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001442724 0247_ $$a10.1007/978-981-16-7148-7$$2doi
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001442724 1001_ $$aYamazaki, Yasuomi.
001442724 24510 $$aDevelopment of synthetic methods for novel photofunctional multinuclear complexes :$$bsimple synthetic methods for multinuclear complexes using various C-C coupling reactions /$$cYasuomi Yamazaki.
001442724 260__ $$aSingapore :$$bSpringer,$$c[2022]
001442724 300__ $$a1 online resource
001442724 336__ $$atext$$btxt$$2rdacontent
001442724 337__ $$acomputer$$bc$$2rdamedia
001442724 338__ $$aonline resource$$bcr$$2rdacarrier
001442724 347__ $$atext file
001442724 347__ $$bPDF
001442724 4901_ $$aSpringer theses,$$x2190-5061
001442724 500__ $$a"Doctoral Thesis accepted by Tokyo Institute of Technology, Tokyo, Japan."
001442724 504__ $$aIncludes bibliographical references.
001442724 5050_ $$aGeneral Introduction -- Synthesis of Multinuclear Complexes Using the Mizoroki-Heck reaction -- Selective Synthesis of Various Photofunctional Multinuclear Complexes Using Combination of the Mizoroki-Heck Reaction and the Homo-coupling Reaction -- Photochemical and Electrochemical Hydrogenation of Pi Conjugated Bridging Ligands on Photofunctional Multinuclear Complexes -- Synthesis of Novel Multinuclear Complexes for Light-harvesting Systems Using the Coupling Reactions with Ring-shaped Multinuclear Re(I) Complexes as Building Blocks -- Conclusions.
001442724 506__ $$aAccess limited to authorized users.
001442724 520__ $$aThis book presents several helpful synthetic methods for diverse multinuclear complexes. The results described can be used to selectively connect mononuclear as well as multinuclear complexes with other metal complexes to construct valuable photofunctional compounds. Using the new synthetic methods, it was possible to selectively connect several types of metal complexes in a single step under relatively mild reaction conditions. This so-called building block approach utilizes various C-coupling reactions between metal complexes with functional groups as active moieties. Owing to the large pi-conjugation systems, the multinuclear complexes synthesized using coupling reactions showed a strong absorption ability over a wide range of visible light and long emission lifetimes, which are ideal properties for photosensitizers and light absorbers. By combining these coupling methods with the newly developed hydrogenation reactions, the binding mode of the linkers in multinuclear complexes can be modified in order to tune the photophysical properties and photocatalytic ability. As such, the synthesized multinuclear complexes can be used for various purposes, e.g., as photocatalysts and photosensitizers, and in light-harvesting systems. The synthetic methods and strategies presented in this book diversify not only the structures but also functions of multinuclear complexes.
001442724 588__ $$aOnline resource; title from PDF title page (SpringerLink, viewed November 18, 2021).
001442724 650_0 $$aPhotochemistry.
001442724 650_6 $$aPhotochimie.
001442724 655_0 $$aElectronic books.
001442724 77608 $$iPrint version:$$aYamazaki, Yasuomi.$$tDevelopment of synthetic methods for novel photofunctional multinuclear complexes.$$dSingapore : Springer, [2022]$$z9811671478$$z9789811671470$$w(OCoLC)1268326211
001442724 830_0 $$aSpringer theses,$$x2190-5061
001442724 852__ $$bebk
001442724 85640 $$3Springer Nature$$uhttps://univsouthin.idm.oclc.org/login?url=https://link.springer.com/10.1007/978-981-16-7148-7$$zOnline Access$$91397441.1
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001442724 980__ $$aEBOOK
001442724 982__ $$aEbook
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