__ $$aOnline
001435696 994__ $$a92$$bISE