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Table of Contents
Intro
Series Editors' Foreword
Preface
Contents
About the Authors
About the Series Editors
Abbreviations
1 Application of Instrumental Methods in the Analysis of Historical, Artistic, and Archaeological Objects
1.1 Archaeology and Conservation of Cultural Heritage
1.1.1 Archaeology, Archaeometry, and Archaeological Science
1.1.2 Conservation of Cultural Heritage
1.1.3 A Brief History of the Scientific Analysis of Cultural Heritage
1.2 Role of the Analytical Methods in Archaeometrical and Cultural Heritage Research
1.3 Information Provided by the Analytical Research
1.3.1 Analytical Information Obtained from the Object
1.3.2 Analytical Information Obtained from the Environment
1.3.3 Analytical Information Obtained from the Conservation Processes
1.4 Analytical Methodologies Applied to Archaeometry and Cultural Heritage Research
1.4.1 Requirements of the Analytical Methodologies
1.4.2 Sampling Strategy
1.4.3 Preparation of Samples
1.4.4 Data Measurement and Processing
1.5 An Overview of Scientific Methods Applied in Archaeometry and Cultural Heritage Research
1.5.1 Analytical Methods
1.5.2 Dating Methods
References
2 Electrochemical Processes and Techniques
2.1 Introduction
2.2 Voltammetry of Immobilized Microparticles
2.2.1 Voltammetry, General Aspects and Conventions
2.2.2 Solid-State Transformations
2.2.3 Reductive/Oxidative Dissolution Processes
2.2.4 Redox Processes with Phase Changes
2.3 Electrochemical Impedance Spectroscopy
2.3.1 Impedance Measurements and Impedance Spectroscopy
2.3.2 Circuit Elements and Equivalent Circuits
2.4 Other Techniques
2.4.1 Combination with Non-electrochemical Techniques
2.4.2 Scanning Electrochemical Microscopy
2.5 A Note on Thermochemical Calculations
References
3 Voltammetry: The Essentials
3.1 General Aspects
3.2 The Electrochemical Reaction
3.3 Reversible Solution-Phase Voltammetry Under Diffusion Control
3.4 Resistive and Capacitive Effects
3.5 Deviations from Reversibility and Coupled Chemical Reactions
3.6 Voltammetry of Surface-Confined Species
3.7 Voltammetry of Oxidation/Reduction of Ion-Permeable Solids
3.8 Voltammetry of Oxidative/Reductive Dissolution Processes
3.9 Voltammetry of Solid-to-Solid Redox Transformations
3.10 Electrocatalysis
References
4 Analytical Issues
4.1 Generalities
4.2 Identification of Components
4.2.1 Voltammetric Parameters
4.2.2 Tafel-Type Analysis
4.3 Quantification
4.3.1 General Aspects
4.3.2 Voltammetric and Coulometric Quantification Strategies
4.3.3 Standard Addition Methods
4.3.4 Quantification in the Presence of Interferents
4.4 Speciation
4.5 Electrochemical Data Processing
4.5.1 Handling Electrochemical Signals
4.5.2 Bivariant and Multivariant Techniques
References
Series Editors' Foreword
Preface
Contents
About the Authors
About the Series Editors
Abbreviations
1 Application of Instrumental Methods in the Analysis of Historical, Artistic, and Archaeological Objects
1.1 Archaeology and Conservation of Cultural Heritage
1.1.1 Archaeology, Archaeometry, and Archaeological Science
1.1.2 Conservation of Cultural Heritage
1.1.3 A Brief History of the Scientific Analysis of Cultural Heritage
1.2 Role of the Analytical Methods in Archaeometrical and Cultural Heritage Research
1.3 Information Provided by the Analytical Research
1.3.1 Analytical Information Obtained from the Object
1.3.2 Analytical Information Obtained from the Environment
1.3.3 Analytical Information Obtained from the Conservation Processes
1.4 Analytical Methodologies Applied to Archaeometry and Cultural Heritage Research
1.4.1 Requirements of the Analytical Methodologies
1.4.2 Sampling Strategy
1.4.3 Preparation of Samples
1.4.4 Data Measurement and Processing
1.5 An Overview of Scientific Methods Applied in Archaeometry and Cultural Heritage Research
1.5.1 Analytical Methods
1.5.2 Dating Methods
References
2 Electrochemical Processes and Techniques
2.1 Introduction
2.2 Voltammetry of Immobilized Microparticles
2.2.1 Voltammetry, General Aspects and Conventions
2.2.2 Solid-State Transformations
2.2.3 Reductive/Oxidative Dissolution Processes
2.2.4 Redox Processes with Phase Changes
2.3 Electrochemical Impedance Spectroscopy
2.3.1 Impedance Measurements and Impedance Spectroscopy
2.3.2 Circuit Elements and Equivalent Circuits
2.4 Other Techniques
2.4.1 Combination with Non-electrochemical Techniques
2.4.2 Scanning Electrochemical Microscopy
2.5 A Note on Thermochemical Calculations
References
3 Voltammetry: The Essentials
3.1 General Aspects
3.2 The Electrochemical Reaction
3.3 Reversible Solution-Phase Voltammetry Under Diffusion Control
3.4 Resistive and Capacitive Effects
3.5 Deviations from Reversibility and Coupled Chemical Reactions
3.6 Voltammetry of Surface-Confined Species
3.7 Voltammetry of Oxidation/Reduction of Ion-Permeable Solids
3.8 Voltammetry of Oxidative/Reductive Dissolution Processes
3.9 Voltammetry of Solid-to-Solid Redox Transformations
3.10 Electrocatalysis
References
4 Analytical Issues
4.1 Generalities
4.2 Identification of Components
4.2.1 Voltammetric Parameters
4.2.2 Tafel-Type Analysis
4.3 Quantification
4.3.1 General Aspects
4.3.2 Voltammetric and Coulometric Quantification Strategies
4.3.3 Standard Addition Methods
4.3.4 Quantification in the Presence of Interferents
4.4 Speciation
4.5 Electrochemical Data Processing
4.5.1 Handling Electrochemical Signals
4.5.2 Bivariant and Multivariant Techniques
References