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Acknowledgements; Contents; List of Figures; Introduction; 1 Bloch Surface Waves on A One Dimensional Photonic Crystal; 1.1 Bloch Surface Waves: General Properties; 1.2 Ultrathin Refractive Structures for 2D Optics; 1.3 Resonant Coupling Assisted by Surface Diffractive Structures; References; 2 Coupling of Spontaneous Emitters with Bloch Surface Waves; 2.1 Tunable Coupling of BSWs with the External Environment: Influence of the Multilayer Thickness; 2.2 Directional Extraction of Luminescence Assisted by Surface Relief Gratings; 2.3 Enhanced Fluorescent Signal in Bio-Sensing Experiments.