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000755782 019__ $$a951595228
000755782 020__ $$a9789811011399$$q(electronic book)
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000755782 050_4 $$aQD481
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000755782 1001_ $$aYadav, Veejendra K.$$eauthor.
000755782 24510 $$aSteric and stereoelectronic effects in organic chemistry$$h[electronic resource] /$$cVeejendra K. Yadav.
000755782 264_1 $$aSingapore :$$bSpringer,$$c2016.
000755782 300__ $$a1 online resource.
000755782 336__ $$atext$$btxt$$2rdacontent
000755782 337__ $$acomputer$$bc$$2rdamedia
000755782 338__ $$aonline resource$$bcr$$2rdacarrier
000755782 504__ $$aIncludes bibliographical references.
000755782 5050_ $$aSteric and Stereoelectronic Control of Organic Molecular Structures and Organic Reactions -- Reactions at Saturated and Unsaturated Carbons -- Diastereoselectivity in Organic Reactions -- A(1,2) and A(1,3) Strains -- The Conservation of Orbital Symmetry (Woodward-Hoffmann Rules) -- The Overlap Component of the Stereoelectronic Factor vis-à-vis the Conservation of Orbital Symmetry Rules -- Miscellaneous.
000755782 506__ $$aAccess limited to authorized users.
000755782 520__ $$aThe steric and stereoelectronic effects control the rate and stereochemical outcome of reactions. Hence, a decent understanding of the related concepts is essential for successful synthetic planning. The book attempts to address several important issues related to these concepts in a simplified manner, and is intended for graduate students. It lays stress on the important aspects of steric and stereoelectronic effects and their control on the conformational profile and reactivity features. The book covers the geometrical requirements for reactions at saturated and unsaturated carbons in both cyclic and acyclic systems, and the resultant stereochemical features. The aspect of geometrical flexibility is also covered with a few examples involving intramolecular reactions. It deals with the facial selectivity of nucleophilic additions to acyclic and cyclic carbonyl compounds, and explains how the steric and stereoelectronic effects control the same. The work comments on allylic strains and their stereochemical control on different reactions with the related conformational control. It is a must read to understand the control elements, the prominent among these elements are spiro-conjugation, periselectivity, torquoselectivity, a-effect, Hammett's substituent constants, Hammond postulate, and Curtin-Hammett principle.
000755782 588__ $$aOnline resource; title from PDF title page (SpringerLink, viewed June 16, 2016).
000755782 650_0 $$aStereochemistry.
000755782 650_0 $$aChemistry, Organic.
000755782 77608 $$iPrint version:$$aYadav, Veejendra K.$$tSteric and Stereoelectronic Effects in Organic Chemistry$$dSingapore : Springer Singapore,c2016$$z9789811011382
000755782 852__ $$bebk
000755782 85640 $$3SpringerLink$$uhttps://univsouthin.idm.oclc.org/login?url=http://link.springer.com/10.1007/978-981-10-1139-9$$zOnline Access$$91397441.1
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000755782 980__ $$aEBOOK
000755782 980__ $$aBIB
000755782 982__ $$aEbook
000755782 983__ $$aOnline
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