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Group 2 mediated dehydrocoupling [electronic resource] / David J. Liptrot.

9783319210360 (electronic book)
331921036X (electronic book)
9783319210353

Cham : Springer, [2016]

©2016

English

1 online resource.

10.1007/978-3-319-21036-0 doi

QD172.T6

546/.3

This book presents an in-depth study into the utility of ℓℓ-bond metathesis in Group 2 mediated reactivity. A comprehensive introduction defines the state of the art in both Group 2 mediated catalysis and dehydrocoupling. Structural investigations giving rise to a range of mixed s-block metal hydrides including a remarkable dodecabimetallic decahydride are then described. Subsequent extensive mechanistic work focussing on both silicon-nitrogen and boron-nitrogen dehydrocoupling gives insights into both congeneric effects down Group 2 and ligand effects centring upon magnesium. These studies show the striking effects of these factors, as well as the electronic nature of the hydridic coupling partner.℗ℓ Finally, the unprecedented introduction of single-electron transfer steps into Group 2 catalytic manifolds is described. The use of the stable radical TEMPO to induce single-electron transfer to substituents bound to Group 2 centres coupled with ℓℓ-bond metathesis allows a novel hydrogen release from silanes.

"Doctoral thesis accepted by the University of Bath, UK"--t.p.

Includes references.

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Online resource; title from PDF title page (viewed July 31, 2015)

Springer theses.

Print version: 9783319210353

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