000755382 000__ 03123cam\a2200493Ii\4500 000755382 001__ 755382 000755382 005__ 20230306141846.0 000755382 006__ m\\\\\o\\d\\\\\\\\ 000755382 007__ cr\cn\nnnunnun 000755382 008__ 160517s2016\\\\gw\a\\\\ob\\\\000\0\eng\d 000755382 019__ $$a950056025 000755382 020__ $$a9783662498477$$q(electronic book) 000755382 020__ $$a3662498472$$q(electronic book) 000755382 020__ $$z9783662498453 000755382 020__ $$z3662498456 000755382 035__ $$aSP(OCoLC)ocn949884364 000755382 035__ $$aSP(OCoLC)949884364$$z(OCoLC)950056025 000755382 040__ $$aN$T$$beng$$erda$$epn$$cN$T$$dGW5XE$$dN$T$$dIDEBK$$dEBLCP$$dYDXCP$$dAZU 000755382 049__ $$aISEA 000755382 050_4 $$aQD505 000755382 08204 $$a541/.395$$223 000755382 1001_ $$aWu, Yuen,$$eauthor. 000755382 24510 $$aControlled synthesis of Pt-Ni bimetallic catalysts and study of their catalytic properties$$h[electronic resource] /$$cYuen Wu. 000755382 264_1 $$aBerlin :$$bSpringer,$$c2016. 000755382 300__ $$a1 online resource (xii, 111 pages) :$$billustrations. 000755382 336__ $$atext$$btxt$$2rdacontent 000755382 337__ $$acomputer$$bc$$2rdamedia 000755382 338__ $$aonline resource$$bcr$$2rdacarrier 000755382 4901_ $$aSpringer theses 000755382 500__ $$a"Doctoral thesis accepted by Tsinghua University, Beijing, China." 000755382 504__ $$aIncludes bibliographical references. 000755382 5050_ $$aIntroduction -- Controllable Synthesis of Water-soluble Pt-Ni Alloys and the Study of their Catalytic Properties -- The Study of a Strategy for Desigining a Concave Pt-Ni Alloy through Controlled Chemical Synthesis -- The Discovery of Nano Defect Effects and the Design of Trimetallic Pt-Ni@M Core-shell Catalysts -- The Synthesis Strategy of Au Modified Pt-Ni Trimetal Nanoframe Structure. 000755382 506__ $$aAccess limited to authorized users. 000755382 520__ $$aThis thesis focuses on the controlled synthesis of Pt-Ni bimetallic nanoparticles and the study of their catalytic properties. It discusses in detail the nucleation mechanism and the growth process of bimetallic systems, which is vital for a deeper understanding of the design of bimetallic catalysts. The author presents four pioneering studies: (1) syntheses of water-soluble octahedral, truncated octahedral, and cubic Pt-Ni nanocrystals and the study of their structure-activity relationship in model hydrogenation reactions; (2) a strategy for designing a concave Pt-Ni alloy using controllable chemical etching; (3) defect-dominated shape recovery of nanocrystals, which is a new synthesis strategy for trimetallic catalysts; (4) a sophisticated construction of Au islands on Pt-Ni, which is an ideal trimetallic nanoframe catalyst. This thesis inspires researchers working in materials, catalysis as well as other interdisciplinary areas. . 000755382 588__ $$aOnline resource; title from PDF title page (SpringerLink, viewed May 18, 2016). 000755382 650_0 $$aMetal catalysts$$xSynthesis. 000755382 650_0 $$aPlatinum alloys. 000755382 650_0 $$aNickel alloys. 000755382 77608 $$iPrint version:$$z9783662498453$$z3662498456$$w(OCoLC)944472982 000755382 830_0 $$aSpringer theses. 000755382 852__ $$bebk 000755382 85640 $$3SpringerLink$$uhttps://univsouthin.idm.oclc.org/login?url=http://link.springer.com/10.1007/978-3-662-49847-7$$zOnline Access$$91397441.1 000755382 909CO $$ooai:library.usi.edu:755382$$pGLOBAL_SET 000755382 980__ $$aEBOOK 000755382 980__ $$aBIB 000755382 982__ $$aEbook 000755382 983__ $$aOnline 000755382 994__ $$a92$$bISE