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000696082 020__ $$a9783642397561 $$qelectronic book
000696082 020__ $$a3642397565 $$qelectronic book
000696082 020__ $$z9783642397554
000696082 0247_ $$a10.1007/978-3-642-39756-1$$2doi
000696082 035__ $$aSP(OCoLC)ocn865508052
000696082 035__ $$aSP(OCoLC)865508052
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000696082 049__ $$aISEA
000696082 050_4 $$aQD501
000696082 08204 $$a541/.39$$223
000696082 1001_ $$aRen, Zefeng,$$eauthor.
000696082 24510 $$aState-to-state dynamical research in the F+H2 reaction system$$h[electronic resource]  /$$cZefeng Ren.
000696082 264_1 $$aHeidelberg :$$bSpringer,$$c2014.
000696082 300__ $$a1 online resource (xii, 77 pages) :$$billustrations (some color).
000696082 336__ $$atext$$btxt$$2rdacontent
000696082 337__ $$acomputer$$bc$$2rdamedia
000696082 338__ $$aonline resource$$bcr$$2rdacarrier
000696082 4901_ $$aSpringer theses,$$x2190-5053
000696082 502__ $$bPh.D.$$cDalian Institute of Chemical Physics$$d[2013?]
000696082 504__ $$aIncludes bibliographical references.
000696082 5050_ $$aHydrogen Atom Rydberg Tagging Time-of-Flight Crossed Molecular Beam Apparatus -- Dynamical Resonances in F+H2 Reactions -- The Non-Adiabatic Effects in F(2P)+D2?DF+D.
000696082 506__ $$aAccess limited to authorized users.
000696082 520__ $$aThis thesis addresses two important and also challenging issues in the research of chemical reaction dynamics of F+H2 system. One is to probe the reaction resonance and the other is to determine the extent of the breakdown of the Born-Oppenheimer approximation (BOA) experimentally. The author introduces a state-of-the-art crossed molecular beam-scattering apparatus using a hydrogen atom Rydberg "tagging" time-of-flight method, and presents thorough state-to-state experimental studies to address the above issues. The author also describes the observation of the Feshbach resonance in the F+H2 reaction, a precise measurement of the differential cross section in the F+HD reaction, and validation of a new accurate potential energy surface with spectroscopic accuracy. Moreover, the author determines the reactivity ratio between the ground state F(2P3/2) and the excited state F*(2P1/2) in the F+D2 reaction, and exploits the breakdown of BOA in the low collision energy.
000696082 588__ $$aDescription based on online resource; title from PDF title page (SpringerLink, viewed November 11, 2013).
000696082 650_0 $$aChemical reactions.
000696082 650_0 $$aHydrogen.
000696082 650_0 $$aRydberg states.
000696082 830_0 $$aSpringer theses,$$x2190-5053
000696082 85280 $$bebk$$hSpringerLink
000696082 85640 $$3SpringerLink$$uhttps://univsouthin.idm.oclc.org/login?url=http://dx.doi.org/10.1007/978-3-642-39756-1$$zOnline Access
000696082 909CO $$ooai:library.usi.edu:696082$$pGLOBAL_SET
000696082 980__ $$aEBOOK
000696082 980__ $$aBIB
000696082 982__ $$aEbook
000696082 983__ $$aOnline
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