5 All-Inorganic Zeolitic Octahedral Metal Oxides
5.1 General Introduction of Zeolitic Octahedral Metal Oxides
5.2 Material Synthesis
5.2.1 Conditions for Material Synthesis
5.2.2 Design of Framework
5.3 Advanced Structure Determination, Step by Step
5.3.1 Structure Determination Using Single Crystal X-ray Analysis
5.3.2 Structure Determination Using Powder X-ray Diffraction Analysis
5.3.3 Structure Confirmation Using Atomic Resolution Electron Microscopy
5.4 Typical Zeolitic Octahedral Metal Oxides
5.4.1 [epsilon]-Keggin POM-Based ZOMOs
5.4.2 Hexagon Unit-Based ZOMOs

Intro
Preface
Contents
Contributors
1 Overview of Crystalline Metal Oxide Catalysts
1.1 General Introduction
1.1.1 Progress of Metal Oxide Catalyst Development: Toward Complexation and Crystalline State
1.1.2 Structural Classification of Complex Metal Oxide Catalysts
1.2 Structure Chemistry and Catalysis Chemistry of Crystalline Complex Metal Oxide Catalysts
1.2.1 Simple Metal Oxides with Catalytic Function
1.2.2 Crystalline Complex Metal Oxides with Catalytic Function
1.2.3 Synthetic Chemistry of Crystalline Complex Metal Oxide Catalysts
References

2 Catalysis Chemistry of Crystalline Complex Metal Oxide Catalysts
2.1 Catalysis Chemistry of Crystalline Complex Metal Oxides
2.1.1 Metastable State
2.1.2 Dynamic Reversible Phase Transfer Under Catalysis (MvK Mechanism)
2.1.3 Defect Structure and Ion-Conduction
2.1.4 Valence Control and Mixed Valence
2.1.5 Introducing Coordinatively Unsaturated State
2.1.6 Catalytic Collaboration among Constituting Elements and Interplay of Different Structural Phases
2.1.7 Crystal Facet Dependence of Catalytic Function
2.1.8 Catalysis based on Molecularity of Discrete Structure

2.1.9 Descriptors
2.2 Catalysis Chemistry in Complexity
2.2.1 Structure Difference Between Bulk and Surface of Complex Metal Oxides
2.2.2 Difficulty in Determination of Active Site Number on Metal Oxide Surface
2.2.3 Micro-Structure in Amorphous Complex Metal Oxides
2.2.4 Structural Surface Material Formation
References
3 Polyoxometalate Unit Assembling for Crystal Catalysts
3.1 Introduction
3.1.1 Polyoxometalates
3.1.2 Structure of Polyoxometalates
3.1.3 Scope and Limitations
3.2 Design of Polyoxometalate Crystals
3.2.1 Molecule Structure

3.2.2 Polyoxometalate Unit-Based Crystal
3.3 Perspective
References
4 Mo-V-Based Crystalline Complex Metal Oxide Catalysts
4.1 Introduction
4.2 Mo-V-Based Oxide Catalysts for Selective Oxidations
4.2.1 Development of Industrial Oxidation Catalysts
4.2.2 Evolution of Crystalline Mo3VOx Catalysts
4.3 Catalytic Property of Crystalline Mo3VOx
4.3.1 Catalysis Field based on Crystal Structure
4.3.2 Oxidation Catalysis for Ethane Oxidation
4.3.3 Catalytically Active Structure for Acrolein Oxidation
4.4 Conclusions and Future Outlook
References