001463658 000__ 04294cam\a2200625\i\4500
001463658 001__ 1463658
001463658 003__ OCoLC
001463658 005__ 20230601003331.0
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001463658 007__ cr\cn\nnnunnun
001463658 008__ 230502s2023\\\\si\a\\\\ob\\\\000\0\eng\d
001463658 019__ $$a1378096167
001463658 020__ $$a9789819910984$$qelectronic book
001463658 020__ $$a9819910986$$qelectronic book
001463658 020__ $$z9789819910977$$qprint
001463658 020__ $$z9819910978$$qprint
001463658 0247_ $$a10.1007/978-981-99-1098-4$$2doi
001463658 035__ $$aSP(OCoLC)1378079228
001463658 040__ $$aGW5XE$$beng$$erda$$epn$$cGW5XE$$dYDX$$dEBLCP$$dYDX
001463658 049__ $$aISEA
001463658 050_4 $$aQD412.B1$$bO93 2023
001463658 08204 $$a547/.05671$$223/eng/20230502
001463658 1001_ $$aOzawa, Yu,$$eauthor.
001463658 24510 $$aCopper(I)-catalyzed stereoselective borylation reactions :$$bmultisubstituted alkenyl and allylic boronates /$$cYu Ozawa.
001463658 264_1 $$aSingapore :$$bSpringer,$$c[2023]
001463658 300__ $$a1 online resource (xiii, 226 pages) :$$billustrations (some color).
001463658 336__ $$atext$$btxt$$2rdacontent
001463658 337__ $$acomputer$$bc$$2rdamedia
001463658 338__ $$aonline resource$$bcr$$2rdacarrier
001463658 4901_ $$aSpringer theses
001463658 500__ $$a"Doctoral thesis accepted by Hokkaido University, Sapporo, Japan."
001463658 504__ $$aIncludes bibliographical references.
001463658 5050_ $$a1. General Introduction -- 2. Modification of QuinoxP*-Type Bisphosphine Ligands for High-Performance Asymmetric Boryl Substitution of Racemic Allyl Electrophiles -- 3. Allylcopper(I) Isomerization-Enabled Copper(I)-Catalyzed Intramolecular Alkylboration of Terminal Allenes -- 4. Intermolecular Alkylboration of gem-Disubstituted Allenes for Stereoselective Synthesis of Multi-Alkylated Allylic Boronates -- 5. Computational Investigation on Copper(I)-Catalyzed Enantioselective Radical Borylation of Benzyl Halides -- 6. Summary of This Thesis.
001463658 506__ $$aAccess limited to authorized users.
001463658 520__ $$aThis book focuses on the development of novel functionalized organoboron compounds and those synthetic methods. High degrees of chemo-, regio-, and stereoselectivities of the borylation reactions are attained through catalyst design and optimization. Furthermore, the selectivity-determining mechanisms are analyzed with state-of-the-art DFT and other computational methods. In this book, the author synthesizes some multi-substituted alkenyl and allylic boronates via borylation reactions using a copper(I)/diboron catalyst system. Those compounds contain novel densely substituted and distorted structures, which have not been accessed by other methods. The high stereoselectivities are achieved by the optimization of the catalyst, especially the ligand. Some new ligands are also developed in this book. Furthermore, the derivatization of the borylation products is demonstrated to access the sterically demanding complex molecules. Also, the author performs computational analysis to reveal how the catalyst controls the selectivities. The deep insight into the reaction mechanism provides guides for rational catalyst design for not only copper(I) catalysis but also other transition metal catalysis. Thus, the content should be of interest to academic and industrial scientists in a wide range of areas.
001463658 588__ $$aDescription based on online resource; title from digital title page (viewed on May 26, 2023).
001463658 650_0 $$aOrganoboron compounds$$xSynthesis.
001463658 650_0 $$aCopper catalysts.
001463658 655_0 $$aElectronic books.
001463658 77608 $$iPrint version: $$z9819910978$$z9789819910977$$w(OCoLC)1370487487
001463658 830_0 $$aSpringer theses.
001463658 852__ $$bebk
001463658 85640 $$3Springer Nature$$uhttps://univsouthin.idm.oclc.org/login?url=https://link.springer.com/10.1007/978-981-99-1098-4$$zOnline Access$$91397441.1
001463658 909CO $$ooai:library.usi.edu:1463658$$pGLOBAL_SET
001463658 980__ $$aBIB
001463658 980__ $$aEBOOK
001463658 982__ $$aEbook
001463658 983__ $$aOnline
001463658 994__ $$a92$$bISE