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000725633 019__ $$a908091525
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000725633 0247_ $$a10.1007/978-3-658-08796-8$$2doi
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000725633 050_4 $$aQD474$$b.H47 2015eb
000725633 08204 $$a541.2242$$223
000725633 1001_ $$aHerrmann, Sven,$$eauthor.
000725633 24510 $$aNew synthetic routes to polyoxometalate containing ionic liquids$$h[electronic resource] :$$ban investigation of their properties /$$cSven Herrmann ; foreword by Prof Dr. Carsten Steb.
000725633 264_1 $$aWiesbaden :$$bSpringer Spektrum,$$c[2015]
000725633 264_4 $$c©2015
000725633 300__ $$a1 online resource :$$billustrations.
000725633 336__ $$atext$$btxt$$2rdacontent
000725633 337__ $$acomputer$$bc$$2rdamedia
000725633 338__ $$aonline resource$$bcr$$2rdacarrier
000725633 4901_ $$aBestMasters
000725633 504__ $$aIncludes bibliographical references.
000725633 5050_ $$aPolyoxometlates and Ionic Liquids in General -- POM-Ils as New Class of Compounds -- Synthesis and Characterization of POM-ILs -- Reactivity Towards Azide and Carbonmonoxide.
000725633 506__ $$aAccess limited to authorized users.
000725633 520__ $$aIn his Master project Sven Herrmann for the first time carried out fundamental investigations into the development of polyoxometalate based ionic liquids (POM-ILs). The POM-ILs were obtained by charge balancing inorganic polyoxometalate (POM) anions with sterically demanding tetraalkylammonium or tetraalkylphosphonium cations. By functionalization of lacunary Keggin clusters with 3d-transition metals and charge balancing with tetraalkylammonium cations of differing chain length, a model system for the correlation of the molecular structure with macroscopic materials properties was obtained. In a systematic approach the syntheses via self-aggregation is presented. Analytic methods comprise UV-Vis, FTIR, NMR, EPR and M©œ©ℓbauer spectroscopy. For determination of the materials properties TGA and DSC were carried out and rheological studies shed light onto the flow characteristics of the highly viscous materials. ℗ℓContents Polyoxometlates and Ionic Liquids in General POM-Ils as New Class of Compounds Synthesis and Characterization of POM-ILs Reactivity Towards Azide and Carbonmonoxide ℗ℓTarget Groups Researchers and students in the field of chemistry Practitioners in this area ℗ℓThe Author Sven Herrmann obtained his Masters degree at the University of Erlangen-N©ơrnberg. He then joined the working group of Prof. Carsten Streb in the inorganic department at the University of Ulm to work on his PhD thesis that targets the development of polyoxometalate based ionic liquids (POM-ILs).
000725633 588__ $$aDescription based on online resource; title from PDF title page (viewed February 18, 2015).
000725633 650_0 $$aPolyoxometalates.
000725633 650_0 $$aIonic solutions.
000725633 7001_ $$aSteb, Carsten,$$eauthor of introduction, etc.
000725633 77608 $$iPrint version:$$z9783658087951
000725633 830_0 $$aBestMasters.
000725633 852__ $$bebk
000725633 85640 $$3SpringerLink$$uhttps://univsouthin.idm.oclc.org/login?url=http://link.springer.com/10.1007/978-3-658-08796-8$$zOnline Access$$91397441.1
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000725633 980__ $$aBIB
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000725633 983__ $$aOnline
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