@article{1442791,
      recid = {1442791},
      author = {Imayoshi, Ayumi.},
      title = {Discrimination of mobile supramolecular chirality :  acylative molecular transformations by organocatalysis /},
      publisher = {Springer,},
      address = {Singapore :},
      pages = {1 online resource},
      year = {2022},
      note = {"Doctoral Thesis accepted by Kyoto University, Kyoto,  Japan."},
      abstract = {This book proposes a novel concept for molecular  recognition. In the field of asymmetric synthesis  approaching the mature science, asymmetric discrimination  and catalytic synthesis of chiral supramolecules still  stand as unsolved problems. The extreme difficulty in  asymmetric synthesis of such supramolecules may result from  the mobile nature of supramolecular chirality. Here the  author shows the first highly enantioselective synthesis of  mechanically chiral supramolecules. In the presence of a  chiral organocatalyst, a mechanically planar chiral  rotaxane was obtained with p erfect enantiopurity (>99% ee)  with an excellent selectivity. The dynamic and flexible  recognition mode enabled asymmetric synthesis of  supramolecules with conformational flexibility and  mobility. The recognition mode of the catalyst is a  contrast to the traditional static and rigid recognition  mode of the typical conventional catalysts. The concept of  dynamic molecular recognition will be adopted as a novel  concept in a wide range of fields beyond the field of  organic chemistry, including material chemistry,  biochemistry, and medicinal chemistry.},
      url = {http://library.usi.edu/record/1442791},
      doi = {https://doi.org/10.1007/978-981-16-7431-0},
}