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000778223 019__ $$a964922869$$a970614594$$a974650235
000778223 020__ $$a9783319483504$$q(electronic book)
000778223 020__ $$a3319483501$$q(electronic book)
000778223 020__ $$z9783319483498
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000778223 0247_ $$a10.1007/978-3-319-48350-4$$2doi
000778223 035__ $$aSP(OCoLC)ocn964650658
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000778223 049__ $$aISEA
000778223 050_4 $$aQD716.P45
000778223 08204 $$a541/.395$$223
000778223 1001_ $$aSahoo, Basudev.
000778223 24510 $$aVisible light photocatalyzed redox-neutral organic reactions and synthesis of novel metal-organic frameworks /$$cBasudev Sahoo.
000778223 260__ $$aCham, Switzerland :$$bSpringer,$$c2017.
000778223 300__ $$a1 online resource.
000778223 336__ $$atext$$btxt$$2rdacontent
000778223 337__ $$acomputer$$bc$$2rdamedia
000778223 338__ $$aonline resource$$bcr$$2rdacarrier
000778223 347__ $$atext file$$bPDF$$2rda
000778223 4901_ $$aSpringer theses
000778223 500__ $$a"Doctoral thesis accepted by University of Münster, Germany."
000778223 504__ $$aIncludes bibliographical references.
000778223 5050_ $$aAbstract -- Introduction to Photocatalysis -- Dual Gold and Visible Light Photoredox-Catalyzed Heteroarylations of Non-Activated Alkenes -- Visible Light Photoredox Catalyzed Trifluoromethylation-Ring Expansion via Semipinacol Rearrangement -- Transition Metal Free Visible Light-Mediated Synthesis of Polycyclic Indolizines -- Synthesis and Characterizations of Novel Metal-Organic Frameworks (MOFs) -- Experimental Section.
000778223 506__ $$aAccess limited to authorized users.
000778223 520__ $$aThis unique thesis discusses the development of conceptually novel and synthetically valuable methods that use visible light photocatalysis. Each chapter addresses a different topic in the emerging field of photocatalysis, which has become an indispensable tool for organic synthesis. Photocatalysis employs environmentally harmless and abundant visible light in the presence of a photosensitizer, and as such offers an attractive alternative to harmful UV light in photo-mediated reactions. This book introduces the novel concept of merging gold catalysis with visible light photocatalysis in a dual catalytic fashion, which demonstrates their compatibility with each other for first time and has inspired the development of various reactions. Moreover, a novel trifluoromethylation method, which combines radical addition chemistry with a polar rearrangement to synthesize valuable fluorinated compounds, is presented, since compounds featuring fluorinated functionality are the subject of increasing attention in pharmaceutical, agrochemical and material research. It also develops an external photocatalyst-free photochemical method for the synthesis of valuable indolizine heterocycles, where the product mediates its own formation. Lastly, it describes the synthesis and characterization of two novel highly porous metal-organic frameworks (MOFs). The comprehensive text is rounded out with illustrations and color figures.
000778223 650_0 $$aPhotocatalysis.
000778223 650_0 $$aOrganic photochemistry.
000778223 650_0 $$aOrganometallic chemistry.
000778223 77608 $$iPrint version:$$z3319483498$$z9783319483498$$w(OCoLC)959033654
000778223 830_0 $$aSpringer theses.
000778223 852__ $$bebk
000778223 85640 $$3SpringerLink$$uhttps://univsouthin.idm.oclc.org/login?url=http://link.springer.com/10.1007/978-3-319-48350-4$$zOnline Access$$91397441.1
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000778223 982__ $$aEbook
000778223 983__ $$aOnline
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