001446797 000__ 03662cam\a2200541Ii\4500 001446797 001__ 1446797 001446797 003__ OCoLC 001446797 005__ 20230310004018.0 001446797 006__ m\\\\\o\\d\\\\\\\\ 001446797 007__ cr\un\nnnunnun 001446797 008__ 220520s2022\\\\si\a\\\\ob\\\\000\0\eng\d 001446797 019__ $$a1319198923$$a1319217205 001446797 020__ $$a9789811922473$$q(electronic bk.) 001446797 020__ $$a9811922470$$q(electronic bk.) 001446797 020__ $$z9789811922466 001446797 020__ $$z9811922462 001446797 0247_ $$a10.1007/978-981-19-2247-3$$2doi 001446797 035__ $$aSP(OCoLC)1319075174 001446797 040__ $$aYDX$$beng$$erda$$epn$$cYDX$$dGW5XE$$dEBLCP$$dOCLCF$$dUKAHL$$dOCLCQ$$dN$T 001446797 049__ $$aISEA 001446797 050_4 $$aTA455.P46 001446797 08204 $$a620.1/98$$223/eng/20220601 001446797 1001_ $$aZhang, Wenrui,$$eauthor. 001446797 24510 $$aOxide-ion conduction in the Dion-Jacobson-type layered perovskites /$$cWenrui Zhang. 001446797 264_1 $$aSingapore :$$bSpringer,$$c[2022] 001446797 264_4 $$c©2022 001446797 300__ $$a1 online resource :$$billustrations (chiefly color). 001446797 336__ $$atext$$btxt$$2rdacontent 001446797 337__ $$acomputer$$bc$$2rdamedia 001446797 338__ $$aonline resource$$bcr$$2rdacarrier 001446797 4901_ $$aSpringer theses 001446797 500__ $$a"Doctoral thesis accepted by Tokyo Institute of Technology, Tokyo, Japan." 001446797 504__ $$aIncludes bibliographical references. 001446797 5050_ $$a1. Introduction -- 2. New Oxide-ion conductors of DionJacobson-Type Layered Perovskites CsBi₂Ti₂NbO₁₀[delta] -- 3. New Oxide-ion conductors of DionJacobson- Type Layered Perovskites CsLn₂Ti2₂NbO₁₀ (Ln = La, Pr, Nd, Sm, Gd, Ho and Yb) and CsLa₂xMxTi₂+yNb₁yO₁₀x/₂y/₂ (M = Ca, Sr and Ba; x = 0, 0.1; y = 0.1, 0 and 0.1) -- 4. Conclusion and Future Work. . 001446797 506__ $$aAccess limited to authorized users. 001446797 520__ $$aThis book reports a study of a class of DionJacobson-type layered perovskite oxides in which high oxide-ion conductivities in phases were discovered for the first time in the world. The oxide-ion conductors are important in various energy conversion devices and environmental protection applications such as solid-oxide fuel cells, oxygen gas sensors, oxygen separation membranes, and oxygen-based catalysts. The discoveries are based on a new screening method, called the bond valence method, combined with an original design concept. The present finding of high oxide-ion conductivity reported in the thesis suggested the potential of DionJacobson phases as a platform to identify superior oxide-ion conductors. To understand what causes such high oxide-ion conductivities in these layered perovskite oxides, the author analyzed their crystal structures at high temperature and described the relationship between oxide-ion conductivities and their crystal structures. A deep understanding of the mechanisms of oxide-ion diffusivity at an atomic level in the DionJacobson phases is clarified. The discovery of these materials, the new screening method, and the original design concept make possible the realization of many environment-friendly technologies. The findings in this thesis facilitate the possibilities for many novel applications that will help lead to a sustainable future. . 001446797 588__ $$aOnline resource; title from PDF title page (SpringerLink, viewed June 1, 2022). 001446797 650_0 $$aPerovskite materials. 001446797 650_0 $$aElectric conductivity. 001446797 655_0 $$aElectronic books. 001446797 77608 $$iPrint version:$$z9811922462$$z9789811922466$$w(OCoLC)1304359969 001446797 830_0 $$aSpringer theses. 001446797 852__ $$bebk 001446797 85640 $$3Springer Nature$$uhttps://univsouthin.idm.oclc.org/login?url=https://link.springer.com/10.1007/978-981-19-2247-3$$zOnline Access$$91397441.1 001446797 909CO $$ooai:library.usi.edu:1446797$$pGLOBAL_SET 001446797 980__ $$aBIB 001446797 980__ $$aEBOOK 001446797 982__ $$aEbook 001446797 983__ $$aOnline 001446797 994__ $$a92$$bISE