Dynamical decoupling in distance measurements by double electron-electron resonance [electronic resource] / Janne Marie Soetbeer.
2016
QC793.5.L428
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Title
Dynamical decoupling in distance measurements by double electron-electron resonance [electronic resource] / Janne Marie Soetbeer.
ISBN
9783658146702 (electronic book)
3658146702 (electronic book)
9783658146696
3658146702 (electronic book)
9783658146696
Published
Wiesbaden : Springer Spektrum, 2016.
Language
English
Description
1 online resource (xxi, 74 pages) : illustrations.
Call Number
QC793.5.L428
Dewey Decimal Classification
539.7/5
Summary
Janne Marie Soetbeer determines the optimal dynamical decoupling (DD) scheme for efficient reduction of electron spin coherence loss in model systems for spin labelled biomolecules depending on their particular relaxation behavior. Extending the nth order DD scheme to double electron-electron resonance (DEER) experiments require the addition of multiple pump pulses for ≠ 1. Incomplete excitation of pump spin packets introduce signal artefacts which are minimized by pump pulse optimization including linear-chirp and asymmetric hyperbolic secant pulses. Prolonging the dipolar evolution time with decreased signal artefact allows to extent the measurable interspin distances in biomolecules which were otherwise not accessible due to spin echo relaxation. Contents The Spin Hamiltonian Pulsed EPR Experiments Relaxation Processes Dynamical Decoupling Model Systems Target Groups Lecturers and Students of Chemistry, especially of Physical Chemistry The Author Janne Marie Soetbeer completed her Master's Thesis at the Swiss Federal Institute of Technology in Zurich, Switzerland. After a research stay with Prof. Dr. Robert Griffin at the Massachusetts Institute of Technology in Cambridge, USA, she will be returning to Zurich to start her PhD in Prof. Dr. Gunnar Jeschke's group.
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Includes bibliographical references.
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Source of Description
Online resource; title from PDF title page (SpringerLink, viewed June 23, 2016).
Series
BestMasters.
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Dynamical decoupling in distance measurements by double electron-electron resonance.
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Table of Contents
The Spin Hamiltonian
Pulsed EPR Experiments
Relaxation Processes
Dynamical Decoupling
Model Systems.
Pulsed EPR Experiments
Relaxation Processes
Dynamical Decoupling
Model Systems.