000697232 000__ 03102cam\a2200445Ki\4500 000697232 001__ 697232 000697232 005__ 20230306135728.0 000697232 006__ m\\\\\o\\d\\\\\\\\ 000697232 007__ cr\cn\nnnunnun 000697232 008__ 140205s2014\\\\ja\a\\\\ob\\\\000\0\eng\d 000697232 020__ $$a9784431546252$$q(electronic book) 000697232 020__ $$a4431546251$$q(electronic book) 000697232 020__ $$z9784431546245 000697232 035__ $$aSP(OCoLC)ocn869894000 000697232 035__ $$aSP(OCoLC)869894000 000697232 040__ $$aN$T$$beng$$erda$$epn$$cN$T$$dYDXCP$$dGW5XE$$dVT2$$dCOO 000697232 049__ $$aISEA 000697232 050_4 $$aQD181.C9 000697232 08204 $$a546.652$$223 000697232 1001_ $$aNishikawa, Michihiro,$$eauthor. 000697232 24510 $$aPhotofunctionalization of molecular switch based on pyrimidine ring rotation in copper complexes$$h[electronic resource] /$$cMichihiro Mishikawa. 000697232 264_1 $$aTokyo :$$bSpringer,$$c[2014]. 000697232 264_4 $$c©2014. 000697232 300__ $$a1 online resource :$$billustrations. 000697232 336__ $$atext$$btxt$$2rdacontent 000697232 337__ $$acomputer$$bc$$2rdamedia 000697232 338__ $$aonline resource$$bcr$$2rdacarrier 000697232 4901_ $$aSpringer theses 000697232 500__ $$a"Doctoral Thesis accepted by The University of Tokyo, Tokyo, Japan." 000697232 504__ $$aIncludes bibliographical references. 000697232 5050_ $$aGeneral introduction -- Details of Molecular Bistability Based on Pyrimidine Ring Rotation in Copper(I) Complexes -- Dual emission caused by ring rotational isomerization of a copper(I) complex -- Repeatable Copper(II)/(I) Redox Potential Switching Driven Visible Light-Induced Coordinated Ring Rotation -- Concluding remarks. 000697232 506__ $$aAccess limited to authorized users. 000697232 520__ $$aThis book provides a detailed description of photofunctionalization of molecular switch based on pyrimidine ring rotational isomerization in copper complexes bearing two bidentate ligands. The most important features of this work focus on the properties associated with the rotational isomerization based on the two possible coordination geometries at the copper center derived from two nitrogen atoms on the unsymmetrically substituted pyrimidine ring. The functions of systems such as dual emission and redox potential switching based on photo-driven rotation will be of particular interest to readers. Both the functions and the procedures for proving these phenomena are beneficial for the development of more functionalized systems based on material science, molecular science, nanoscience, nanotechnology, electrochemistry, photochemistry, coordination chemistry, physical chemistry, and related disciplines. The finding elucidated here holds promise for handling the photoprocesses of metal complexes, valid for both applications and novel properties. This system is expected make it possible to extract an electrochemical potential response from molecular switches, aiming to simulate the five senses of human beings at a single molecular level. 000697232 650_0 $$aCopper compounds. 000697232 650_0 $$aPhotochemistry. 000697232 830_0 $$aSpringer theses. 000697232 85280 $$bebk$$hSpringerLink 000697232 85640 $$3SpringerLink$$uhttps://univsouthin.idm.oclc.org/login?url=http://dx.doi.org/10.1007/978-4-431-54625-2$$zOnline Access 000697232 909CO $$ooai:library.usi.edu:697232$$pGLOBAL_SET 000697232 980__ $$aEBOOK 000697232 980__ $$aBIB 000697232 982__ $$aEbook 000697232 983__ $$aOnline 000697232 994__ $$a92$$bISE