TY  - GEN
AB  - This book presents an in-depth study into the utility of ℓℓ-bond metathesis in Group 2 mediated reactivity. A comprehensive introduction defines the state of the art in both Group 2 mediated catalysis and dehydrocoupling. Structural investigations giving rise to a range of mixed s-block metal hydrides including a remarkable dodecabimetallic decahydride are then described. Subsequent extensive mechanistic work focussing on both silicon-nitrogen and boron-nitrogen dehydrocoupling gives insights into both congeneric effects down Group 2 and ligand effects centring upon magnesium. These studies show the striking effects of these factors, as well as the electronic nature of the hydridic coupling partner.℗ℓ Finally, the unprecedented introduction of single-electron transfer steps into Group 2 catalytic manifolds is described. The use of the stable radical TEMPO to induce single-electron transfer to substituents bound to Group 2 centres coupled with ℓℓ-bond metathesis allows a novel hydrogen release from silanes.
AU  - Liptrot, David J.,
CN  - QD172.T6
DO  - 10.1007/978-3-319-21036-0
DO  - doi
ID  - 751698
KW  - Transition metals.
KW  - Chemistry, Inorganic.
KW  - Metal complexes.
LK  - https://univsouthin.idm.oclc.org/login?url=http://link.springer.com/10.1007/978-3-319-21036-0
N1  - "Doctoral thesis accepted by the University of Bath, UK"--t.p.
N2  - This book presents an in-depth study into the utility of ℓℓ-bond metathesis in Group 2 mediated reactivity. A comprehensive introduction defines the state of the art in both Group 2 mediated catalysis and dehydrocoupling. Structural investigations giving rise to a range of mixed s-block metal hydrides including a remarkable dodecabimetallic decahydride are then described. Subsequent extensive mechanistic work focussing on both silicon-nitrogen and boron-nitrogen dehydrocoupling gives insights into both congeneric effects down Group 2 and ligand effects centring upon magnesium. These studies show the striking effects of these factors, as well as the electronic nature of the hydridic coupling partner.℗ℓ Finally, the unprecedented introduction of single-electron transfer steps into Group 2 catalytic manifolds is described. The use of the stable radical TEMPO to induce single-electron transfer to substituents bound to Group 2 centres coupled with ℓℓ-bond metathesis allows a novel hydrogen release from silanes.
SN  - 9783319210360
SN  - 331921036X
T1  - Group 2 mediated dehydrocoupling
TI  - Group 2 mediated dehydrocoupling
UR  - https://univsouthin.idm.oclc.org/login?url=http://link.springer.com/10.1007/978-3-319-21036-0
ER  -