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000779623 1001_ $$aHadlington, Terrance John,$$eauthor.
000779623 24510 $$aOn the catalytic efficacy of low-oxidation state group 14 complexes /$$cTerrance John Hadlington.
000779623 264_1 $$aCham, Switzerland :$$bSpringer,$$c2017.
000779623 300__ $$a1 online resource.
000779623 336__ $$atext$$btxt$$2rdacontent
000779623 337__ $$acomputer$$bc$$2rdamedia
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000779623 4901_ $$aSpringer theses
000779623 500__ $$a"Doctoral thesis accepted by Monash University, Australia."
000779623 504__ $$aIncludes bibliographical references.
000779623 5050_ $$aSupervisor's Foreword; Preface; Parts of this thesis have been published in the following journal articlesEfficient Reduction of Carbon Dioxide to Methanol Equivalents Catalyzed by Two-Coordinate Amido-Germanium(II) and Tin(II) Hydride Complexes; Hadlington, T. J., Hermann, M., Frenking, G., and Jones, C., accepted to ACS Catalysis.Stabilization of a Two-Coordinate, Acyclic Diaminosilylene (ADASi): Completion of the Series of Isolable Diaminotetrylenes, :E(NR2)2 (E = Group 14 Element); Hadlington, T. J., Abdalla, J. A. B., Tir; Acknowledgements; Contents; Abbreviations
000779623 5058_ $$a1 General Introduction1.1 Low-Oxidation State Main-Group Chemistry; 1.2 Oxidation States and the Inert-Pair Effect; 1.2.1 Bonding in the Heavier Ditetrelenes; 1.2.2 Bonding in the Heavier Ditetrylynes; 1.2.3 Kinetic Stabilisation; 1.2.4 Accessing Low-Oxidation State Main-Group Complexes; 1.2.4.1 Salt-Metathesis with Low-Oxidation State Halide Sources; 1.2.4.2 Reduction of Element Halide Precursors; References; 2 The Development of Extremely Bulky Amide Ligands and Their Application to the Synthesis of Group 14 Element(II) Halide Complexes; 2.1 Introduction
000779623 5058_ $$a2.1.1 The Use of Sterically Demanding Chelating Ligands in Group 14 Element(II) Chemistry2.1.2 The Use of Sterically Demanding Monodentate Ligands in Group 14 Element(II) Chemistry; 2.2 Research Proposal; 2.3 Results and Discussion; 2.3.1 Synthesis of Extremely Bulky Secondary Amines; 2.3.1.1 Extremely Bulky Anilines; 2.3.1.2 Extremely Bulky Aryl-Silyl Amines; 2.3.1.3 Extremely Bulky Bis(aryl) Amines; 2.3.2 Synthesis of Group 14 Element(II) Halide Complexes; 2.3.2.1 Aryl-Silyl Amido Group 14 Element(II) Halide Complexes; 2.3.2.2 Bis(aryl) Amido Group 14 Element(II) Halide Complexes
000779623 5058_ $$a2.4 Conclusion2.5 Experimental; References; 3 Synthesis and Reactivity of Heavier Alkyne Analogues Stabilised by Extremely Bulky Amide Ligands; 3.1 Introduction; 3.1.1 Silicon Analogues of Alkynes; 3.1.1.1 Synthesis and Reactivity of 2-Coordinate Disilynes; 3.1.2 Germanium Analogues of Alkynes; 3.1.2.1 Synthesis of 2-Coordinate Digermynes; 3.1.2.2 Reactivity of 2-Coordiante Digermynes Towards H2 and Lewis-Bases; 3.1.2.3 Reactions of 2-Coordinate Digermynes with Unsaturated Molecules and Olefin Activation/Addition; N-N Unsaturates; Alkynes; Linear Alkenes; Cycloalkenes
000779623 5058_ $$a3.1.3 Tin Analogues of Alkynes3.1.3.1 Synthesis of 2-Coordinate Distannynes; 3.1.3.2 Reactivity of 2-Coordinate Distannynes; 3.1.4 Lead Analogues of Alkynes; 3.1.4.1 Synthesis and Reactivity of a 2-Coordinate Diplumbyne; 3.1.5 Low-Oxidation State Group 14 Element Hydride Complexes; 3.1.5.1 Parent Heavier Methylenes; 3.1.5.2 Di-nuclear Low-Oxidation State Group 14 Element Hydride Complexes; 3.1.5.3 Monomeric Low-Oxidation State Group 14 Element Hydride Complexes; Monomeric Silicon (II) Hydride Complexes; Monomeric Germanium(II) Hydride Complexes; Monomeric Tin(II) Hydride Complexes
000779623 506__ $$aAccess limited to authorized users.
000779623 520__ $$aThis outstanding thesis describes a detailed investigation into the use of low-oxidation-state group 14 complexes in catalysis, developed at the cutting edge of inorganic and organometallic chemistry. It includes the preparation of a number of landmark compounds, some of which challenge our current understanding of metal?metal bonding and low-oxidation-state main group chemistry. Among the many highlights of this thesis, the standout result is the development of the first well-defined, low- oxidation-state main group hydride systems as highly efficient catalysts in the hydroboration of carbonyl substrates, including carbon dioxide, which are as efficient as those observed in more traditional, transition-metal catalyses. These results essentially define a new subdiscipline of chemistry.
000779623 588__ $$aOnline resource; title from PDF title page (SpringerLink, viewed Feb. 22, 2017).
000779623 650_0 $$aGroup 14 elements.
000779623 650_0 $$aCatalysts.
000779623 650_0 $$aCatalysis.
000779623 77608 $$iPrint version:$$z3319518062$$z9783319518060$$w(OCoLC)965344935
000779623 830_0 $$aSpringer theses.
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