001482268 000__ 06517cam\\22006257i\4500
001482268 001__ 1482268
001482268 003__ OCoLC
001482268 005__ 20231128003329.0
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001482268 007__ cr\cn\nnnunnun
001482268 008__ 231007s2023\\\\sz\a\\\\o\\\\\000\0\eng\d
001482268 019__ $$a1401907733$$a1406516478$$a1407320820
001482268 020__ $$a9783031348358$$qelectronic book
001482268 020__ $$a3031348354$$qelectronic book
001482268 020__ $$z3031348346
001482268 020__ $$z9783031348341
001482268 0247_ $$a10.1007/978-3-031-34835-8$$2doi
001482268 035__ $$aSP(OCoLC)1402024699
001482268 040__ $$aEBLCP$$beng$$cEBLCP$$dGW5XE$$dYDX$$dEBLCP$$dSFB$$dYDX$$dOCLCO$$dOCLCF
001482268 049__ $$aISEA
001482268 050_4 $$aQD79.C454$$bL54 2023
001482268 08204 $$a543/.84$$223/eng/20231010
001482268 1001_ $$aMalik, Muhammad Imran,$$eauthor.
001482268 24510 $$aLiquid chromatography of synthetic polymers :$$bentropy/enthalpy compensation and critical conditions /$$cMuhammad Imran Malik, Dusan Berek.
001482268 264_1 $$aCham :$$bSpringer International Publishing AG,$$c2023.
001482268 300__ $$a1 online resource (xx, 296 pages) :$$billustrations (some color).
001482268 336__ $$atext$$btxt$$2rdacontent
001482268 337__ $$acomputer$$bc$$2rdamedia
001482268 338__ $$aonline resource$$bcr$$2rdacarrier
001482268 4901_ $$aPhysical Chemistry in Action Series
001482268 500__ $$a8.5 Limitations and Opportunities
001482268 5050_ $$aIntro -- Foreword -- Preface -- Contents -- Abbreviations -- 1 Polymers and Their Complexity -- References -- 2 Polymers in Solution -- 2.1 Basic Terminology -- 2.2 Solubility of Polymers -- 2.3 Polymers in Solution in Contact with Porous Solid Particles -- 2.3.1 Entropy-Controlled Processes -- 2.3.2 Enthalpy-Affected Processes -- References -- 3 Liquid Chromatography as a Tool for Determination of Distribution of Polymer Molecular Characteristics -- 3.1 Separation Mechanisms in Polymer LC -- 3.2 Theory of Polymer Chromatography -- 3.2.1 Size Exclusion Chromatography (SEC)
001482268 5058_ $$a3.2.2 Interaction Chromatography (IC) or Liquid Adsorption Chromatography (LAC) -- 3.2.3 Liquid Chromatography at Critical Conditions -- 3.3 Thermodynamics of Polymer Chromatography -- References -- 4 Instrumentation for Polymer Liquid Chromatography -- 4.1 Solvent Delivery System and Injector -- 4.2 Columns -- 4.3 Stationary Phases -- 4.3.1 Physical Structure of Stationary Phases -- 4.3.2 Chemical Nature of Stationary Phases -- 4.4 Mobile Phases/Eluents and Sample Solvents -- 4.5 Detectors -- 4.5.1 Concentration Sensitive Detectors -- 4.5.2 Molar Mass Sensitive Detectors -- References
001482268 5058_ $$a5 Non-exclusion Methods of Polymer Liquid Chromatography -- 5.1 Polymer-Mobile Phase Interactions -- 5.1.1 Precipitation-(Re)dissolution Polymer LC -- 5.1.2 Hydrodynamic Chromatography -- 5.1.3 Field-Flow Fractionation -- 5.2 Polymer-Column Packing Interactions -- 5.2.1 Eluent (Mobile Phase) Gradient Interaction Chromatography (EGIC) -- 5.2.2 Full Adsorption-Desorption Polymer LC -- 5.3 Coupled Methods of Polymer Separation -- References -- 6 Conventional Entropy-Controlled Methods of Polymer Liquid Chromatography -- 6.1 Size Exclusion Chromatography
001482268 5058_ $$a6.1.1 Origin and First Stage of Size Exclusion Chromatography -- 6.1.2 Theory of Size Exclusion Chromatography -- 6.1.3 Column Packings, Mobile Phases/Eluents for Size Exclusion Chromatography -- 6.1.4 Relation Between Elution Volume and Polymer Molar Mass in Size Exclusion Chromatography -- 6.1.5 Secondary Effects in Size Exclusion Chromatography -- 6.1.6 Applications of Size Exclusion Chromatography -- 6.1.7 Unwanted Enthalpic Effects in Size Exclusion Chromatography -- 6.2 Exclusion-Interaction Combinations -- References -- 7 Entropy/Enthalpy Compensation in Polymer Liquid Chromatography
001482268 5058_ $$a7.1 History of Entropy/Enthalpy Compensation-The Critical Conditions -- 7.2 Terminology of Polymer LC Based on Entropy/Enthalpy Compensation -- 7.3 Molar Mass Versus Elution Volumes in the Process of Entropy/Enthalpy Compensation -- 7.4 Rational for Polymer Chromatography Based on Entropy/Enthalpy Compensation -- References -- 8 Liquid Chromatography at Critical Conditions -- 8.1 Establishment of Critical Conditions -- 8.2 Sensitivity of Critical Conditions -- 8.3 Working Principle -- 8.4 Applications of LCCC in Polymer Analysis -- 8.4.1 LCCC-SEC -- 8.4.2 LCCC-IC
001482268 506__ $$aAccess limited to authorized users.
001482268 520__ $$aThis book elucidates the peculiar phenomenon of entropy/enthalpy compensation that takes place in high performance liquid chromatography (HPLC) of polymers. Numerous publications, including some books, are devoted to molecular characterization of synthetic polymers, materials presently produced in large and steadily growing quantities, applying methods of HPLC. A knowledge of the molecular characteristics of polymers is indispensable, not only for their proper applications but also for their recycling and remediation. Polymer scientists generally focus on synthesis and potential applications of polymers while not giving due attention to an important central link, their comprehensive characterization in context of development of structure-property correlations. To fill this gap is one of the aims of the present book. The process of entropy/enthalpy compensation plays a decisive role in the advanced method of polymer characterization such as liquid chromatography at critical conditions, eluent gradient interaction chromatography, and temperature gradient interaction chromatography. All chemists working on any aspect of polymer science will find this book a valuable resource for the development of structure-property correlations.
001482268 588__ $$aDescription based on online resource; title from digital title page (viewed on November 06, 2023).
001482268 650_0 $$aLiquid chromatography.
001482268 650_0 $$aPolymers.
001482268 650_6 $$aChromatographie en phase liquide.
001482268 650_6 $$aPolymères.
001482268 655_0 $$aElectronic books.
001482268 7001_ $$aBerek, Dusan,$$eauthor.
001482268 77608 $$iPrint version:$$aMalik, Muhammad Imran$$tLiquid Chromatography of Synthetic Polymers$$dCham : Springer International Publishing AG,c2023$$z9783031348341
001482268 830_0 $$aPhysical chemistry in action.
001482268 852__ $$bebk
001482268 85640 $$3Springer Nature$$uhttps://univsouthin.idm.oclc.org/login?url=https://link.springer.com/10.1007/978-3-031-34835-8$$zOnline Access$$91397441.1
001482268 909CO $$ooai:library.usi.edu:1482268$$pGLOBAL_SET
001482268 980__ $$aBIB
001482268 980__ $$aEBOOK
001482268 982__ $$aEbook
001482268 983__ $$aOnline
001482268 994__ $$a92$$bISE