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Table of Contents
Probability, distributions, and equilibrium
The distribution of energy
Energy levels in real chemical systems
Internal energy (U) and the first law
Bonding and internal energy
The effect of temperature on equilibrium
Entropy (S) and the second law
The effect of pressure and concentration on entropy
Enthalpy (H) and the surroundings
Gibbs energy (G)
The equilibrium constant (K)
Applications of Gibbs energy : phase changes
Applications of Gibbs energy : electrochemistry
Appendix A: Symbols and constants
Appendix B: Mathematical tricks
Appendix C: Table of standard reduction potentials
Appendix D: Table of standard thermodynamic data (25[degree symbol]C and 1 bar)
Appendix E: Thermodynamic data for the evaporation of liquid water.
The distribution of energy
Energy levels in real chemical systems
Internal energy (U) and the first law
Bonding and internal energy
The effect of temperature on equilibrium
Entropy (S) and the second law
The effect of pressure and concentration on entropy
Enthalpy (H) and the surroundings
Gibbs energy (G)
The equilibrium constant (K)
Applications of Gibbs energy : phase changes
Applications of Gibbs energy : electrochemistry
Appendix A: Symbols and constants
Appendix B: Mathematical tricks
Appendix C: Table of standard reduction potentials
Appendix D: Table of standard thermodynamic data (25[degree symbol]C and 1 bar)
Appendix E: Thermodynamic data for the evaporation of liquid water.