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Foreword; Contents; 1 Emission Spectroelectrochemistry: Cell Design and Setup; Abstract; 1 Introduction and Chapter Scope; 2 Conventional Fluorescence Spectroelectrochemistry Cells; 2.1 Fluorescence Spectroelectrochemical Cells; 2.1.1 Optically Transparent Thin-Layer Electrochemical (OTTLE) Cells; 2.1.2 Long Optical Path Electrochemical Cells; 2.1.3 Hydrodynamic Voltammetry; 2.1.4 Variable Thickness Thin-Layer Cells; 2.2 Data Processing; 3 Electrochemistry and Fluorescence Microscopy Coupling; 3.1 Fluorescence Detection; 3.1.1 Epifluorescence; 3.1.2 Confocal Fluorescence Microscopy
3.1.3 Total Internal Reflection Fluorescence Microscopy (TIRFM)3.2 Coupling Setup; 4 Conclusion; Acknowledgement; References; 2 In Situ Spectroelectrochemical Fluorescence Microscopy for Visualizing Interfacial Structure and Dynamics in Self-assembled Monolayers; Abstract; 1 Introduction; 2 Metal-Mediated Fluorescence Quenching; 2.1 Fluorescence and Photonic Density of States; 2.2 Fluorescence Near a Metal Surface; 2.3 Near-Field Decay Mechanisms and Quenching; 2.4 Measuring Fluorescence in the Far Field; 3 In Situ Spectroelectrochemical Fluorescence Microscopy Imaging (iSEFMI) Methodology
3.1 Spectroelectrochemical Cell Designs3.2 Digital Imaging System; 3.3 In Situ Fluorescence Lifetime Imaging (FLIM); 4 Study of Alkylthiol SAMs Using iSEFMI; 4.1 Reductive Desorption; 4.2 Oxidative Desorption of Alkylthiol SAMs; 5 Study of Thiol SAMs Composed of BODIPY-Labeled Aib Peptides; 6 iSEFMI Studies of Fluorescently Labeled DNA SAMs; 7 Conclusions and Outlook; Acknowledgements; Appendix; References; 3 Electrochemically Modulated Luminescence in Nanophotonic Structures; Abstract; 1 Introduction; 2 Background; 2.1 High-Sensitivity Current Measurements
2.2 Coupling Electron Transfer to Luminescence3 Spectroelectrochemistry in Nanophotonic Structures; 3.1 Enzymes in Nanophotonic Structures; 3.2 Immobilized Luminescent Factors; 3.3 Freely Diffusing Molecules; 4 Conclusions and Prospects for the Future; 4.1 Luminescence Versus Direct Current Measurement; 4.2 Stochastic Nature of Single-Electron Transfer Events; 4.3 Additional Opportunities for Nanophotonic Electrochemistry; Acknowledgements; References; 4 Electrochemically Monitored Photoluminescence of Conjugated Polymers; Abstract; 1 Introduction; 2 Optical Properties of Conjugated Polymers
3 Electrochemical Properties of Conjugated Polymers4 In Situ Electrochemical Fluorescence Spectroscopy: A Short Survey on Its Application to the Characterization of Conjugated Polymers; 5 Major Features of In Situ Electrochemical Fluorescence Spectroscopy of Conjugated Polymers; 6 Modeling and Quantification of Fluorescence Electrochemical Quenching; 7 Conclusion; References; 5 Electrofluorochromic Devices with Organic Dyes and Conjugated Polymers; Abstract; 1 Introduction; 1.1 Key Parameters in Electrofluorochromism; 2 Electrofluorochromism by Redox Chemistry of Fluorescent Dyes (Type I)
3.1.3 Total Internal Reflection Fluorescence Microscopy (TIRFM)3.2 Coupling Setup; 4 Conclusion; Acknowledgement; References; 2 In Situ Spectroelectrochemical Fluorescence Microscopy for Visualizing Interfacial Structure and Dynamics in Self-assembled Monolayers; Abstract; 1 Introduction; 2 Metal-Mediated Fluorescence Quenching; 2.1 Fluorescence and Photonic Density of States; 2.2 Fluorescence Near a Metal Surface; 2.3 Near-Field Decay Mechanisms and Quenching; 2.4 Measuring Fluorescence in the Far Field; 3 In Situ Spectroelectrochemical Fluorescence Microscopy Imaging (iSEFMI) Methodology
3.1 Spectroelectrochemical Cell Designs3.2 Digital Imaging System; 3.3 In Situ Fluorescence Lifetime Imaging (FLIM); 4 Study of Alkylthiol SAMs Using iSEFMI; 4.1 Reductive Desorption; 4.2 Oxidative Desorption of Alkylthiol SAMs; 5 Study of Thiol SAMs Composed of BODIPY-Labeled Aib Peptides; 6 iSEFMI Studies of Fluorescently Labeled DNA SAMs; 7 Conclusions and Outlook; Acknowledgements; Appendix; References; 3 Electrochemically Modulated Luminescence in Nanophotonic Structures; Abstract; 1 Introduction; 2 Background; 2.1 High-Sensitivity Current Measurements
2.2 Coupling Electron Transfer to Luminescence3 Spectroelectrochemistry in Nanophotonic Structures; 3.1 Enzymes in Nanophotonic Structures; 3.2 Immobilized Luminescent Factors; 3.3 Freely Diffusing Molecules; 4 Conclusions and Prospects for the Future; 4.1 Luminescence Versus Direct Current Measurement; 4.2 Stochastic Nature of Single-Electron Transfer Events; 4.3 Additional Opportunities for Nanophotonic Electrochemistry; Acknowledgements; References; 4 Electrochemically Monitored Photoluminescence of Conjugated Polymers; Abstract; 1 Introduction; 2 Optical Properties of Conjugated Polymers
3 Electrochemical Properties of Conjugated Polymers4 In Situ Electrochemical Fluorescence Spectroscopy: A Short Survey on Its Application to the Characterization of Conjugated Polymers; 5 Major Features of In Situ Electrochemical Fluorescence Spectroscopy of Conjugated Polymers; 6 Modeling and Quantification of Fluorescence Electrochemical Quenching; 7 Conclusion; References; 5 Electrofluorochromic Devices with Organic Dyes and Conjugated Polymers; Abstract; 1 Introduction; 1.1 Key Parameters in Electrofluorochromism; 2 Electrofluorochromism by Redox Chemistry of Fluorescent Dyes (Type I)