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000752101 019__ $$a924633344$$a925962876$$a931592530$$a932170713$$a932333421
000752101 020__ $$a9783662475102$$q(electronic book)
000752101 020__ $$a3662475103$$q(electronic book)
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000752101 0247_ $$a10.1007/978-3-662-47510-2$$2doi
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000752101 24500 $$aApplication of ionic liquids on rare earth green separation and utilization$$h[electronic resource] /$$cJi Chen, editor.
000752101 264_1 $$aBerlin :$$bSpringer,$$c[2016]
000752101 264_4 $$c©2016
000752101 300__ $$a1 online resource.
000752101 336__ $$atext$$btxt$$2rdacontent
000752101 337__ $$acomputer$$bc$$2rdamedia
000752101 338__ $$aonline resource$$bcr$$2rdacarrier
000752101 347__ $$atext file$$bPDF$$2rda
000752101 4901_ $$aGreen chemistry and sustainable technology
000752101 504__ $$aIncludes bibliographical references.
000752101 5050_ $$aPreface; Contents; Contributors; Part I: Introduction; Chapter 1: Ionic Liquids in the Context of Rare Earth Separation and Utilization; 1.1 Rare Earths; 1.2 Overview of REs Resources and Associated Issues; 1.2.1 Primary Resource; 1.2.1.1 Bastnasite; 1.2.1.2 Monazite; 1.2.1.3 Ion-Absorbed RE Deposit; 1.2.2 Secondary Resource; 1.2.3 Advanced Nuclear Fuel System; 1.3 Separation History of REs; 1.3.1 Hazardous Issues Associated with Organic Dilute; 1.3.2 Overview of the Defects of Organic Extractant; 1.4 Ionic Liquids in RE Separation; 1.4.1 Introduction of Ionic Liquids; 1.4.2 Why Choose ILs?
000752101 5058_ $$a1.4.3 Uniqueness of ILs for the Separation1.4.3.1 ILs Used as Solvent; 1.4.3.2 ILs Used as Extractant; 1.5 Solid-Liquid Separation Systems; 1.6 IL-Based RE Functional Materials; 1.7 Outlook; References; Part II: Chemistry of Ionic Liquids with Rare Earth; Chapter 2: Using Crystal Structures of Ionic Compounds to Explore Complexation and Extraction of Rare Earth Elements in Ionic ...; 2.1 Introduction; 2.2 Inner-Sphere Interactions Between Metal Ions and Ionic Liquid Extractants: Bis(O,O-ethyl)dithiophosphate
000752101 5058_ $$a2.3 Inner- and Outer-Sphere Interactions in a Fully Ionic Environment: 1,2-di(4-Pyridyl)ethylene2.4 Ionic Interactions Between Charged Complexes of Different Metals: [Tb(NO3)2(OH2)5][Th(NO3)5(OH2)2]; 2.5 Conclusions; References; Part III: Ionic Liquids for the Extraction and Separation of Rare Earth; Chapter 3: Separating Rare-Earth Elements with Ionic Liquids; 3.1 Introduction; 3.2 Preparation of Ionic Liquids for Extraction; 3.2.1 Synthesis Methods; 3.2.2 Purification Methods; 3.3 Properties of Ionic Liquids for Extraction; 3.3.1 Volatility, Thermal Stability, and Flammability
000752101 5058_ $$a3.3.2 Viscosity3.3.3 Solubility and Degradation; 3.4 Recycling Rare-Earth Elements with Ionic Liquid-Based Extractants; 3.4.1 Solvent Extraction Separation of La3+ and Ba2+; 3.4.2 TALSPEAK-Like Extraction of REEs with Task-Specific ILs; 3.4.3 Mechanism Study of TALSPEAK-Like Extraction of REEs; 3.4.4 Extracting REEs from Aqueous Solution with Methylimidazole in Ionic Liquids; 3.5 Conclusions; References; Chapter 4: Ionic Liquid-Based Extraction and the Application to Liquid Membrane Separation of Rare Earth Metals; 4.1 Introduction; 4.2 Extraction System for Rare-Earth Metals Using ILs
000752101 5058_ $$a4.2.1 Extraction Using Industrial Extractants4.2.2 Extraction Using a Novel Extractant; 4.2.3 Application of IL DODGAA System; 4.3 IL-Based Liquid Membrane System; 4.4 Conclusions; References; Chapter 5: Application of Ionic Liquid Extractants on Rare Earth Green Separation; 5.1 General; 5.2 Preparation and Classification of ILs for REEs Separation; 5.2.1 General Terms and Signs for Extraction Procedure; 5.2.1.1 Distribution Ratio (D); 5.2.1.2 Extraction Efficiency (E%); 5.2.1.3 Separation Factor (beta); 5.2.1.4 Stripping Ratio (St); 5.2.2 Preparation of Bif-ILEs
000752101 506__ $$aAccess limited to authorized users.
000752101 520__ $$aThis book comprehensively details the applications of ionic liquids in rare earth green separation and utilization based on the unique interactions of ionic liquids with rare earth ions. It consists of nine chapters demonstrating the synthesis and properties of ionic liquids, coordination chemistry of ionic liquids and rare earth, ionic liquids as diluents, extractants, adsorption resins for rare earth extraction and separation, electrodeposition of rare earth metals in ionic liquids, and preparation of rare earth material with the aid of ionic liquids. It is both interesting and useful to chemists, metallurgists and graduate students working on fundamental research of ionic liquids as well as professionals in the rare earth industry. It provides considerable insights into green chemistry and sustainable processes for rare earth separation in order to meet the environmental challenge of rare earth metallurgy around the globe, especially in China. Ji Chen is a Professor of Chemistry at the Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, China.
000752101 588__ $$aOnline resource; title from PDF title page (viewed October 20, 2015)
000752101 650_0 $$aIonic solutions.
000752101 650_0 $$aRare earths.
000752101 7001_ $$aChen, Ji,$$eeditor.
000752101 77608 $$iPrint version:$$z9783662475096$$z366247509X$$w(OCoLC)909327703
000752101 830_0 $$aGreen chemistry and sustainable technology.
000752101 85280 $$bebk$$hSpringerLink
000752101 85640 $$3SpringerLink$$uhttps://univsouthin.idm.oclc.org/login?url=http://link.springer.com/10.1007/978-3-662-47510-2$$zOnline Access$$91397441.1
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000752101 980__ $$aBIB
000752101 982__ $$aEbook
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