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001469701 019__ $$a1382695894
001469701 020__ $$a9783031328671$$q(electronic bk.)
001469701 020__ $$a3031328671$$q(electronic bk.)
001469701 020__ $$z9783031328664
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001469701 0247_ $$a10.1007/978-3-031-32867-1$$2doi
001469701 035__ $$aSP(OCoLC)1382525990
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001469701 08204 $$a547/.2$$223/eng/20230622
001469701 24500 $$aC-C cross couplings with 3d base metal catalysts /$$cXiao-Feng Wu, editor ; with contributions by C.M.A. Afsina [and 23 others].
001469701 264_1 $$aCham :$$bSpringer,$$c[2023]
001469701 264_4 $$c©2023
001469701 300__ $$a1 online resource (vii, 400 pages).
001469701 336__ $$atext$$btxt$$2rdacontent
001469701 337__ $$acomputer$$bc$$2rdamedia
001469701 338__ $$aonline resource$$bcr$$2rdacarrier
001469701 4901_ $$aTopics in organometallic chemistry ;$$v93
001469701 5050_ $$aIntro -- Preface -- Contents -- C-C Cross Couplings with Chromium Catalysis -- 1 Introduction -- 2 Cr-Catalyzed Cross Couplings of C-O Bonds to Form C-C Bonds -- 2.1 Cr-Catalyzed Kumada Coupling of C-O Bonds -- 2.2 Cr-Catalyzed Cross-Electrophile-Coupling of C-O Bonds -- 3 Cr-Catalyzed Cross Couplings of C-N Bonds to Form C-C Bonds -- 3.1 Cr-Catalyzed Kumada Coupling of C-N Bonds -- 3.2 Cr-Catalyzed Cross-Electrophile-Coupling of C-N Bonds -- 4 Cr-Catalyzed Cross Couplings of C-Halide, C-S and C-P Bonds to Form C-C Bonds -- 5 Conclusions -- References -- Mn-Catalyzed C-C Coupling Reactions
001469701 5058_ $$a1 Introduction -- 2 C-H Activation -- 2.1 Addition to Polar Bonds -- 2.2 Addition to Nonpolar Bonds -- 2.3 Addition to Mn=C Bond -- 2.4 Substitutive C-H Activation -- 3 Hydrocarbofunctionalization of Unsaturated C-C Bond Without C-H Activation -- 4 Conclusion -- References -- Iron-Catalyzed Carbon-Carbon Coupling Reaction -- 1 Introduction -- 2 Fe-Catalyzed Coupling Reaction of Electrophilic Reagents and Nucleophilic Reagents -- 2.1 Fe-Catalyzed C(sp2)C(sp3) Coupling Reaction -- 2.1.1 Fe-Catalyzed C(sp2)X-C(sp3)M Coupling -- 2.1.2 Fe-Catalyzed C(sp3)X-C(sp2)M Coupling
001469701 5058_ $$a2.2 Fe-Catalyzed C(sp2)-C(sp2) Coupling -- 2.3 Fe-Catalyzed C(sp3)-C(sp3) Coupling -- 2.4 Fe-Catalyzed C(sp3)-C(sp) Coupling -- 3 Fe-Catalyzed C-H Direct Coupling -- 3.1 Fe-Catalyzed C-H Direct Coupling-C(sp3)-C(sp2) Coupling -- 3.2 Fe-Catalyzed C-H Direct Coupling-C(sp2)-C(sp2) Coupling -- 3.3 Fe-Catalyzed C-H Direct Coupling-C(sp2)-C(sp) Coupling -- 4 Fe-Catalyzed Oxidative/Reductive Coupling -- 4.1 Fe-Catalyzed Oxidative Coupling -- 4.2 Fe-Catalyzed Reductive Coupling -- 5 Summary and Outlook -- References -- Cobalt-Catalyzed C-C Coupling Reactions with Csp3 Electrophiles -- 1 Introduction
001469701 5058_ $$a2 Cobalt-Catalyzed C-Csp3 Coupling Reactions Using Organometallic Reagents -- 2.1 Cobalt-Catalyzed C-Csp3 Coupling Reactions with Organomagnesium Reagents -- 2.2 Cobalt-Catalyzed C-Csp3 Coupling Reactions with Organozinc Reagents -- 2.3 Cobalt-Catalyzed C-Csp3 Coupling Reactions with Mn-, Al-, and B-Based Reagents -- 3 Cobalt-Catalyzed Reductive C-Csp3 Coupling Reactions Between Two Electrophiles -- 4 Cobalt-Catalyzed C-Csp3 Coupling Reactions via C-H Activations -- 5 Conclusions -- References -- Co-catalyzed C-C Coupling Reactions with Csp2 Electrophiles -- 1 Introduction
001469701 5058_ $$a2 Csp2 Electrophile with Grignard Regents -- 2.1 Csp2-Csp2 Bonds Formation -- 2.2 Csp2-Csp3 Bonds Formation -- 3 Csp2 Electrophile with Organozinc Reagents -- 3.1 Csp2-Csp3 Bonds Formation -- 3.2 Csp2-Csp Bonds Formation -- 4 Csp2 Electrophile with Other Organometallic Reagents -- 5 Co-catalyzed Reductive Cross-Coupling Involving Csp2 Electrophiles -- 5.1 Csp2-Csp3 Bonds Formation -- 5.2 Formation of Csp2-Csp2 Bonds -- 5.2.1 Formation of Ar-Vinyl Derivatives -- 5.2.2 Formation of Ar-(Het)Ar Derivatives -- 6 Conclusion -- References -- Recent Advances in Nickel-Catalyzed C-C Cross-Coupling
001469701 506__ $$aAccess limited to authorized users.
001469701 520__ $$aThis volume presents recent progress on 3d base metal catalyzed C-C cross coupling reactions. The contributions provide detailed discussions on the use of cheap metal catalysts such as Cr, Mn, Fe, Co, Ni, Cu, and Zn to construct Csp2-Csp2, Csp2-Csp3 and Csp3-Csp3 bonds with a variety of substrates. These non-noble metal catalyst have many advantages such as being inexpensive, having low toxicity and are environmentally benign. Therefore the use of cheap metal catalysts in organic synthesis has gained much attention in efforts to develop more sustainable synthetic green chemistry. Each chapter is written by international experts in the field and is a great resource for students, researchers and chemists working in industry to gain an overview on the latest developments.
001469701 650_0 $$aOrganic compounds$$xSynthesis.
001469701 650_0 $$aMetal catalysts.
001469701 655_0 $$aElectronic books.
001469701 7001_ $$aWu, Xiao-Feng,$$d1985-$$eeditor.
001469701 77608 $$iPrint version: $$z3031328663$$z9783031328664$$w(OCoLC)1375537936
001469701 830_0 $$aTopics in organometallic chemistry ;$$v93.
001469701 852__ $$bebk
001469701 85640 $$3Springer Nature$$uhttps://univsouthin.idm.oclc.org/login?url=https://link.springer.com/10.1007/978-3-031-32867-1$$zOnline Access$$91397441.1
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001469701 980__ $$aBIB
001469701 980__ $$aEBOOK
001469701 982__ $$aEbook
001469701 983__ $$aOnline
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