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000723701 0247_ $$a10.1007/978-3-319-10500-0$$2doi
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000723701 1001_ $$aDicks, Andrew P.,$$eauthor.
000723701 24510 $$aGreen chemistry metrics$$h[electronic resource] :$$ba guide to determining and evaluating process greenness /$$cAndrew P. Dicks, Andrei Hent.
000723701 264_1 $$aCham :$$bSpringer,$$c[2014]
000723701 264_4 $$c©2015
000723701 300__ $$a1 online resource (viii, 90 pages) :$$billustrations.
000723701 336__ $$atext$$btxt$$2rdacontent
000723701 337__ $$acomputer$$bc$$2rdamedia
000723701 338__ $$aonline resource$$bcr$$2rdacarrier
000723701 4901_ $$aSpringerBriefs in molecular science, Green chemistry for sustainability,$$x2191-5407
000723701 504__ $$aIncludes bibliographical references.
000723701 5050_ $$aPreface; Contents; 1 Green Chemistry and Associated Metrics; Abstract; 1.1 Green Chemistry; 1.1.1 The Twelve Principles of Green Chemistry; 1.1.2 Synthetic Efficiency and Overall Process Quality; 1.2 Some Award-Winning Green Processes; 1.2.1 The Presidential Green Chemistry Challenge Awards; 1.2.2 BHC Ibuprofen Synthesis: A Perspective on Intrinsic Efficiency; 1.2.3 Merck's Synthesis of Januvia: Highlights and Global Efficiency; 1.2.4 Pfizer's Sertraline Process: A Perspective on Overall Process Quality; 1.3 Green Metrics: Overview and the Path Forward; References
000723701 5058_ $$a2 Atom Economy and Reaction Mass EfficiencyAbstract; 2.1 Atom Economy; 2.1.1 Development and Motivation; 2.1.2 Definition and Key Assumptions; 2.1.3 Reaction Types: The Good, the Bad and the Ugly; 2.1.4 Catalysis, Industry and Innovation; 2.1.4.1 Heterogeneous Catalysis; 2.1.4.2 Homogeneous Catalysis; 2.1.4.3 Biocatalysis; 2.1.5 100 % Atom Economy: Above and Beyond; 2.2 Reaction Mass Efficiency (RME); 2.2.1 History and Development; 2.2.1.1 A Good Start: The Curzons Definition; 2.2.1.2 A Unifying Concept: The Andraos Definition; 2.2.2 Applying RME to Catalysis
000723701 5058_ $$a2.2.2.1 Mass Efficiency in Heterogeneous Catalysis2.2.2.2 A Homogeneous Base-Catalyzed Amidation; 2.2.2.3 Biocatalysis and the Synthesis of 7-ACA; 2.2.3 Future Directions; References; 3 The E Factor and Process Mass Intensity; Abstract; 3.1 The E Factor; 3.1.1 History and Development; 3.1.2 Intrinsic and Global E Factors; 3.1.3 Perspective on Waste in Academia and Industry; 3.1.4 The Solution: Catalysis; 3.1.4.1 The Advantage of Heterogeneous Catalysis; 3.1.4.2 Opportunities in Homogeneous Catalysis; 3.1.4.3 Biocatalysis and the Issue of Solvent Waste
000723701 5058_ $$a3.1.5 Perspectives on Waste in Alternative Reaction Media3.1.6 Beyond the E Factor: Innovative Synthetic Methods; 3.2 Process Mass Intensity (PMI); 3.2.1 History and Motivation; 3.2.2 Process Mass Intensity in Relation to Other Metrics; 3.2.3 Biocatalysis and the Synthesis of Singulair; 3.2.4 Future Trends and the Changing Industrial Landscape; References; 4 Selected Qualitative Green Metrics; Abstract; 4.1 The EcoScale; 4.1.1 The Penalty System: Virtues and Drawbacks; 4.1.2 Application in Education and Academia; 4.1.3 The Modified Ecoscale: An Industrial Metric?
000723701 5058_ $$a4.2 Other Qualitative Metrics4.2.1 Environmental Assessment Tool for Organic Syntheses; 4.2.2 The Andraos Algorithm: Advancing Radial Polygons; 4.2.3 Future Directions: What Does ``Global'' Really Mean?; References; 5 An Introduction to Life Cycle Assessment; Abstract; 5.1 History and the Journey Toward Standardization; 5.2 Life Cycle Assessment (LCA); 5.2.1 The Nuts and Bolts; 5.2.2 The Green Chemistry Connection; 5.2.3 Virtues and Limitations; 5.3 Industrial Application: Revisiting the Synthesis of 7-Aminocephalosporanic Acid
000723701 506__ $$aAccess limited to authorized users.
000723701 520__ $$aThis contribution to SpringerBriefs in Green Chemistry outlines and discusses the four major green chemistry metrics (atom economy, reaction mass efficiency, E factor and process mass intensity), at a level that is comprehensible by upper-level undergraduates. Such students have previously received fundamental training in organic chemistry basics, and are ideally positioned to learn about green chemistry principles, of which metrics is one foundational pillar. Following this, other green metrics in common use are discussed, along with applications that allow important calculations to be easily.
000723701 588__ $$aOnline resource; title from PDF title page (SpringerLink, viewed October 8, 2014).
000723701 650_0 $$aGreen chemistry$$xMeasurement.
000723701 7001_ $$aHent, Andrei,$$eauthor.
000723701 77608 $$iPrint version:$$aDicks, Andrew$$tGreen Chemistry Metrics : A Guide to Determining and Evaluating Process Greenness$$dCham : Springer International Publishing,c2014$$z9783319104997
000723701 830_0 $$aSpringerBriefs in molecular science.$$pGreen chemistry for sustainability,
000723701 852__ $$bebk
000723701 85640 $$3SpringerLink$$uhttps://univsouthin.idm.oclc.org/login?url=http://link.springer.com/10.1007/978-3-319-10500-0$$zOnline Access$$91397441.1
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