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001475949 001__ 1475949
001475949 003__ OCoLC
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001475949 020__ $$a9783031367359
001475949 020__ $$a3031367359
001475949 0247_ $$a10.1007/978-3-031-36735-9$$2doi
001475949 035__ $$aSP(OCoLC)1393308654
001475949 040__ $$aEBLCP$$beng$$cEBLCP$$dGW5XE$$dEBLCP$$dOCLCQ
001475949 049__ $$aISEA
001475949 050_4 $$aQD400
001475949 08204 $$a547/.59$$223/eng/20230815
001475949 24500 $$aHeterocycles from carbenes and nitrenes :$$bmethods, reactions and synthetic applications /$$cMichael P. Doyle, Xinfang Xu, editors.
001475949 260__ $$aCham, Switzerland :$$bSpringer,$$c2023.
001475949 300__ $$a1 online resource (381 p.).
001475949 4901_ $$aTopics in Heterocyclic Chemistry ;$$vvolume 59
001475949 500__ $$aDescription based upon print version of record.
001475949 500__ $$a2 Cyclopropanation of Furans
001475949 5050_ $$aIntro -- Preface -- Contents -- Photo-Induced Carbene Transformations to Heterocycles -- 1 Introduction -- 2 Carbenes for the Photochemical Synthesis of Heterocycles -- 2.1 C-H Insertions Leading to Heterocyclic Scaffolds -- 2.2 O-H Insertions in Heterocycle Synthesis -- 2.3 Photochemically Generated Ylides in Heterocycle Synthesis -- 2.4 Photochemical Wolff Rearrangements and Subsequent Transformations -- 2.5 Light-Induced [2+1]-Cycloadditions Leading to Heterocycle Rings -- 2.6 Carbenes Generated Via Photochemical Brook Rearrangements
001475949 5058_ $$a2.7 Nitrenes as Intermediates in Photochemical Synthesis of Heterocycles -- 2.8 Miscellaneous -- 3 Conclusion -- References -- Heterocycles from Onium Ylides -- 1 Introduction -- 2 Heterocycle Synthesis via Onium Ylides from Diazoalkanes -- 2.1 Ammonium Ylides -- 2.2 Oxonium Ylides -- 2.3 Sulfonium Ylides -- 3 Heterocycle Synthesis via Onium Ylides from Triazoles -- 3.1 Nitrogen-Based Ylides -- 3.2 Oxonium Ylides -- 3.3 Sulfonium Ylides -- 3.4 Selenonium Ylides -- 4 Conclusion -- References -- Heterocycles from Sulfur Ylides -- 1 Introduction
001475949 5058_ $$a2 Heterocycle Synthesis from Sulfur Ylide Mediated by Carbenes -- 2.1 Category 1: Direct Metal-Carbene Formation from Sulfur Ylides -- 2.1.1 Nitrogen Heterocycles -- 2.1.2 Oxygen Heterocycles -- 2.1.3 Sulfur-Containing Heterocycles -- 2.2 Category 2: Metal-Catalyzed C-H Activation Before Metal-Carbene Formation -- 2.2.1 Nitrogen Heterocycles -- 2.2.2 Oxygen Heterocycles -- 2.2.3 Heterocycles Containing Two or More Heteroatoms -- 3 Summary and Outlook -- References -- Heterocycles from Cascade Reactions via Carbene gem-Difunctionalization -- 1 Introduction
001475949 5058_ $$a2 Heterocyclic Skeleton Construction via Intramolecular Cyclization -- 2.1 Heterocyclic Skeleton Construction via Nucleophilic Cyclization -- 2.1.1 Diazo Compounds as Carbene Precursors -- 2.1.2 Alkynes as Carbene Precursors -- 2.1.3 Cyclopropenes as Carbene Precursors -- 2.2 Heterocyclic Skeleton Construction via Electrophilic Cyclization -- 3 Heterocyclic Skeleton Construction via Carbene gem-Difunctionalization -- 3.1 Heterocycles from the Interception of Ammonium Ylides -- 3.2 Heterocycles from the Interception of Oxonium Ylides
001475949 5058_ $$a3.3 Heterocycles from the Interception of Zwitterionic Intermediates -- 3.4 Heterocycles from the Interception of Other Reactive Intermediates -- 3.5 Heterocycles from One-Pot Cyclization Post the Carbene gem-Difunctionalization -- 4 Heterocyclic Skeleton Modification via Carbene gem-Difunctionalization -- 4.1 Modification of Heterocyclic Carbene Precursors -- 4.2 Modification of Heterocyclic Nucleophiles -- 4.3 Modification of Heterocyclic Electrophiles -- 5 Conclusion -- References -- Heterocycles from Cyclopropanation of Five-Membered Heteroarenes -- 1 Introduction
001475949 506__ $$aAccess limited to authorized users.
001475949 520__ $$aThis book provides researchers in the fields of organic chemistry, organometallic chemistry and homogeneous catalysis with an overview of recent developments in the applications of reactions involving carbene and nitrene intermediates directed to the synthesis of heterocyclic compounds. Multiple pathways through which diverse heterocyclic compounds are accessed occur from a variety of carbene and nitrene precursors through C-H/X-H insertions, cycloadditions, ylide transformations, rearrangements, and cascade reactions. Catalytic processes that form metallo-carbenes and nitrenes offer unparalleled chemo-, regio-, and stereo-selectivities. Insights are provided into the scope of these methodologies and the inherent control of catalyst ligands on reaction selectivities.
001475949 588__ $$aOnline resource; title from PDF title page (SpringerLink, viewed August 15, 2023).
001475949 650_0 $$aHeterocyclic compounds.
001475949 650_0 $$aCarbenes (Methylene compounds)
001475949 650_0 $$aNitrenes.
001475949 655_0 $$aElectronic books.
001475949 7001_ $$aDoyle, Michael P.,$$eeditor.
001475949 7001_ $$aXu, Xinfang,$$eeditor.
001475949 77608 $$iPrint version:$$aDoyle, Michael P.$$tHeterocycles from Carbenes and Nitrenes$$dCham : Springer International Publishing AG,c2023$$z9783031367342
001475949 830_0 $$aTopics in heterocyclic chemistry ;$$v59.
001475949 852__ $$bebk
001475949 85640 $$3Springer Nature$$uhttps://univsouthin.idm.oclc.org/login?url=https://link.springer.com/10.1007/978-3-031-36735-9$$zOnline Access$$91397441.1
001475949 909CO $$ooai:library.usi.edu:1475949$$pGLOBAL_SET
001475949 980__ $$aBIB
001475949 980__ $$aEBOOK
001475949 982__ $$aEbook
001475949 983__ $$aOnline
001475949 994__ $$a92$$bISE