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Preface; Contents; Contributors; Part I: Novel Strategies for Synthesizing Zeolites; Chapter 1: Sustainable Routes for Zeolite Synthesis; 1.1 Introduction; 1.2 Synthesis of Zeolites Using Sustainable Templates; 1.2.1 Synthesis of Zeolites Using Low-Toxicity Templates; 1.2.2 Synthesis of Zeolites Using Low-Cost Templates; 1.2.3 Synthesis of Zeolites Using Recyclable Templates; 1.3 Synthesis of Zeolites Without Using Organic Templates; 1.3.1 MFI Zeolite; 1.3.2 BEA Zeolite; 1.3.3 EMT Zeolite; 1.3.4 MTW Zeolite; 1.3.5 TON Zeolite; 1.3.6 MTT Zeolite; 1.3.7 RTH Zeolite; 1.3.8 FER Zeolite
1.3.9 LEV Zeolite1.3.10 SZR Zeolite; 1.3.11 ZSM-34 Zeolite; 1.3.12 ECR-1 Zeolite; 1.3.13 ZSM-5/ZSM-11; 1.3.14 MEL Zeolite; 1.4 Solvent-Free Synthesis of Zeolites; 1.4.1 Solvent-Free Synthesis of Nanoporous Materials; 1.4.2 Solvent-Free Synthesis of Aluminosilicate Zeolites; 1.4.3 Solvent-Free Synthesis of Aluminophosphate Zeolites; 1.4.4 Summary and Perspective; References; Chapter 2: Ionothermal Synthesis of Molecular Sieves; 2.1 Introduction; 2.2 Reaction Medium in Ionothermal Synthesis; 2.2.1 IL and DES; 2.2.2 Hydrogen Bonding Interactions in Ionothermal Synthesis
2.2.3 Synthesis Opportunities2.2.3.1 Extremely Low Volatility; 2.2.3.2 High Microwave-Adsorption Capacity; 2.2.3.3 Stability; 2.3 Ionothermal Synthesis Technique; 2.3.1 General Steps of Ionothermal Synthesis; 2.3.1.1 Preparation of IL/DES; 2.3.1.2 Mixing and Ageing; 2.3.1.3 Recovery and Reuse of IL/DES; 2.3.2 Examples of Ionothermal Synthesis; 2.3.2.1 [EMIm]Br System [51]; 2.3.2.2 Tetraethylammonium Chloride-Pentaerythritol System [52]; 2.3.3 Reactant Selection; 2.3.3.1 IL/DES and Additive Organic Species; 2.3.3.2 Framework Sources; 2.3.3.3 Water; 2.3.4 Key Parameters of Crystallization
2.3.4.1 Reaction Vessel: Open or Sealed?2.3.4.2 Heating Method; 2.4 Molecular Sieves Ionothermally Synthesized; 2.4.1 Zeolitic Metal Phosphates; 2.4.1.1 New Zeolitic Materials; 2.4.1.2 SAPOs; 2.4.2 Zeolites; 2.4.2.1 Zeolites Synthesized from Sol/Gel-IL Mixtures; 2.4.2.2 Zeolites Synthesized in Basic IL [BMIm]OH0.65Br0.35; 2.4.3 Other Crystalline Microporous Materials; 2.4.4 Mesoporous and Hierarchical Porous Materials; 2.4.4.1 Mesoporous Al2O3; 2.4.4.2 Hierarchical Porous FeAPOs; 2.4.5 Molecular Sieves with Special Morphologies; 2.4.5.1 Morphology-Controlled Single Crystals
2.4.5.2 Zeolite Films and Membranes2.5 Structure-Directing Effect in Ionothermal Synthesis; 2.5.1 IL/DES; 2.5.2 Decomposition Species of ILs; 2.5.3 Additive Organic Species; 2.5.3.1 Co-Structure-Directing Effect; 2.5.3.2 Structure-Directing Effect of Hydrogen Bonded Complex Cations; 2.5.3.3 Other Influences; 2.5.4 Transition Metal Cations; 2.6 Prospect and Conclusion; References; Chapter 3: Interlayer Expansion of the Layered Zeolites; 3.1 Introduction; 3.2 Interlayer-Expanded MWW-Type Zeolite; 3.2.1 Structural Diversity of MWW-Type Zeolite; 3.2.2 ITQ-2; 3.2.3 Al-IEZ-MWW
1.3.9 LEV Zeolite1.3.10 SZR Zeolite; 1.3.11 ZSM-34 Zeolite; 1.3.12 ECR-1 Zeolite; 1.3.13 ZSM-5/ZSM-11; 1.3.14 MEL Zeolite; 1.4 Solvent-Free Synthesis of Zeolites; 1.4.1 Solvent-Free Synthesis of Nanoporous Materials; 1.4.2 Solvent-Free Synthesis of Aluminosilicate Zeolites; 1.4.3 Solvent-Free Synthesis of Aluminophosphate Zeolites; 1.4.4 Summary and Perspective; References; Chapter 2: Ionothermal Synthesis of Molecular Sieves; 2.1 Introduction; 2.2 Reaction Medium in Ionothermal Synthesis; 2.2.1 IL and DES; 2.2.2 Hydrogen Bonding Interactions in Ionothermal Synthesis
2.2.3 Synthesis Opportunities2.2.3.1 Extremely Low Volatility; 2.2.3.2 High Microwave-Adsorption Capacity; 2.2.3.3 Stability; 2.3 Ionothermal Synthesis Technique; 2.3.1 General Steps of Ionothermal Synthesis; 2.3.1.1 Preparation of IL/DES; 2.3.1.2 Mixing and Ageing; 2.3.1.3 Recovery and Reuse of IL/DES; 2.3.2 Examples of Ionothermal Synthesis; 2.3.2.1 [EMIm]Br System [51]; 2.3.2.2 Tetraethylammonium Chloride-Pentaerythritol System [52]; 2.3.3 Reactant Selection; 2.3.3.1 IL/DES and Additive Organic Species; 2.3.3.2 Framework Sources; 2.3.3.3 Water; 2.3.4 Key Parameters of Crystallization
2.3.4.1 Reaction Vessel: Open or Sealed?2.3.4.2 Heating Method; 2.4 Molecular Sieves Ionothermally Synthesized; 2.4.1 Zeolitic Metal Phosphates; 2.4.1.1 New Zeolitic Materials; 2.4.1.2 SAPOs; 2.4.2 Zeolites; 2.4.2.1 Zeolites Synthesized from Sol/Gel-IL Mixtures; 2.4.2.2 Zeolites Synthesized in Basic IL [BMIm]OH0.65Br0.35; 2.4.3 Other Crystalline Microporous Materials; 2.4.4 Mesoporous and Hierarchical Porous Materials; 2.4.4.1 Mesoporous Al2O3; 2.4.4.2 Hierarchical Porous FeAPOs; 2.4.5 Molecular Sieves with Special Morphologies; 2.4.5.1 Morphology-Controlled Single Crystals
2.4.5.2 Zeolite Films and Membranes2.5 Structure-Directing Effect in Ionothermal Synthesis; 2.5.1 IL/DES; 2.5.2 Decomposition Species of ILs; 2.5.3 Additive Organic Species; 2.5.3.1 Co-Structure-Directing Effect; 2.5.3.2 Structure-Directing Effect of Hydrogen Bonded Complex Cations; 2.5.3.3 Other Influences; 2.5.4 Transition Metal Cations; 2.6 Prospect and Conclusion; References; Chapter 3: Interlayer Expansion of the Layered Zeolites; 3.1 Introduction; 3.2 Interlayer-Expanded MWW-Type Zeolite; 3.2.1 Structural Diversity of MWW-Type Zeolite; 3.2.2 ITQ-2; 3.2.3 Al-IEZ-MWW