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Table of Contents
Series Editor; Aims and Scope; Preface; Contents; A Fluorescent Lifetime: Reminiscing About Gregorio Weber; References; Gregorio Weberś Roots in Argentina; 1 Introduction; 2 Gregorio Weberś Family and Childhood in Buenos Aires; 3 The City: Buenos Aires
and the Countryside
La Cumbre, Córdoba; 4 Medical School Days and the Forging of Lifelong Friendships; 5 Scientific Mentors and Influences During Early Research Days in Buenos Aires; 6 Doctoral Thesis at the University of Buenos Aires; 7 Second Law of Thermodynamics: Irreversible Departure from Argentina
8 Family Reencounters in the Northern Hemisphere9 His Long Visit in 1970: A Brief Incursion into Argentine Neuroscience; 10 Gregorio Weberś Influence: A Personal Experience; 11 Exploring a Possible Return; 12 Subsequent Short Visits to Buenos Aires; References; The Labyrinthine World of Gregorio Weber; 1 Getting to Know Gregorio Weber; 2 Why This Chapter; 3 The Historical Brain Drain from Argentina; 4 Enrique Gaviola; 5 The Gaviola-Weber Connection; 6 Family Matters (``Yoyo)́́; 7 Why Medicine; 8 PhD Thesis and Beyond; 9 Weber Number; 10 The Influence of GW on my Scientific Career
11 Concluding RemarksReferences; Personal Recollections of Gregorio Weber, My Postdoc Advisor, and the Important Consequences for My Own Academic Career; References; Measurements of Fluorescence Decay Time by the Frequency Domain Method; 1 Time and Frequency Domain; 2 The Frequency Domain Method; 3 Pulsed Sources; 4 The Parallel Fluorometer Principle; 5 Photon Histograms; 5.1 Dead Time; 5.2 Duty Cycle; 5.3 Time Resolution; 6 Photon Counting Multifrequency Parallel Fluorometer; 7 Conclusions; References
Ultra-Fast Fluorescence Anisotropy Decay of N-Acetyl-l-Tryptophanamide Reports on the Apparent Microscopic Viscosity of Aqueou...1 Introduction; 2 Experimental Section; 2.1 Materials and Solutions; 2.2 Measurement Setup; 2.3 Data Analysis; 3 Results; 3.1 Searching for the Optimum Fluorescence Lifetime of the Reference Compound; 3.2 Total Fluorescence Decay Analysis of NATA in Aqueous Buffer; 3.3 Fluorescence Anisotropy Decay Analysis of NATA in Aqueous Buffer; 3.4 Fluorescence Anisotropy Decay Analysis of NATA in Aqueous Buffer Containing GuHCl
3.5 Relative Increase of Viscosity at Increasing GuHCl Concentration4 Discussion; 4.1 Is NATA a Single Fluorescence Lifetime Standard?; 4.2 Microscopic and Macroscopic Viscosities; 5 Conclusions; References; Weberś Red-Edge Effect that Changed the Paradigm in Photophysics and Photochemistry; 1 Historical Introduction; 2 Modern Interpretation of Red-Edge Effects and of Related Phenomena; 2.1 Inhomogeneous Broadening and the Principle of Photoselection; 2.2 Connection with Molecular Relaxations; 2.3 Observations with Time Resolution; 2.4 Diversity of Wavelength-Selective Effects
and the Countryside
La Cumbre, Córdoba; 4 Medical School Days and the Forging of Lifelong Friendships; 5 Scientific Mentors and Influences During Early Research Days in Buenos Aires; 6 Doctoral Thesis at the University of Buenos Aires; 7 Second Law of Thermodynamics: Irreversible Departure from Argentina
8 Family Reencounters in the Northern Hemisphere9 His Long Visit in 1970: A Brief Incursion into Argentine Neuroscience; 10 Gregorio Weberś Influence: A Personal Experience; 11 Exploring a Possible Return; 12 Subsequent Short Visits to Buenos Aires; References; The Labyrinthine World of Gregorio Weber; 1 Getting to Know Gregorio Weber; 2 Why This Chapter; 3 The Historical Brain Drain from Argentina; 4 Enrique Gaviola; 5 The Gaviola-Weber Connection; 6 Family Matters (``Yoyo)́́; 7 Why Medicine; 8 PhD Thesis and Beyond; 9 Weber Number; 10 The Influence of GW on my Scientific Career
11 Concluding RemarksReferences; Personal Recollections of Gregorio Weber, My Postdoc Advisor, and the Important Consequences for My Own Academic Career; References; Measurements of Fluorescence Decay Time by the Frequency Domain Method; 1 Time and Frequency Domain; 2 The Frequency Domain Method; 3 Pulsed Sources; 4 The Parallel Fluorometer Principle; 5 Photon Histograms; 5.1 Dead Time; 5.2 Duty Cycle; 5.3 Time Resolution; 6 Photon Counting Multifrequency Parallel Fluorometer; 7 Conclusions; References
Ultra-Fast Fluorescence Anisotropy Decay of N-Acetyl-l-Tryptophanamide Reports on the Apparent Microscopic Viscosity of Aqueou...1 Introduction; 2 Experimental Section; 2.1 Materials and Solutions; 2.2 Measurement Setup; 2.3 Data Analysis; 3 Results; 3.1 Searching for the Optimum Fluorescence Lifetime of the Reference Compound; 3.2 Total Fluorescence Decay Analysis of NATA in Aqueous Buffer; 3.3 Fluorescence Anisotropy Decay Analysis of NATA in Aqueous Buffer; 3.4 Fluorescence Anisotropy Decay Analysis of NATA in Aqueous Buffer Containing GuHCl
3.5 Relative Increase of Viscosity at Increasing GuHCl Concentration4 Discussion; 4.1 Is NATA a Single Fluorescence Lifetime Standard?; 4.2 Microscopic and Macroscopic Viscosities; 5 Conclusions; References; Weberś Red-Edge Effect that Changed the Paradigm in Photophysics and Photochemistry; 1 Historical Introduction; 2 Modern Interpretation of Red-Edge Effects and of Related Phenomena; 2.1 Inhomogeneous Broadening and the Principle of Photoselection; 2.2 Connection with Molecular Relaxations; 2.3 Observations with Time Resolution; 2.4 Diversity of Wavelength-Selective Effects