000751698 000__ 02989cam\a2200505Ii\4500
000751698 001__ 751698
000751698 005__ 20230306141232.0
000751698 006__ m\\\\\o\\d\\\\\\\\
000751698 007__ cr\cn\nnnunnun
000751698 008__ 150730s2016\\\\sz\\\\\\ob\\\\000\0\eng\d
000751698 019__ $$a931578801$$a932322283
000751698 020__ $$a9783319210360$$q(electronic book)
000751698 020__ $$a331921036X$$q(electronic book)
000751698 020__ $$z9783319210353
000751698 0247_ $$a10.1007/978-3-319-21036-0$$2doi
000751698 035__ $$aSP(OCoLC)ocn915134713
000751698 035__ $$aSP(OCoLC)915134713$$z(OCoLC)931578801$$z(OCoLC)932322283
000751698 040__ $$aN$T$$beng$$erda$$epn$$cN$T$$dN$T$$dGW5XE$$dIDEBK$$dYDXCP$$dOCLCF$$dCOO$$dEBLCP$$dDEBSZ$$dSNK$$dCDX
000751698 049__ $$aISEA
000751698 050_4 $$aQD172.T6
000751698 08204 $$a546/.3$$223
000751698 1001_ $$aLiptrot, David J.,$$eauthor.
000751698 24510 $$aGroup 2 mediated dehydrocoupling$$h[electronic resource] /$$cDavid J. Liptrot.
000751698 264_1 $$aCham :$$bSpringer,$$c[2016]
000751698 264_4 $$c©2016
000751698 300__ $$a1 online resource.
000751698 336__ $$atext$$btxt$$2rdacontent
000751698 337__ $$acomputer$$bc$$2rdamedia
000751698 338__ $$aonline resource$$bcr$$2rdacarrier
000751698 4901_ $$aSpringer theses
000751698 500__ $$a"Doctoral thesis accepted by the University of Bath, UK"--t.p.
000751698 504__ $$aIncludes references.
000751698 5050_ $$aIntroduction -- Group 1-Group 2 Bimetallic Alkyls and Hydrides -- Silicon-nitrogen Dehydrocoupling -- Boron-nitrogen Dehydrocoupling -- Single Electron Transfer Steps in Group 2 Catalysis -- Summary -- Future Work.
000751698 506__ $$aAccess limited to authorized users.
000751698 520__ $$aThis book presents an in-depth study into the utility of ℓℓ-bond metathesis in Group 2 mediated reactivity. A comprehensive introduction defines the state of the art in both Group 2 mediated catalysis and dehydrocoupling. Structural investigations giving rise to a range of mixed s-block metal hydrides including a remarkable dodecabimetallic decahydride are then described. Subsequent extensive mechanistic work focussing on both silicon-nitrogen and boron-nitrogen dehydrocoupling gives insights into both congeneric effects down Group 2 and ligand effects centring upon magnesium. These studies show the striking effects of these factors, as well as the electronic nature of the hydridic coupling partner.℗ℓ Finally, the unprecedented introduction of single-electron transfer steps into Group 2 catalytic manifolds is described. The use of the stable radical TEMPO to induce single-electron transfer to substituents bound to Group 2 centres coupled with ℓℓ-bond metathesis allows a novel hydrogen release from silanes.
000751698 588__ $$aOnline resource; title from PDF title page (viewed July 31, 2015)
000751698 650_0 $$aTransition metals.
000751698 650_0 $$aChemistry, Inorganic.
000751698 650_0 $$aMetal complexes.
000751698 77608 $$iPrint version:$$z9783319210353
000751698 830_0 $$aSpringer theses.
000751698 852__ $$bebk
000751698 85640 $$3SpringerLink$$uhttps://univsouthin.idm.oclc.org/login?url=http://link.springer.com/10.1007/978-3-319-21036-0$$zOnline Access$$91397441.1
000751698 909CO $$ooai:library.usi.edu:751698$$pGLOBAL_SET
000751698 980__ $$aEBOOK
000751698 980__ $$aBIB
000751698 982__ $$aEbook
000751698 983__ $$aOnline
000751698 994__ $$a92$$bISE