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Preface; Acknowledgement; About the Book; Contents; About the Authors; Abbreviations; Abstract; 1 Optically Active Polymers: A Systematic Study on Syntheses and Properties; 1 Introduction; 2 Synthesis of Optically Active Polymers; 2.1 Helical Polymer; 2.2 Poly (ethyl l-lysinimide)s; 2.3 Poly (ethyl l-lysinamide)s; 2.4 Optically Active Poly(amide-imide)s; 2.5 Poly(phenylacetylene); 2.6 Optically Active Dendronized Polymers; 2.7 Optically Active Poly(ester-imide)s [33]; 2.8 Optically Active Polyalkylthiophenes [34-37]
2.8.1 5, 5″-Dibromo-3,3″-di[(S)-(+)-2-methylbutyl]-2,2′:5′,2″-terthiophene, (S)-(+)-DBDMBTT2.8.2 3,3″″-Di-N-Hexyl-4′,3‴-di[(S)-(+)-2-methylbutyl]-2,2′:5′,2″:5″,2‴: 5‴,2″″- quinquethiophene, (S)-(+)-DHDMBQT; 2.8.3 Polymerization of (S)-(+)-DHDMBQT; 2.9 Synthesis of Optically Active Azoaromatic and Carbazole Containing Azoaromatic Polymers and Copolymers; 2.9.1 Homopolymer of (R)-3-methacryloyloxy-1-(4′-cyano-4-azobenzene) pyrrolidine [55, 56]; 2.9.2 Optically Active Methacrylic Polymer and Azocarbazole Chromophore as Side-Chain: Poly[(S)-MLECA]
2.9.3 Methacrylic Polymers with 9-Phenylazocarbazole Moieties as Side Chains(S)-3-Hidroxy-N-{4-[(4-cyanophenyl)-(3-carbazolyl)-diazene]-phenyl}- pyrrolidine [(S)-HCAPP-C]; 2-Hydroxy-N-ethyl-N-{4-[(4-cyanophenyl)-(3-carbazolyl)-diazene]}phenyl-amine [HCAPE-C]; 2.9.4 Optically Active Copolymers with Carbazole Side Chain and Azochromophores; Optically Active Side Chain 3-Carbazole Based Copolymers and Azochromophores: Poly[(S)-(+)-MECSI-Co-(S)-(+)-MOSI]s and Poly[(S)-(−)-MECP-Co-(S)-MAP-N]
Optically Active Side Chain 9-Phenylcarbazole Based Copolymers and Azochromophores: poly[(S)-(+)-MCPS-Co-(S)-(+)-MOSI], poly[(S)-(−)-MCPP-Co-(S)-MAP-N] and poly[(S)-(−)-MCPP-Co-(S)-MAP-C]2.10 Synthesis of Optically Active Benzodithiophene Based Poly(aryleneethynylene)s for Solar Cells [71]; 2.10.1 Ethyl 2-amino-5-octylthiophene-3-carboxylate; 2.10.2 Ethyl 5-Octylthiophene-3-Carboxylate; 2.10.3 5-Octylthiophene-3-carboxylic acid; 2.10.4 N,N-Diethyl-5-octylthiophene-3-carboxamide; 2.10.5 2,6-Dioctyl-4,8-dihydrobenzo[1,2-b:4,5-b′]dithiophen-4,8-dione
2.10.6 2, 6-Dioctyl-4, 8-bis (trimethylsilylethynyl)-benzo[1, 2-b:4, 5-b′] dithiophene2.10.7 2, 6-Dioctyl-4,8-diethynyl-benzo[1,2-b:4,5-b′]dithiophene; 2.10.8 Synthesis of Polymer PEBBDT; 2.10.9 Synthesis of Polymer PEBTTZ; 2.10.10 Synthesis and Structural Characterization; 2.11 Synthesis of Optically Active Porphyrin Derivatives Bearing Four Chiral Citronellal Moieties; 2.11.1 Metal Free Meso-5,10,15,20-tetra-(2,6-dimethyl-5-heptenyl)porphyrin; 2.11.2 Meso-5,10,15,20-Tetra-(2,6-dimethyl-5-heptenyl) porphyrinato Zinc Complex
2.8.1 5, 5″-Dibromo-3,3″-di[(S)-(+)-2-methylbutyl]-2,2′:5′,2″-terthiophene, (S)-(+)-DBDMBTT2.8.2 3,3″″-Di-N-Hexyl-4′,3‴-di[(S)-(+)-2-methylbutyl]-2,2′:5′,2″:5″,2‴: 5‴,2″″- quinquethiophene, (S)-(+)-DHDMBQT; 2.8.3 Polymerization of (S)-(+)-DHDMBQT; 2.9 Synthesis of Optically Active Azoaromatic and Carbazole Containing Azoaromatic Polymers and Copolymers; 2.9.1 Homopolymer of (R)-3-methacryloyloxy-1-(4′-cyano-4-azobenzene) pyrrolidine [55, 56]; 2.9.2 Optically Active Methacrylic Polymer and Azocarbazole Chromophore as Side-Chain: Poly[(S)-MLECA]
2.9.3 Methacrylic Polymers with 9-Phenylazocarbazole Moieties as Side Chains(S)-3-Hidroxy-N-{4-[(4-cyanophenyl)-(3-carbazolyl)-diazene]-phenyl}- pyrrolidine [(S)-HCAPP-C]; 2-Hydroxy-N-ethyl-N-{4-[(4-cyanophenyl)-(3-carbazolyl)-diazene]}phenyl-amine [HCAPE-C]; 2.9.4 Optically Active Copolymers with Carbazole Side Chain and Azochromophores; Optically Active Side Chain 3-Carbazole Based Copolymers and Azochromophores: Poly[(S)-(+)-MECSI-Co-(S)-(+)-MOSI]s and Poly[(S)-(−)-MECP-Co-(S)-MAP-N]
Optically Active Side Chain 9-Phenylcarbazole Based Copolymers and Azochromophores: poly[(S)-(+)-MCPS-Co-(S)-(+)-MOSI], poly[(S)-(−)-MCPP-Co-(S)-MAP-N] and poly[(S)-(−)-MCPP-Co-(S)-MAP-C]2.10 Synthesis of Optically Active Benzodithiophene Based Poly(aryleneethynylene)s for Solar Cells [71]; 2.10.1 Ethyl 2-amino-5-octylthiophene-3-carboxylate; 2.10.2 Ethyl 5-Octylthiophene-3-Carboxylate; 2.10.3 5-Octylthiophene-3-carboxylic acid; 2.10.4 N,N-Diethyl-5-octylthiophene-3-carboxamide; 2.10.5 2,6-Dioctyl-4,8-dihydrobenzo[1,2-b:4,5-b′]dithiophen-4,8-dione
2.10.6 2, 6-Dioctyl-4, 8-bis (trimethylsilylethynyl)-benzo[1, 2-b:4, 5-b′] dithiophene2.10.7 2, 6-Dioctyl-4,8-diethynyl-benzo[1,2-b:4,5-b′]dithiophene; 2.10.8 Synthesis of Polymer PEBBDT; 2.10.9 Synthesis of Polymer PEBTTZ; 2.10.10 Synthesis and Structural Characterization; 2.11 Synthesis of Optically Active Porphyrin Derivatives Bearing Four Chiral Citronellal Moieties; 2.11.1 Metal Free Meso-5,10,15,20-tetra-(2,6-dimethyl-5-heptenyl)porphyrin; 2.11.2 Meso-5,10,15,20-Tetra-(2,6-dimethyl-5-heptenyl) porphyrinato Zinc Complex