@article{1463658,
      recid = {1463658},
      author = {Ozawa, Yu,},
      title = {Copper(I)-catalyzed stereoselective borylation reactions :  multisubstituted alkenyl and allylic boronates /},
      pages = {1 online resource (xiii, 226 pages) :},
      note = {"Doctoral thesis accepted by Hokkaido University, Sapporo,  Japan."},
      abstract = {This book focuses on the development of novel  functionalized organoboron compounds and those synthetic  methods. High degrees of chemo-, regio-, and  stereoselectivities of the borylation reactions are  attained through catalyst design and optimization.  Furthermore, the selectivity-determining mechanisms are  analyzed with state-of-the-art DFT and other computational  methods. In this book, the author synthesizes some  multi-substituted alkenyl and allylic boronates via  borylation reactions using a copper(I)/diboron catalyst  system. Those compounds contain novel densely substituted  and distorted structures, which have not been accessed by  other methods. The high stereoselectivities are achieved by  the optimization of the catalyst, especially the ligand.  Some new ligands are also developed in this book.  Furthermore, the derivatization of the borylation products  is demonstrated to access the sterically demanding complex  molecules. Also, the author performs computational analysis  to reveal how the catalyst controls the selectivities. The  deep insight into the reaction mechanism provides guides  for rational catalyst design for not only copper(I)  catalysis but also other transition metal catalysis. Thus,  the content should be of interest to academic and  industrial scientists in a wide range of areas.},
      url = {http://library.usi.edu/record/1463658},
      doi = {https://doi.org/10.1007/978-981-99-1098-4},
}