First example of a lyotropic smectic C* analog phase [electronic resource] : design, properties and chirality effects / Johanna Ricarda Bruckner.

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First example of a lyotropic smectic C* analog phase [electronic resource] : design, properties and chirality effects / Johanna Ricarda Bruckner.

9783319272030 (electronic book)
3319272039 (electronic book)
9783319272023
3319272020

Cham : Springer, ©2016.

English

1 online resource.

10.1007/978-3-319-27203-0 doi

QD923

530.4/29
540

In this thesis Johanna Bruckner reports the discovery of the lyotropic counterpart of the thermotropic SmC* phase, which has become famous as the only spontaneously polarized, ferroelectric fluid in nature. By means of polarizing optical microscopy, X-ray diffraction and electro-optic experiments she firmly establishes aspects of the structure of the novel lyotropic liquid crystalline phase and elucidates its fascinating properties, among them a pronounced polar electro-optic effect, analogous to the ferroelectric switching of its thermotropic counterpart. The helical ground state of the mesophase raises the fundamental question of how chiral interactions are "communicated" across layers of more or less disordered and achiral solvent molecules which are located between adjacent bi-layers of the chiral amphiphile molecules. This thesis bridges an important gap between thermotropic and lyotropic liquid crystals and pioneers a new field of liquid crystal research.

"Doctoral thesis accepted by the University of Stuttgart, Stuttgart, Germany."

Includes bibliographical references.

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Description based on print version record.

Springer theses.

Print version: 9783319272023

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