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Introduction
Theory of experimental techniques
The mechanism of [FeFe]-hydrogenases
How Aldehydes Inhibit H2 Evolution
The Direct Electrochemistry of Fuel-Forming Enzymes on Semiconducting Electrodes: How Light-Harvesting Semiconductors can Alter The Bias of Reversible Electrocatalysts in Favour of H2 Production and CO2 Reduction
Selective Visible-Light-Driven CO2 Reduction on a p-type Dye-Sensitised NiO Photocathode
A Multi-Haem Flavoenzyme as a Solar Conversion Catalyst
Conclusions and Perspectives
Experimental Section
Bibliography.

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