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Table of Contents
Intro
front-matter
Table of Contents
Preface
1
Multiscale Study of Hydrogen Storage in Metal-Organic Frameworks
1. Introduction
2. DFT study of site characteristics in MOFs for hydrogen adsorption
3. Grand Canonical Monte Carlo (GCMC) for gravimetric and volumetric uptakes
Conclusion
Reference
2
Metal Organic Frameworks Based Materials for Renewable Energy Applications
1. Introduction
2. Need for renewal energy
3. Metal organic frameworks
4. MOFs for environmental applications and renewable energy
5. Metallic organic framework based materials for hydrogen energy applications
6. Hydrogen Storage by MOFs
7. Storage of gases and separation process by MOFs
8. Metal organic frameworks based materials for conversion and storage of CO2
9. Use of MOFs for biogas
10. Storage of thermal energy using MOF materials
11. Metal organic frameworks based materials for oxygen catalysis
12. MOF based materials for rechargeable batteries and supercapacitors
13. Metal organic framework based materials in the use of dye sensitized solar cells
Conclusion
References
3
Metal Organic Frameworks Composites for Lithium Battery Applications
1. Introduction
2. Applications of MOFs in lithium-ion batteries
3. Applications of MOFs in lithium sulphur batteries.
4. Summary and outlook
References
4
Metal-Organic-Framework-Quantum Dots (QD@MOF) Composites
1. Introduction
1.1 Metal-organic frameworks
1.2 Quantum dots
1.3 Gold QDs (AuQDs)
2. QD polymeric materials
2.1 Integration of QDs
2.2 Methods of encapsulating QD to polymer matrices
2.3 Incorporation into premade polymers
2.4 Suspension polymerization
2.5 Encapsulation via emulsion polymerization
2.6 Encapsulation via miniemulsion polymerization
3. QD hybrid materials.
3.1 Strategies to generate QD hybrid materials
3.2 Exchanging ligand between polymer and QDs
3.3 Polymer grafting to QDs
3.4 Polymer grafting from QDs
3.5 Polymer capping into QDs
3.6 QDs growth within polymer
3.7 Challenges in biocompatible polymer/QDs
4. Applications of QD composites
4.1 Bio-imaging
4.2 Photo-thermal therapies
4.3 Opto-electric applications
4.3.1 QD LEDs
4.3.2 Polymer QD liquid crystal displays
4.3.3 QD polymer photo-voltaic devices
5. Metallic NCs
5.1 Classification of metallic NCs
5.2 Production of metallic NCs
5.2.1 Metallic NCs synthesis methods
5.3 Applications of metallic nano-particles
5.3.1 Silver NCs
5.3.2 Pbs QDs
Conclusion
References
5
Designing Metal-Organic-Framework for Clean Energy Applications
1. Introduction
1.1 Introduction to MOF Composites &
Derivatives
1.2 Chemistry of MOFs
2. Applications of MOF in clean energy
2.1 Hydrogen Storage
2.2 Carbon dioxide capture
2.3 Methane storage
2.4 Electrical energy storage and conversion
2.4.1 Fuel cell
2.5 MOFs for supercapacitor applications
2.6 NH3 removal
2.7 Benzene removal
2.8 NO2 removal
2.9 Photocatalysis
Conclusion
References
6
Nanoporous Metal-Organic-Framework
1. Introduction
1.1 Fundamental stabilities of nano MOFs
1.1.1 Chemical stability
1.1.2 In water medium
1.1.3 In acid/base condition
1.1.4 Thermal Stability
1.1.5 Mechanical Stability
1.2 Synthesis
1.2.1 Modulated synthesis
1.2.2 Post-synthetic modification (PSM)
1.3 Applications of MOFs
1.3.1 Gas separations and storage
1.3.2 Catalysis
1.3.2.1 Lewis acid catalysis
1.3.2.2 Bronsted acid catalysis
1.3.2.3 Redox Catalysis
1.3.2.4 Photocatalysis
1.3.2.5 Electrocatalysis
1.3.3 Water treatment
1.4 Other applications.
1.4.1 Sensors
1.4.2 Supercapacitors
1.4.3 Biomedical applications
Conclusion
References
7
Metal-Organic-Framework-Based Materials for Energy Applications
1. Introduction
1.1 Role of MOF in supercapacitor
1.2 Role of MOF in oxygen evolution reaction (OER)
2. Synthesis of Ni3(HITP)2 MOF
3. Characterization of Ni3(HITP)2 MOF
4. Ni3(HITP)2MOF as supercapacitor electrode for EDLC :
5. Two electrode measurements
6. Electrochemical impedance (EIS) measurements
7. Device performance
8. Hybrid Co3O4C nanowires electrode for OER process
9. Synthesis of hybrid Co3O4C nanowires
10. Characterization of hybrid Co3O4C nanowires
11. Hybrid Co3O4C nanowires MOF electrode for oxygen evolution reaction
Conclusion
References
8
Metal-Organic-Framework Composites as Proficient Cathodes for Supercapacitor Applications
1. Introduction
2. MOFs: Structure, properties and strategies for SCs
3. Single-metal MOFs
4. Bimetal or doped MOFs
5. Hybrids and composites
6. Flexible or freestanding SCs
Conclusion and Perspectives
References
9
Metal-Organic Frameworks and their Therapeutic Applications
1. Introduction
2. Metal-organic frameworks
2.1 Usage areas of metal-organic frameworks
2.1.1 Controlled drug release
2.1.2 Antibacterial activity of MOFs
2.1.3 Biomedicine
2.1.4 Chemical sensors
Conclusions and recommendations
References
10
Significance of Metal Organic Frameworks Consisting of Porous Materials
1. Introduction
1.1 Definition of porosity
2. Inferences obtained from the wide range of relevant research articles
2.1 Introduction to porous MOFs
2.2 Zeolites - an amorphous &
inorganic porous material
2.3 Activated carbon - an organic porous material
2.4 Formation of pores in MOFs
2.5 Types of pores.
2.6 Characterization of porous MOFs
2.7 Checking for permanent porosity
2.8 Advantages of MOF porous materials
2.9 Porous MOFs in separation of gases
2.10 Nanoporous MOFs
Conclusion
References
11
Metal Organic Frameworks (MOF's) for Biosensing and Bioimaging Applications
1. Introduction
2. In vitro MOF complex sensors
2.1 DNA-RNA-MOF complex sensor
2.2 Enzyme-MOF complex
2.2.1 Enzymatic-MOF complex
2.2.2 Non-enzymatic-MOF complex
2.3 Fluorescent-MOF complex
3. In-vivo MOF complex sensors
3.1 MR complex
3.2 CT complex
Conclusions and recommendations
References
12
Nanoscale Metal Organic Framework for Phototherapy of Cancer
1. Introduction
2. Nanoscience and nanotechnology
2.1 Tumor ablation and nanotechnology in cancer treatment
3. Metal organic frameworks (MOFs)
4. Photothermal therapy (PTT)
5. Photodynamic therapy (PDT)
6. Historical development of phototherapy
7. Mechanism of phototherapy
7.1 Basic elements of photodynamic therapy
7.1.1 Singlet oxygen
7.1.2 Light sources
8. Photosensitizers (PSs)
8.1 First generation photosensitizers
8.2 Second generation photosensitizers
8.3 Third generation photosensitizers
8.4 Introduction of tumor cells and intracellular localization of photosensitizer
9. Cell death in phototherapy
10. nMOFs for PDT
11. nMOFs for PTT
11.1 Surface plasmon resonance (SPR) mechanism and plasmonic photothermal treatment (PPTT) method
11.1.1 Mie theory
11.1.2 Gold nanostructures
11.1.3 Photothermal properties of different gold nanostructures
11.1.4 Gold nanospheres used in photothermal therapy
11.1.5 Gold nanocages and nanorods used in photothermal therapy
11.1.6 Bioconjugation of gold nanostructures used in photothermal therapy
11.1.7 Determination of temperature changes in gold surface.
12. Results and Perspectives
References
back-matter
Keyword Index
About the Editors.
front-matter
Table of Contents
Preface
1
Multiscale Study of Hydrogen Storage in Metal-Organic Frameworks
1. Introduction
2. DFT study of site characteristics in MOFs for hydrogen adsorption
3. Grand Canonical Monte Carlo (GCMC) for gravimetric and volumetric uptakes
Conclusion
Reference
2
Metal Organic Frameworks Based Materials for Renewable Energy Applications
1. Introduction
2. Need for renewal energy
3. Metal organic frameworks
4. MOFs for environmental applications and renewable energy
5. Metallic organic framework based materials for hydrogen energy applications
6. Hydrogen Storage by MOFs
7. Storage of gases and separation process by MOFs
8. Metal organic frameworks based materials for conversion and storage of CO2
9. Use of MOFs for biogas
10. Storage of thermal energy using MOF materials
11. Metal organic frameworks based materials for oxygen catalysis
12. MOF based materials for rechargeable batteries and supercapacitors
13. Metal organic framework based materials in the use of dye sensitized solar cells
Conclusion
References
3
Metal Organic Frameworks Composites for Lithium Battery Applications
1. Introduction
2. Applications of MOFs in lithium-ion batteries
3. Applications of MOFs in lithium sulphur batteries.
4. Summary and outlook
References
4
Metal-Organic-Framework-Quantum Dots (QD@MOF) Composites
1. Introduction
1.1 Metal-organic frameworks
1.2 Quantum dots
1.3 Gold QDs (AuQDs)
2. QD polymeric materials
2.1 Integration of QDs
2.2 Methods of encapsulating QD to polymer matrices
2.3 Incorporation into premade polymers
2.4 Suspension polymerization
2.5 Encapsulation via emulsion polymerization
2.6 Encapsulation via miniemulsion polymerization
3. QD hybrid materials.
3.1 Strategies to generate QD hybrid materials
3.2 Exchanging ligand between polymer and QDs
3.3 Polymer grafting to QDs
3.4 Polymer grafting from QDs
3.5 Polymer capping into QDs
3.6 QDs growth within polymer
3.7 Challenges in biocompatible polymer/QDs
4. Applications of QD composites
4.1 Bio-imaging
4.2 Photo-thermal therapies
4.3 Opto-electric applications
4.3.1 QD LEDs
4.3.2 Polymer QD liquid crystal displays
4.3.3 QD polymer photo-voltaic devices
5. Metallic NCs
5.1 Classification of metallic NCs
5.2 Production of metallic NCs
5.2.1 Metallic NCs synthesis methods
5.3 Applications of metallic nano-particles
5.3.1 Silver NCs
5.3.2 Pbs QDs
Conclusion
References
5
Designing Metal-Organic-Framework for Clean Energy Applications
1. Introduction
1.1 Introduction to MOF Composites &
Derivatives
1.2 Chemistry of MOFs
2. Applications of MOF in clean energy
2.1 Hydrogen Storage
2.2 Carbon dioxide capture
2.3 Methane storage
2.4 Electrical energy storage and conversion
2.4.1 Fuel cell
2.5 MOFs for supercapacitor applications
2.6 NH3 removal
2.7 Benzene removal
2.8 NO2 removal
2.9 Photocatalysis
Conclusion
References
6
Nanoporous Metal-Organic-Framework
1. Introduction
1.1 Fundamental stabilities of nano MOFs
1.1.1 Chemical stability
1.1.2 In water medium
1.1.3 In acid/base condition
1.1.4 Thermal Stability
1.1.5 Mechanical Stability
1.2 Synthesis
1.2.1 Modulated synthesis
1.2.2 Post-synthetic modification (PSM)
1.3 Applications of MOFs
1.3.1 Gas separations and storage
1.3.2 Catalysis
1.3.2.1 Lewis acid catalysis
1.3.2.2 Bronsted acid catalysis
1.3.2.3 Redox Catalysis
1.3.2.4 Photocatalysis
1.3.2.5 Electrocatalysis
1.3.3 Water treatment
1.4 Other applications.
1.4.1 Sensors
1.4.2 Supercapacitors
1.4.3 Biomedical applications
Conclusion
References
7
Metal-Organic-Framework-Based Materials for Energy Applications
1. Introduction
1.1 Role of MOF in supercapacitor
1.2 Role of MOF in oxygen evolution reaction (OER)
2. Synthesis of Ni3(HITP)2 MOF
3. Characterization of Ni3(HITP)2 MOF
4. Ni3(HITP)2MOF as supercapacitor electrode for EDLC :
5. Two electrode measurements
6. Electrochemical impedance (EIS) measurements
7. Device performance
8. Hybrid Co3O4C nanowires electrode for OER process
9. Synthesis of hybrid Co3O4C nanowires
10. Characterization of hybrid Co3O4C nanowires
11. Hybrid Co3O4C nanowires MOF electrode for oxygen evolution reaction
Conclusion
References
8
Metal-Organic-Framework Composites as Proficient Cathodes for Supercapacitor Applications
1. Introduction
2. MOFs: Structure, properties and strategies for SCs
3. Single-metal MOFs
4. Bimetal or doped MOFs
5. Hybrids and composites
6. Flexible or freestanding SCs
Conclusion and Perspectives
References
9
Metal-Organic Frameworks and their Therapeutic Applications
1. Introduction
2. Metal-organic frameworks
2.1 Usage areas of metal-organic frameworks
2.1.1 Controlled drug release
2.1.2 Antibacterial activity of MOFs
2.1.3 Biomedicine
2.1.4 Chemical sensors
Conclusions and recommendations
References
10
Significance of Metal Organic Frameworks Consisting of Porous Materials
1. Introduction
1.1 Definition of porosity
2. Inferences obtained from the wide range of relevant research articles
2.1 Introduction to porous MOFs
2.2 Zeolites - an amorphous &
inorganic porous material
2.3 Activated carbon - an organic porous material
2.4 Formation of pores in MOFs
2.5 Types of pores.
2.6 Characterization of porous MOFs
2.7 Checking for permanent porosity
2.8 Advantages of MOF porous materials
2.9 Porous MOFs in separation of gases
2.10 Nanoporous MOFs
Conclusion
References
11
Metal Organic Frameworks (MOF's) for Biosensing and Bioimaging Applications
1. Introduction
2. In vitro MOF complex sensors
2.1 DNA-RNA-MOF complex sensor
2.2 Enzyme-MOF complex
2.2.1 Enzymatic-MOF complex
2.2.2 Non-enzymatic-MOF complex
2.3 Fluorescent-MOF complex
3. In-vivo MOF complex sensors
3.1 MR complex
3.2 CT complex
Conclusions and recommendations
References
12
Nanoscale Metal Organic Framework for Phototherapy of Cancer
1. Introduction
2. Nanoscience and nanotechnology
2.1 Tumor ablation and nanotechnology in cancer treatment
3. Metal organic frameworks (MOFs)
4. Photothermal therapy (PTT)
5. Photodynamic therapy (PDT)
6. Historical development of phototherapy
7. Mechanism of phototherapy
7.1 Basic elements of photodynamic therapy
7.1.1 Singlet oxygen
7.1.2 Light sources
8. Photosensitizers (PSs)
8.1 First generation photosensitizers
8.2 Second generation photosensitizers
8.3 Third generation photosensitizers
8.4 Introduction of tumor cells and intracellular localization of photosensitizer
9. Cell death in phototherapy
10. nMOFs for PDT
11. nMOFs for PTT
11.1 Surface plasmon resonance (SPR) mechanism and plasmonic photothermal treatment (PPTT) method
11.1.1 Mie theory
11.1.2 Gold nanostructures
11.1.3 Photothermal properties of different gold nanostructures
11.1.4 Gold nanospheres used in photothermal therapy
11.1.5 Gold nanocages and nanorods used in photothermal therapy
11.1.6 Bioconjugation of gold nanostructures used in photothermal therapy
11.1.7 Determination of temperature changes in gold surface.
12. Results and Perspectives
References
back-matter
Keyword Index
About the Editors.