@article{725633,
      author = {Herrmann, Sven, and Steb, Carsten,},
      url = {http://library.usi.edu/record/725633},
      title = {New synthetic routes to polyoxometalate containing ionic  liquids an investigation of their properties / [electronic  resource] :},
      abstract = {In his Master project Sven Herrmann for the first time  carried out fundamental investigations into the development  of polyoxometalate based ionic liquids (POM-ILs). The  POM-ILs were obtained by charge balancing inorganic  polyoxometalate (POM) anions with sterically demanding  tetraalkylammonium or tetraalkylphosphonium cations. By  functionalization of lacunary Keggin clusters with  3d-transition metals and charge balancing with  tetraalkylammonium cations of differing chain length, a  model system for the correlation of the molecular structure  with macroscopic materials properties was obtained. In a  systematic approach the syntheses via self-aggregation is  presented. Analytic methods comprise UV-Vis, FTIR, NMR, EPR  and M©œ©ℓbauer spectroscopy. For determination of the  materials properties TGA and DSC were carried out and  rheological studies shed light onto the flow  characteristics of the highly viscous materials.  ℗ℓContents Polyoxometlates and Ionic Liquids in General  POM-Ils as New Class of Compounds Synthesis and  Characterization of POM-ILs Reactivity Towards Azide and  Carbonmonoxide ℗ℓTarget Groups Researchers and students  in the field of chemistry Practitioners in this area  ℗ℓThe Author Sven Herrmann obtained his Masters degree  at the University of Erlangen-N©ơrnberg. He then joined  the working group of Prof. Carsten Streb in the inorganic  department at the University of Ulm to work on his PhD  thesis that targets the development of polyoxometalate  based ionic liquids (POM-ILs).},
      doi = {https://doi.org/10.1007/978-3-658-08796-8},
      recid = {725633},
      pages = {1 online resource :},
}