Oxide-ion conduction in the Dion-Jacobson-type layered perovskites / Wenrui Zhang.
2022
TA455.P46
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Title
Oxide-ion conduction in the Dion-Jacobson-type layered perovskites / Wenrui Zhang.
Author
Zhang, Wenrui, author.
ISBN
9789811922473 (electronic bk.)
9811922470 (electronic bk.)
9789811922466
9811922462
9811922470 (electronic bk.)
9789811922466
9811922462
Published
Singapore : Springer, [2022]
Copyright
©2022
Language
English
Description
1 online resource : illustrations (chiefly color).
Other Standard Identifiers
10.1007/978-981-19-2247-3 doi
Call Number
TA455.P46
Dewey Decimal Classification
620.1/98
Summary
This book reports a study of a class of DionJacobson-type layered perovskite oxides in which high oxide-ion conductivities in phases were discovered for the first time in the world. The oxide-ion conductors are important in various energy conversion devices and environmental protection applications such as solid-oxide fuel cells, oxygen gas sensors, oxygen separation membranes, and oxygen-based catalysts. The discoveries are based on a new screening method, called the bond valence method, combined with an original design concept. The present finding of high oxide-ion conductivity reported in the thesis suggested the potential of DionJacobson phases as a platform to identify superior oxide-ion conductors. To understand what causes such high oxide-ion conductivities in these layered perovskite oxides, the author analyzed their crystal structures at high temperature and described the relationship between oxide-ion conductivities and their crystal structures. A deep understanding of the mechanisms of oxide-ion diffusivity at an atomic level in the DionJacobson phases is clarified. The discovery of these materials, the new screening method, and the original design concept make possible the realization of many environment-friendly technologies. The findings in this thesis facilitate the possibilities for many novel applications that will help lead to a sustainable future. .
Note
"Doctoral thesis accepted by Tokyo Institute of Technology, Tokyo, Japan."
Bibliography, etc. Note
Includes bibliographical references.
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Access limited to authorized users.
Source of Description
Online resource; title from PDF title page (SpringerLink, viewed June 1, 2022).
Series
Springer theses.
Available in Other Form
Print version: 9789811922466
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Table of Contents
1. Introduction
2. New Oxide-ion conductors of DionJacobson-Type Layered Perovskites CsBi₂Ti₂NbO₁₀[delta]
3. New Oxide-ion conductors of DionJacobson- Type Layered Perovskites CsLn₂Ti2₂NbO₁₀ (Ln = La, Pr, Nd, Sm, Gd, Ho and Yb) and CsLa₂xMxTi₂+yNb₁yO₁₀x/₂y/₂ (M = Ca, Sr and Ba; x = 0, 0.1; y = 0.1, 0 and 0.1)
4. Conclusion and Future Work. .
2. New Oxide-ion conductors of DionJacobson-Type Layered Perovskites CsBi₂Ti₂NbO₁₀[delta]
3. New Oxide-ion conductors of DionJacobson- Type Layered Perovskites CsLn₂Ti2₂NbO₁₀ (Ln = La, Pr, Nd, Sm, Gd, Ho and Yb) and CsLa₂xMxTi₂+yNb₁yO₁₀x/₂y/₂ (M = Ca, Sr and Ba; x = 0, 0.1; y = 0.1, 0 and 0.1)
4. Conclusion and Future Work. .