State-to-state dynamical research in the F+H2 reaction system [electronic resource] / Zefeng Ren.
Ren, Zefeng, author.
2014
QD501
Available Online

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Title State-to-state dynamical research in the F+H2 reaction system [electronic resource] / Zefeng Ren.
Author Ren, Zefeng, author.
ISBN 9783642397561 electronic book
3642397565 electronic book
9783642397554
DOI https://doi.org/10.1007/978-3-642-39756-1
Published Heidelberg : Springer, 2014.
Language English
Description 1 online resource (xii, 77 pages) : illustrations (some color).
Item Number 10.1007/978-3-642-39756-1 doi
Call Number QD501
Dewey Decimal Classification 541/.39
Summary This thesis addresses two important and also challenging issues in the research of chemical reaction dynamics of F+H2 system. One is to probe the reaction resonance and the other is to determine the extent of the breakdown of the Born-Oppenheimer approximation (BOA) experimentally. The author introduces a state-of-the-art crossed molecular beam-scattering apparatus using a hydrogen atom Rydberg "tagging" time-of-flight method, and presents thorough state-to-state experimental studies to address the above issues. The author also describes the observation of the Feshbach resonance in the F+H2 reaction, a precise measurement of the differential cross section in the F+HD reaction, and validation of a new accurate potential energy surface with spectroscopic accuracy. Moreover, the author determines the reactivity ratio between the ground state F(2P3/2) and the excited state F*(2P1/2) in the F+D2 reaction, and exploits the breakdown of BOA in the low collision energy.
Dissertation Note Ph.D. Dalian Institute of Chemical Physics [2013?]
Bibliography, etc. Note Includes bibliographical references.
Access Note Access limited to authorized users.
Source of Description Description based on online resource; title from PDF title page (SpringerLink, viewed November 11, 2013).
Series Springer theses, 2190-5053
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All Resources
Hydrogen Atom Rydberg Tagging Time-of-Flight Crossed Molecular Beam Apparatus
Dynamical Resonances in F+H2 Reactions
The Non-Adiabatic Effects in F(2P)+D2?DF+D.

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