000734960 000__ 12242cam\a2200493\a\4500 000734960 001__ 734960 000734960 005__ 20210515110831.0 000734960 006__ m\\\\\o\\d\\\\\\\\ 000734960 007__ cr\cn\nnnunnun 000734960 008__ 120411s2010\\\\enkad\\\ob\\\\001\0\eng\d 000734960 010__ $$z 2012397271 000734960 020__ $$z9781847558060$$qhardcover 000734960 020__ $$z1847558062$$qhardcover 000734960 020__ $$a9781849730983$$qelectronic book 000734960 035__ $$a(CaPaEBR)ebr10627698 000734960 035__ $$a(OCoLC)823728351 000734960 040__ $$aCaPaEBR$$cCaPaEBR 000734960 05014 $$aQC145.4.T5$$bA67 2010eb 000734960 24500 $$aApplied thermodynamics of fluids$$h[electronic resource] /$$cedited by A.R.H. Goodwin, J.V. Sengers, C.J. Peters. 000734960 260__ $$aCambridge :$$bRSC Pub.,$$cc2010. 000734960 300__ $$axxiii, 509 p. :$$bill. 000734960 504__ $$aIncludes bibliographical references and index. 000734960 50500 $$gMachine generated contents note:$$gch. 1$$tIntroduction /$$rJ. Peters --$$tReferences --$$gch. 2$$tFundamental Considerations /$$rCor J. Peters --$$g2.1.$$tIntroduction --$$g2.2.$$tBasic Thermodynamics --$$g2.2.1.$$tHomogeneous Functions --$$g2.2.2.$$tThermodynamic Properties from Differentiation of Fundamental Equations --$$g2.3.$$tDeviation Functions --$$g2.3.1.$$tResidual Functions --$$g2.3.2.$$tEvaluation of Residual Functions --$$g2.4.$$tMixing and Departure Functions --$$g2.4.1.$$tDeparture Functions with Temperature, Molar Volume and Composition as the Independent Variables --$$g2.4.2.$$tDeparture Functions with Temperature, Pressure and Composition as the Independent Variables --$$g2.5.$$tMixing and Excess Functions --$$g2.6.$$tPartial Molar Properties --$$g2.7.$$tFugacity and Fugacity Coefficients --$$g2.8.$$tActivity Coefficients --$$g2.9.$$tThe Phase Rule --$$g2.10.$$tEquilibrium Conditions --$$g2.10.1.$$tPhase Equilibria --$$g2.10.2.$$tChemical Equilibria --$$g2.11.$$tStability and the Critical State --$$g2.11.1.$$tDensities and Fields --$$g2.11.2.$$tStability. 000734960 50500 $$g2.11.3.$$tCritical State --$$tReferences --$$gch. 3$$tThe Virial Equation of State /$$rJ. P. Martin Trusler --$$g3.1.$$tIntroduction --$$g3.1.1.$$tTemperature Dependence of the Virial Coefficients --$$g3.1.2.$$tComposition Dependence of the Virial Coefficients --$$g3.1.3.$$tConvergence of the Virial Series --$$g3.1.4.$$tThe Pressure Series --$$g3.2.$$tTheoretical Background --$$g3.2.1.$$tVirial Coefficients of Hard-Core-Square-Well Molecules --$$g3.3.$$tThermodynamic Properties of Gases --$$g3.3.1.$$tPerfect-gas and Residual Properties --$$g3.3.2.$$tHelmholtz Energy and Gibbs Energy --$$g3.3.3.$$tPerfect-Gas Properties --$$g3.3.4.$$tResidual Properties --$$g3.4.$$tEstimation of Second and Third Virial Coefficients --$$g3.4.1.$$tApplication of Intermolecular Potential-energy Functions --$$g3.4.2.$$tCorresponding-states Methods --$$tReferences --$$gch. 4$$tCubic and Generalized van der Waals Equations of State /$$rIoannis G. Economou --$$g4.1.$$tIntroduction --$$g4.2.$$tCubic Equation of State Formulation --$$g4.2.1.$$tThe van der Waals Equation of State (1873) --$$g4.2.2.$$tThe Redlich and Kwong Equation of State (1949). 000734960 50500 $$g4.2.3.$$tThe Soave, Redlich and Kwong Equation of State (1972) --$$g4.2.4.$$tThe Peng and Robinson Equation of State (1976) --$$g4.2.5.$$tThe Patel and Teja (PT) Equation of State (1982) --$$g4.2.6.$$tThe α Parameter --$$g4.2.7.$$tVolume Translation --$$g4.2.8.$$tThe Elliott, Suresh and Donohue (ESD) Equation of State (1990) --$$g4.2.9.$$tHigher-Order Equations of State Rooted to the Cubic Equations of State --$$g4.2.10.$$tExtension of Cubic Equations of State to Mixtures --$$g4.3.$$tApplications --$$g4.3.1.$$tPure Components --$$g4.3.2.$$tOil and Gas Industry -- Hydrocarbons and Petroleum Fractions --$$g4.3.3.$$tChemical Industry -- Polar and Hydrogen Bonding Fluids --$$g4.3.4.$$tPolymers --$$g4.3.5.$$tTransport Properties --$$g4.4.$$tConclusions --$$tReferences --$$gch. 5$$tMixing and Combining Rules /$$rStanley I. Sandler --$$g5.1.$$tIntroduction --$$g5.2.$$tThe Virial Equation of State --$$g5.3.$$tCubic Equations of State --$$g5.3.1.$$tMixing Rules --$$g5.3.2.$$tCombining Rules --$$g5.3.3.$$tNon-Quadratic Mixing and Combining Rules --$$g5.3.4.$$tMixing Rules that Combine an Equation of State with an Activity-Coefficient Model. 000734960 50500 $$g5.4.$$tMulti-Parameter Equations of State --$$g5.4.1.$$tBenedict, Webb, and Rubin Equation of State --$$g5.4.2.$$tGeneralization with the Acentric Factor --$$g5.4.3.$$tHelmholtz-Function Equations of State --$$g5.5.$$tMixing Rules for Hard Spheres and Association --$$g5.5.1.$$tMixing and Combining Rules for SAFT --$$g5.5.2.$$tCubic Plus Association Equation of State --$$tReferences --$$gch. 6$$tThe Corresponding-States Principle /$$rJames F. Ely --$$g6.1.$$tIntroduction --$$g6.2.$$tTheoretical Considerations --$$g6.3.$$tDetermination of Shape Factors --$$g6.3.1.$$tOther Reference Fluids --$$g6.3.2.$$tExact Shape Factors --$$g6.3.3.$$tShape Factors from Generalized Equations of State --$$g6.4.$$tMixtures --$$g6.4.1.$$tvan der Waals One-Fluid Theory --$$g6.4.2.$$tMixture Corresponding-States Relations --$$g6.5.$$tApplications of Corresponding-States Theory --$$g6.5.1.$$tExtended Corresponding-States for Natural Gas Systems --$$g6.5.2.$$tExtended Lee-Kesler --$$g6.5.3.$$tGeneralized Crossover Cubic Equation of State --$$g6.6.$$tConclusions --$$tReferences --$$gch. 7$$tThermodynamics of Fluids at Meso and Nano Scales /$$rChristopher E. Bertrand. 000734960 50500 $$g7.1.$$tIntroduction --$$g7.2.$$tThermodynamic Approach to Meso-Heterogeneous Systems --$$g7.2.1.$$tEquilibrium Fluctuations --$$g7.2.2.$$tLocal Helmholtz Energy --$$g7.3.$$tApplications of Meso-Thermodynamics --$$g7.3.1.$$tVan der Waals Theory of a Smooth Interface --$$g7.3.2.$$tPolymer Chain in a Dilute Solution --$$g7.3.3.$$tBuilding a Nanoparticle Through Self Assembly --$$g7.3.4.$$tModulated Fluid Phases --$$g7.4.$$tMeso-Thermodynamics of Criticality --$$g7.4.1.$$tCritical Fluctuations --$$g7.4.2.$$tScaling Relations --$$g7.4.3.$$tNear-Critical Interface --$$g7.4.4.$$tDivergence of Tolman's Length --$$g7.5.$$tCompetition of Meso-Scales --$$g7.5.1.$$tCrossover to Tricriticality in Polymer Solutions --$$g7.5.2.$$tTolman's Length in Polymer Solutions --$$g7.5.3.$$tFinite-size Scaling --$$g7.6.$$tNon-Equilibrium Meso-Thermodynamics of Fluid Phase Separation --$$g7.6.1.$$tRelaxation of Fluctuations --$$g7.6.2.$$tCritical Slowing Down --$$g7.6.3.$$tHomogeneous Nucleation --$$g7.6.4.$$tSpinodal Decomposition --$$g7.7.$$tConclusion --$$tReferences --$$gch. 8$$tSAFT Associating Fluids and Fluid Mixtures /$$rAmparo Galindo. 000734960 50500 $$g8.1.$$tIntroduction --$$g8.2.$$tStatistical Mechanical Theories of Association and Wertheim's Theory --$$g8.3.$$tSAFT Equations of State --$$g8.3.1.$$tSAFT-HS and SAFT-HR --$$g8.3.2.$$tSoft-SAFT --$$g8.3.3.$$tSAFT-VR --$$g8.3.4.$$tPC-SAFT --$$g8.3.5.$$tSummary --$$g8.4.$$tExtensions of the SAFT Approach --$$g8.4.1.$$tModelling the Critical Region --$$g8.4.2.$$tPolar Fluids --$$g8.4.3.$$tIon-Containing Fluids --$$g8.4.4.$$tModelling Inhomogeneous Fluids --$$g8.4.5.$$tDense Phases: Liquid Crystals and Solids --$$g8.5.$$tParameter Estimation: Towards more Predictive Approaches --$$g8.5.1.$$tPure-component Parameter Estimation --$$g8.5.2.$$tUse of Quantum Mechanics in SAFT Equations of State --$$g8.5.3.$$tUnlike Binary Intermolecular Parameters --$$g8.6.$$tSAFT Group-Contribution Approaches --$$g8.6.1.$$tHomonuclear Group-Contribution Models in SAFT --$$g8.6.2.$$tHeteronuclear Group Contribution Models in SAFT --$$g8.7.$$tConcluding Remarks --$$tReferences --$$gch. 9$$tPolydisperse Fluids /$$rDieter Browarzik --$$g9.1.$$tIntroduction --$$g9.2.$$tInfluence of Polydispersity on the Liquid + Liquid Equilibrium of a Polymer Solution. 000734960 50500 $$g9.3.$$tApproaches to Polydispersity --$$g9.3.1.$$tThe Pseudo-component Method --$$g9.3.2.$$tContinuous Thermodynamics --$$g9.4.$$tApplication to Real Systems --$$g9.4.1.$$tPolymer Systems --$$g9.4.2.$$tPetroleum Fluids, Asphaltenes, Waxes and Other Applications --$$g9.5.$$tConclusions --$$tReferences --$$gch. 10$$tThermodynamic Behaviour of Fluids near Critical Points /$$rMikhail A. Anisimov --$$g10.1.$$tIntroduction --$$g10.2.$$tGeneral Theory of Critical Behaviour --$$g10.2.1.$$tScaling Fields, Critical Exponents, and Critical Amplitudes --$$g10.2.2.$$tParametric Equation of State --$$g10.3.$$tOne-Component Fluids --$$g10.3.1.$$tSimple Scaling --$$g10.3.2.$$tRevised Scaling --$$g10.3.3.$$tComplete Scaling --$$g10.3.4.$$tVapour-Liquid Equilibrium --$$g10.3.5.$$tSymmetric Corrections to Scaling --$$g10.4.$$tBinary Fluid Mixtures --$$g10.4.1.$$tIsomorphic Critical Behaviour of Mixtures --$$g10.4.2.$$tIncompressible Liquid Mixtures --$$g10.4.3.$$tWeakly Compressible Liquid Mixtures --$$g10.4.4.$$tCompressible Fluid Mixtures --$$g10.4.5.$$tDilute Solutions --$$g10.5.$$tCrossover Critical Behaviour --$$g10.5.1.$$tCrossover from Ising-like to Mean-Field Critical Behaviour. 000734960 50500 $$g10.5.2.$$tEffective Critical Exponents --$$g10.5.3.$$tGlobal Crossover Behaviour of Fluids --$$g10.6.$$tDiscussion --$$tAcknowledgements --$$tReferences --$$gch. 11$$tPhase Behaviour of Ionic Liquid Systems /$$rCor J. Peters --$$g11.1.$$tIntroduction --$$g11.2.$$tPhase Behaviour of Binary Ionic Liquid Systems --$$g11.2.1.$$tPhase Behaviour of (Ionic Liquid + Gas Mixtures) --$$g11.2.2.$$tPhase Behaviour of (Ionic Liquid + Water) --$$g11.2.3.$$tPhase Behaviour of (Ionic Liquid + Organic) --$$g11.3.$$tPhase Behaviour of Ternary Ionic Liquid Systems --$$g11.3.1.$$tPhase Behaviour of (Ionic Liquid + Carbon Dioxide + Organic) --$$g11.3.2.$$tPhase Behaviour of (Ionic Liquid + Aliphatic + Aromatic) --$$g11.3.3.$$tPhase Behaviour of (Ionic Liquid + Water + Alcohol) --$$g11.3.4.$$tPhase Behaviour of Ionic Liquid Systems with Azeotropic Organic Mixtures --$$g11.4.$$tModeling of the Phase Behaviour of Ionic Liquid Systems --$$g11.4.1.$$tMolecular Simulations --$$g11.4.2.$$tExcess Gibbs-energy Methods --$$g11.4.3.$$tEquation of State Modeling --$$g11.4.4.$$tQuantum Chemical Methods --$$tReferences --$$gch. 12$$tMulti-parameter Equations of State for Pure Fluids and Mixtures /$$rRoland Span. 000734960 50500 $$g12.1.$$tIntroduction --$$g12.2.$$tThe Development of a Thermodynamic Property Formulation --$$g12.3.$$tFitting an Equation of State to Experimental Data --$$g12.3.1.$$tRecent Nonlinear Fitting Methods --$$g12.4.$$tPressure-Explicit Equations of State --$$g12.4.1.$$tCubic Equations --$$g12.4.2.$$tThe Benedict-Webb-Rubin Equation of State --$$g12.4.3.$$tThe Bender Equation of State --$$g12.4.4.$$tThe Jacobsen-Stewart Equation of State --$$g12.4.5.$$tThermodynamic Properties from Pressure-Explicit Equations of State --$$g12.5.$$tFundamental Equations --$$g12.5.1.$$tThe Equation of Keenan, Keyes, Hill, and Moore --$$g12.5.2.$$tThe Equations of Haar, Gallagher, and Kell --$$g12.5.3.$$tThe Equation of Schmidt and Wagner --$$g12.5.4.$$tReference Equations of Wagner --$$g12.5.5.$$tTechnical Equations of Span and of Lemmon --$$g12.5.6.$$tRecent Equations of State. 000734960 5050_ $$aNote continued-- 000734960 50500 $$g13.6.$$tConcluding Remarks --$$tReferences --$$gch. 14$$tApplied Non-Equilibrium Thermodynamics /$$rDick Bedeaux --$$g14.1.$$tIntroduction --$$g14.1.1.$$tA Systematic Thermodynamic Theory for Transport --$$g14.1.2.$$tOn the Validity of the Assumption of Local Equilibrium --$$g14.1.3.$$tConcluding remarks --$$g14.2.$$tFluxes and Forces from the Second Law of Thermodynamics --$$g14.2.1.$$tContinuous phases --$$g14.2.2.$$tMaxwell-Stefan Equations --$$g14.2.3.$$tDiscontinuous Systems --$$g14.2.4.$$tConcluding Remarks --$$g14.3.$$tChemical Reactions --$$g14.3.1.$$tThermal Diffusion in a Reacting System --$$g14.3.2.$$tMesoscopic Description Along the Reaction Coordinate --$$g14.3.3.$$tHeterogeneous Catalysis --$$g14.3.4.$$tConcluding Remarks --$$g14.4.$$tThe Path of Energy-Efficient Operation --$$g14.4.1.$$tAn Optimisation Procedure --$$g14.4.2.$$tOptimal Heat Exchange --$$g14.4.3.$$tThe Highway Hypothesis for a Chemical Reactor --$$g14.4.4.$$tEnergy-Efficient Production of Hydrogen Gas --$$g14.4.$$tConclusions --$$tReferences. 000734960 506__ $$aAccess limited to authorized users. 000734960 650_0 $$aFluids$$xThermal properties. 000734960 7001_ $$aGoodwin, A. R. H. 000734960 7001_ $$aSengers, J. V. 000734960 7001_ $$aPeters, Cor J. 000734960 7102_ $$aRoyal Society of Chemistry (Great Britain) 000734960 7102_ $$aInternational Union of Pure and Applied Chemistry.$$bPhysical and Biophysical Chemistry Division. 000734960 7102_ $$aInternational Association of Chemical Thermodynamics. 000734960 852__ $$bebk 000734960 85640 $$3ProQuest Ebook Central Academic Complete$$uhttps://univsouthin.idm.oclc.org/login?url=http://site.ebrary.com/lib/usiricelib/Doc?id=10627698$$zOnline Access 000734960 909CO $$ooai:library.usi.edu:734960$$pGLOBAL_SET 000734960 980__ $$aEBOOK 000734960 980__ $$aBIB 000734960 982__ $$aEbook 000734960 983__ $$aOnline