Linked e-resources
Details
Table of Contents
Intro
<
named-book-part-body&
#62
<
p&
#62
Diamane, its derivatives, and two-dimensional (2D) diamond stand at the forefront of materials innovation, poised to reshape a multitude of industries. While diamane remains in its nascent stages of development, it has already exhibited remarkable potential across a diverse spectrum of applications. From automotive engineering to textiles, from flexible electronics to cutting-edge optoelectronics, from the realm of quantum electronics to solar cells, supercapacit
Acknowledgements
Editor biographies
Santosh K Tiwari
Arpan Kumar Nayak
List of contributors
Chapter Introduction to different types of 2D carbon and nanodiamond
1.1 Introduction
1.2 Graphene
1.2.1 Definition and structure
1.2.2 Properties of graphene
1.2.3 Synthesis methods
1.2.4 Applications of graphene
1.2.5 Introduction to graphene oxide
1.2.6 Structure and properties
1.2.7 Synthesis approaches
1.2.8 Functionalization of graphene oxide
1.2.9 Applications of graphene oxide
1.3 Carbon nanotubes
1.3.1 Introduction to carbon nanotubes
1.3.2 Structure and types of CNTs
1.3.3 Properties of CNTs
1.3.4 Synthesis methods
1.3.5 Applications of carbon nanotubes
1.3.6 Introduction to nanodiamond
1.3.7 Structure and properties
1.3.8 Synthesis methods
1.4 Properties of nanodiamond
1.4.1 Dopants and defects
1.4.2 Morphology
1.4.3 Optical properties
1.4.4 Toxicity and biocompatibility of nanodiamonds
1.5 Applications of nanodiamond
1.5.1 Photovoltaic devices
1.5.2 Thin film electronics
1.5.3 Energy storage devices
1.5.4 Electrochemical sensors
1.5.5 Drug delivery
1.5.6 Other applications
1.6 Conclusions and future prospects
References
Chapter Structural and physical properties of diamanes.
2.1 Introduction
2.2 Critical influencing parameters
2.2.1 Functional groups
2.2.2 Number of layers
2.2.3 Stacking sequence
2.2.4 Conformation
2.2.5 Stability
2.3 Physical properties
2.3.1 Electrical properties
2.3.2 Thermal conductivity
2.3.3 Optical properties
2.4 Structural properties
2.5 Conclusion
References
Chapter Synthetic approaches for diamane
3.1 Introduction
3.2 Synthesis of diamane
3.2.1 Fluorination
3.2.2 Hydrogenation
3.2.3 Birch reduction
3.2.4 Chemical vapor deposition
3.2.5 Use of pressure
3.2.6 Substitution by nitrogen
References
Chapter Role of temperature and pressure in the fabrication of diamane and its derivative
4.1 Introduction
4.2 Early works on diamane
4.3 Overview of diamane and diamanoids
4.4 Structure of diamane
4.5 Derivatives of diamane
4.5.1 From graphene and their derivatives
4.5.2 Hydrogenated and hydroxylated diamane
4.5.3 Fluorinated diamane
4.5.4 Pristine diamane
4.6 Thermodynamics of pristine diamane
4.7 Role of temperature in fabrication of diamane and its derivatives
4.8 Role of pressure in fabrication of diamane and its derivatives
4.9 Conclusions
Acknowledgments
Declaration of competing interest
References
Chapter Moiré diamanes through fluorination and hydrogenation
5.1 Introduction
5.2 Structure of moiré diamanes
5.3 Synthesis of moiré diamane
5.4 Properties of moiré diamane
5.4.1 Mechanical properties
5.4.2 Electrical properties
5.4.3 Optical properties
5.4.4 Magnetic properties
5.4.5 Thermal properties
5.5 Applications of moiré diamane
5.6 Conclusion and future scope
References
Chapter Properties of diamane anchored with different groups
6.1 Introduction
6.2 Overview of diamane
6.2.1 Structure of diamane.
6.3 Brief synthesis techniques of diamane
6.3.1 Chemical vapor deposition technique
6.3.2 Hydrogenation
6.3.3 Fluorination
6.3.4 By using pressure
6.4 Properties of diamane
6.4.1 Thermal and mechanical properties
6.4.2 Optical properties
6.4.3 Electronic properties
6.5 Future perspectives
6.6 Conclusions
References
Chapter Diamanoids and diamane oxide synthesis and properties: an overview
7.1 Introduction
7.2 Diamanoids
7.2.1 Early works
7.2.2 Structure of diamanoids
7.3 Diamane oxide
7.3.1 Early works
7.3.2 Structure
7.4 Properties
7.4.1 Properties of diamanoids
7.4.2 Diamane oxide
7.5 Synthesis
7.5.1 Method of diamanoid synthesis
7.5.2 Diamane oxide
7.6 Future scope
7.7 Concluding remarks
References
Chapter Synthesis, properties, and overview of nanodiamonds
8.1 Introduction
8.2 Synthesis of nanodiamonds
8.2.1 Hydrothermal synthesis
8.2.2 Chemical vapor deposition synthesis
8.2.3 Detonation synthesis
8.2.4 Laser ablation synthesis
8.2.5 Ultrasound synthesis
8.2.6 Electrochemical synthesis
8.3 Properties of nanodiamond
8.3.1 Mechanical properties
8.3.2 Optical properties
8.3.3 Electrical properties
8.3.4 Chemical properties
8.4 Overview of nanodiamonds
References
Chapter DFT studies of diamane and 2D diamonds: properties and applications
9.1 Introduction
9.2 Theoretical framework: DFT
9.2.1 Fundamentals of DFT and its key principles
9.2.2 Mathematical formulation of DFT
9.2.3 Computational methods for DFT calculations
9.3 Properties of diamane and 2D diamonds
9.3.1 Structural properties
9.3.2 Mechanical and thermal properties
9.3.3 Optical and vibrational properties
9.4 Applications of diamane and 2D diamonds
9.4.1 Electronic and optoelectronic devices.
9.4.2 Energy storage and conversion
9.4.3 Catalysis and chemical sensing
9.4.4 Biomedical and environmental applications
9.5 Challenges and future directions
9.6 Conclusion
References
Chapter Fine-tuning fabrication parameters for high-grade diamane and derivatives
10.1 Introduction
10.2 High-pressure synthesis techniques
10.2.1 Theoretical high-pressure synthesis methods
10.2.2 Diamond anvil cell technique
10.2.3 High-pressure high-temperature techniques
10.3 Temperature effects on fabrication
10.3.1 Impact of temperature on diamond formation
10.3.2 Thermodynamics of carbon conversion
10.3.3 Temperature ranges for successful synthesis of diamane
10.4 Pressure effects on fabrication
10.4.1 Role of pressure in carbon rearrangement
10.4.2 Pressure requirements for diamane synthesis
10.5 Applications of diamane and derivatives
10.5.1 Overview of potential applications
10.5.2 Electronics and optoelectronics
10.5.3 Energy storage and conversion
10.5.4 Biomedical and sensing applications
10.6 Challenges and future directions
10.7 Conclusion
References.
<
named-book-part-body&
#62
<
p&
#62
Diamane, its derivatives, and two-dimensional (2D) diamond stand at the forefront of materials innovation, poised to reshape a multitude of industries. While diamane remains in its nascent stages of development, it has already exhibited remarkable potential across a diverse spectrum of applications. From automotive engineering to textiles, from flexible electronics to cutting-edge optoelectronics, from the realm of quantum electronics to solar cells, supercapacit
Acknowledgements
Editor biographies
Santosh K Tiwari
Arpan Kumar Nayak
List of contributors
Chapter Introduction to different types of 2D carbon and nanodiamond
1.1 Introduction
1.2 Graphene
1.2.1 Definition and structure
1.2.2 Properties of graphene
1.2.3 Synthesis methods
1.2.4 Applications of graphene
1.2.5 Introduction to graphene oxide
1.2.6 Structure and properties
1.2.7 Synthesis approaches
1.2.8 Functionalization of graphene oxide
1.2.9 Applications of graphene oxide
1.3 Carbon nanotubes
1.3.1 Introduction to carbon nanotubes
1.3.2 Structure and types of CNTs
1.3.3 Properties of CNTs
1.3.4 Synthesis methods
1.3.5 Applications of carbon nanotubes
1.3.6 Introduction to nanodiamond
1.3.7 Structure and properties
1.3.8 Synthesis methods
1.4 Properties of nanodiamond
1.4.1 Dopants and defects
1.4.2 Morphology
1.4.3 Optical properties
1.4.4 Toxicity and biocompatibility of nanodiamonds
1.5 Applications of nanodiamond
1.5.1 Photovoltaic devices
1.5.2 Thin film electronics
1.5.3 Energy storage devices
1.5.4 Electrochemical sensors
1.5.5 Drug delivery
1.5.6 Other applications
1.6 Conclusions and future prospects
References
Chapter Structural and physical properties of diamanes.
2.1 Introduction
2.2 Critical influencing parameters
2.2.1 Functional groups
2.2.2 Number of layers
2.2.3 Stacking sequence
2.2.4 Conformation
2.2.5 Stability
2.3 Physical properties
2.3.1 Electrical properties
2.3.2 Thermal conductivity
2.3.3 Optical properties
2.4 Structural properties
2.5 Conclusion
References
Chapter Synthetic approaches for diamane
3.1 Introduction
3.2 Synthesis of diamane
3.2.1 Fluorination
3.2.2 Hydrogenation
3.2.3 Birch reduction
3.2.4 Chemical vapor deposition
3.2.5 Use of pressure
3.2.6 Substitution by nitrogen
References
Chapter Role of temperature and pressure in the fabrication of diamane and its derivative
4.1 Introduction
4.2 Early works on diamane
4.3 Overview of diamane and diamanoids
4.4 Structure of diamane
4.5 Derivatives of diamane
4.5.1 From graphene and their derivatives
4.5.2 Hydrogenated and hydroxylated diamane
4.5.3 Fluorinated diamane
4.5.4 Pristine diamane
4.6 Thermodynamics of pristine diamane
4.7 Role of temperature in fabrication of diamane and its derivatives
4.8 Role of pressure in fabrication of diamane and its derivatives
4.9 Conclusions
Acknowledgments
Declaration of competing interest
References
Chapter Moiré diamanes through fluorination and hydrogenation
5.1 Introduction
5.2 Structure of moiré diamanes
5.3 Synthesis of moiré diamane
5.4 Properties of moiré diamane
5.4.1 Mechanical properties
5.4.2 Electrical properties
5.4.3 Optical properties
5.4.4 Magnetic properties
5.4.5 Thermal properties
5.5 Applications of moiré diamane
5.6 Conclusion and future scope
References
Chapter Properties of diamane anchored with different groups
6.1 Introduction
6.2 Overview of diamane
6.2.1 Structure of diamane.
6.3 Brief synthesis techniques of diamane
6.3.1 Chemical vapor deposition technique
6.3.2 Hydrogenation
6.3.3 Fluorination
6.3.4 By using pressure
6.4 Properties of diamane
6.4.1 Thermal and mechanical properties
6.4.2 Optical properties
6.4.3 Electronic properties
6.5 Future perspectives
6.6 Conclusions
References
Chapter Diamanoids and diamane oxide synthesis and properties: an overview
7.1 Introduction
7.2 Diamanoids
7.2.1 Early works
7.2.2 Structure of diamanoids
7.3 Diamane oxide
7.3.1 Early works
7.3.2 Structure
7.4 Properties
7.4.1 Properties of diamanoids
7.4.2 Diamane oxide
7.5 Synthesis
7.5.1 Method of diamanoid synthesis
7.5.2 Diamane oxide
7.6 Future scope
7.7 Concluding remarks
References
Chapter Synthesis, properties, and overview of nanodiamonds
8.1 Introduction
8.2 Synthesis of nanodiamonds
8.2.1 Hydrothermal synthesis
8.2.2 Chemical vapor deposition synthesis
8.2.3 Detonation synthesis
8.2.4 Laser ablation synthesis
8.2.5 Ultrasound synthesis
8.2.6 Electrochemical synthesis
8.3 Properties of nanodiamond
8.3.1 Mechanical properties
8.3.2 Optical properties
8.3.3 Electrical properties
8.3.4 Chemical properties
8.4 Overview of nanodiamonds
References
Chapter DFT studies of diamane and 2D diamonds: properties and applications
9.1 Introduction
9.2 Theoretical framework: DFT
9.2.1 Fundamentals of DFT and its key principles
9.2.2 Mathematical formulation of DFT
9.2.3 Computational methods for DFT calculations
9.3 Properties of diamane and 2D diamonds
9.3.1 Structural properties
9.3.2 Mechanical and thermal properties
9.3.3 Optical and vibrational properties
9.4 Applications of diamane and 2D diamonds
9.4.1 Electronic and optoelectronic devices.
9.4.2 Energy storage and conversion
9.4.3 Catalysis and chemical sensing
9.4.4 Biomedical and environmental applications
9.5 Challenges and future directions
9.6 Conclusion
References
Chapter Fine-tuning fabrication parameters for high-grade diamane and derivatives
10.1 Introduction
10.2 High-pressure synthesis techniques
10.2.1 Theoretical high-pressure synthesis methods
10.2.2 Diamond anvil cell technique
10.2.3 High-pressure high-temperature techniques
10.3 Temperature effects on fabrication
10.3.1 Impact of temperature on diamond formation
10.3.2 Thermodynamics of carbon conversion
10.3.3 Temperature ranges for successful synthesis of diamane
10.4 Pressure effects on fabrication
10.4.1 Role of pressure in carbon rearrangement
10.4.2 Pressure requirements for diamane synthesis
10.5 Applications of diamane and derivatives
10.5.1 Overview of potential applications
10.5.2 Electronics and optoelectronics
10.5.3 Energy storage and conversion
10.5.4 Biomedical and sensing applications
10.6 Challenges and future directions
10.7 Conclusion
References.