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Intro
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The effect which now bears his name was discovered in 1958 by Rudolf M&
#x000F6
ssbauer at the Technical University of Munich. At first, this appeared to be a phenomenon related to nuclear energy levels that provided some information about excited state lifetimes and quantum properties. However, it soon became apparent that M&
#x000F6
ssbauer spectroscopy had applications in such diverse fields as general relativity, solid state physics, chemistry, materials scienc
Acknowledgments
Author biography
Richard A Dunlap
Chapter The history of resonance fluorescence
1.1 Introduction
1.2 Atomic resonance fluorescence
1.3 The Heisenberg linewidth and recoil energy
1.4 The early history of nuclear resonance fluorescence
1.5 Problems
Bibliography and suggestions for further reading
Chapter The Mössbauer effect
2.1 Introduction
2.2 Discovery of the Mössbauer effect
2.3 More about the Mössbauer effect
2.4 Choice of a Mössbauer transition
2.5 Properties of 57Fe
2.6 Properties of 119Sn
2.7 Other common Mössbauer nuclides
2.8 Problems
Bibliography and suggestions for further reading
Chapter Properties of the nucleus
3.1 Introduction
3.2 Nuclear quantum numbers
3.3 Electromagnetic multipole moments of the nucleus
Bibliography and suggestions for further reading
Chapter Hyperfine interactions-part I: the electric monopole interaction and the chemical isomer shift
4.1 Introduction
4.2 The electric monopole interaction
4.3 The chemical isomer shift
4.4 The second order Doppler shift
Bibliography and suggestions for further reading
Chapter Hyperfine interactions-part II: the electric quadrupole interaction
5.1 Introduction
5.2 The electric quadrupole interaction.
5.3 Quadrupole splitting of Mössbauer spectra
5.4 Intensity of absorption lines
Bibliography and suggestions for further reading
Chapter Magnetic properties of materials
6.1 Introduction
6.2 Paramagnetic materials
6.3 Ferromagnetic materials and mean field theory
6.4 Antiferromagnetic materials
6.5 Ferrimagnetic materials
Bibliography and suggestions for further reading
Chapter Hyperfine interactions-part III: the magnetic dipole interaction and the nuclear Zeeman effect
7.1 Introduction
7.2 The magnetic dipole interaction
7.3 Zeeman splitting of Mössbauer spectra
7.4 Intensity of absorption lines
7.5 Combined hyperfine interactions
7.6 Problems
Bibliography and suggestions for further reading
Chapter Experimental aspects of Mössbauer spectroscopy
8.1 Introduction
8.2 Mössbauer spectroscopy drive system
8.3 Gamma-ray spectroscopy
8.4 Data accumulation
8.5 Velocity calibration
8.6 Data analysis
8.7 Temperature control
8.8 Transmission and backscatter geometries
8.9 Internal conversion electron Mössbauer spectroscopy
Bibliography and suggestions for further reading
Chapter Applications of Mössbauer spectroscopy to physics, chemistry and materials science
9.1 Introduction
9.2 General relativity
9.3 Magnetic ordering studies
9.4 Crystallographic structure studies
9.5 Hyperfine field distributions
9.5.1 Studies of Fe- and Sn-containing alloys
9.5.2 Studies of the effects of neutron irradiation
9.6 Impurity studies
9.6.1 MFe alloys
9.6.2 FeM alloys
9.7 Surface studies
9.8 Studies of battery materials
Bibliography and suggestions for further reading
Chapter Applications of Mössbauer spectroscopy to other fields
10.1 Introduction
10.2 Mineralogical studies
10.3 Studies of natural glasses.
10.4 Investigations of extraterrestrial materials
10.4.1 Meteorite studies
10.4.2 Studies of lunar samples
10.4.3 In situ studies of Martian samples
10.5 Archaeological studies
10.5.1 Obsidians
10.5.2 Pottery
10.5.3 Metals
10.6 Biological studies
10.7 Counterfeit currency detection
Bibliography and suggestions for further reading
Chapter Ion implantation and synchrotron radiation-based Mössbauer studies
11.1 Introduction
11.2 Ion implantation studies
11.3 Off-line Mössbauer spectroscopy
11.4 On-line Mössbauer spectroscopy
11.5 In-beam Mössbauer spectroscopy
11.6 Fundamentals of synchrotron radiation
11.7 Synchrotron radiation-based Mössbauer techniques
11.8 Time domain synchrotron Mössbauer spectroscopy
11.9 Energy domain synchrotron Mössbauer spectroscopy
Bibliography and suggestions for further reading.
<
named-book-part-body&
#62
<
p&
#62
The effect which now bears his name was discovered in 1958 by Rudolf M&
#x000F6
ssbauer at the Technical University of Munich. At first, this appeared to be a phenomenon related to nuclear energy levels that provided some information about excited state lifetimes and quantum properties. However, it soon became apparent that M&
#x000F6
ssbauer spectroscopy had applications in such diverse fields as general relativity, solid state physics, chemistry, materials scienc
Acknowledgments
Author biography
Richard A Dunlap
Chapter The history of resonance fluorescence
1.1 Introduction
1.2 Atomic resonance fluorescence
1.3 The Heisenberg linewidth and recoil energy
1.4 The early history of nuclear resonance fluorescence
1.5 Problems
Bibliography and suggestions for further reading
Chapter The Mössbauer effect
2.1 Introduction
2.2 Discovery of the Mössbauer effect
2.3 More about the Mössbauer effect
2.4 Choice of a Mössbauer transition
2.5 Properties of 57Fe
2.6 Properties of 119Sn
2.7 Other common Mössbauer nuclides
2.8 Problems
Bibliography and suggestions for further reading
Chapter Properties of the nucleus
3.1 Introduction
3.2 Nuclear quantum numbers
3.3 Electromagnetic multipole moments of the nucleus
Bibliography and suggestions for further reading
Chapter Hyperfine interactions-part I: the electric monopole interaction and the chemical isomer shift
4.1 Introduction
4.2 The electric monopole interaction
4.3 The chemical isomer shift
4.4 The second order Doppler shift
Bibliography and suggestions for further reading
Chapter Hyperfine interactions-part II: the electric quadrupole interaction
5.1 Introduction
5.2 The electric quadrupole interaction.
5.3 Quadrupole splitting of Mössbauer spectra
5.4 Intensity of absorption lines
Bibliography and suggestions for further reading
Chapter Magnetic properties of materials
6.1 Introduction
6.2 Paramagnetic materials
6.3 Ferromagnetic materials and mean field theory
6.4 Antiferromagnetic materials
6.5 Ferrimagnetic materials
Bibliography and suggestions for further reading
Chapter Hyperfine interactions-part III: the magnetic dipole interaction and the nuclear Zeeman effect
7.1 Introduction
7.2 The magnetic dipole interaction
7.3 Zeeman splitting of Mössbauer spectra
7.4 Intensity of absorption lines
7.5 Combined hyperfine interactions
7.6 Problems
Bibliography and suggestions for further reading
Chapter Experimental aspects of Mössbauer spectroscopy
8.1 Introduction
8.2 Mössbauer spectroscopy drive system
8.3 Gamma-ray spectroscopy
8.4 Data accumulation
8.5 Velocity calibration
8.6 Data analysis
8.7 Temperature control
8.8 Transmission and backscatter geometries
8.9 Internal conversion electron Mössbauer spectroscopy
Bibliography and suggestions for further reading
Chapter Applications of Mössbauer spectroscopy to physics, chemistry and materials science
9.1 Introduction
9.2 General relativity
9.3 Magnetic ordering studies
9.4 Crystallographic structure studies
9.5 Hyperfine field distributions
9.5.1 Studies of Fe- and Sn-containing alloys
9.5.2 Studies of the effects of neutron irradiation
9.6 Impurity studies
9.6.1 MFe alloys
9.6.2 FeM alloys
9.7 Surface studies
9.8 Studies of battery materials
Bibliography and suggestions for further reading
Chapter Applications of Mössbauer spectroscopy to other fields
10.1 Introduction
10.2 Mineralogical studies
10.3 Studies of natural glasses.
10.4 Investigations of extraterrestrial materials
10.4.1 Meteorite studies
10.4.2 Studies of lunar samples
10.4.3 In situ studies of Martian samples
10.5 Archaeological studies
10.5.1 Obsidians
10.5.2 Pottery
10.5.3 Metals
10.6 Biological studies
10.7 Counterfeit currency detection
Bibliography and suggestions for further reading
Chapter Ion implantation and synchrotron radiation-based Mössbauer studies
11.1 Introduction
11.2 Ion implantation studies
11.3 Off-line Mössbauer spectroscopy
11.4 On-line Mössbauer spectroscopy
11.5 In-beam Mössbauer spectroscopy
11.6 Fundamentals of synchrotron radiation
11.7 Synchrotron radiation-based Mössbauer techniques
11.8 Time domain synchrotron Mössbauer spectroscopy
11.9 Energy domain synchrotron Mössbauer spectroscopy
Bibliography and suggestions for further reading.