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000779878 019__ $$a974485510$$a974557943$$a974692581
000779878 020__ $$a9783319515748$$q(electronic book)
000779878 020__ $$a3319515748$$q(electronic book)
000779878 020__ $$z9783319515731
000779878 020__ $$z331951573X
000779878 035__ $$aSP(OCoLC)ocn974372370
000779878 035__ $$aSP(OCoLC)974372370$$z(OCoLC)974485510$$z(OCoLC)974557943$$z(OCoLC)974692581
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000779878 049__ $$aISEA
000779878 050_4 $$aQD305.F2
000779878 08204 $$a547/.77$$223
000779878 1001_ $$aFerreira, María Luján,$$eauthor.
000779878 24510 $$aEnzymatic synthesis of structured triglycerides :$$bfrom laboratory to industry /$$cMaría Luján Ferreira, Gabriela Marta Tonetto.
000779878 264_1 $$aCham, Switzerland :$$bSpringer,$$c2017.
000779878 300__ $$a1 online resource.
000779878 336__ $$atext$$btxt$$2rdacontent
000779878 337__ $$acomputer$$bc$$2rdamedia
000779878 338__ $$aonline resource$$bcr$$2rdacarrier
000779878 4901_ $$aSpringer briefs in molecular science
000779878 504__ $$aIncludes bibliographical references and index.
000779878 5050_ $$aChapter 1: Introduction: What ́s the importance of structured triglycerides and diglycerides -- Chapter 2: Literature Review: What has been explored about enzymatic synthesis of ST and SD -- Chapter 3: Drawbacks: What problems arise when enzymatic synthesis of ST is performed -- Chapter 4: Potential Solutions: What can be done about the drawbacks in ST enzymatic synthesis -- Chapter 5: Industry perspective: What has to be taken into account when scaling-up from the lab to the industry -- Chapter 6: Examples of successful industrial synthesis or potential industrial scaling of SD and ST -- Chapter 7: Conclusion: What does the future look like.
000779878 506__ $$aAccess limited to authorized users.
000779878 520__ $$aThis brief presents the state of the art on enzymatic synthesis of structured triglycerides and diglycerides, focusing on glycerol as the substrate and covering interesterification of vegetable oils in one and two steps. It critically reviews the available literature on enzymatic and chemo-enzymatic synthesis of di- and triglycerides in one or more steps. The effects of the structure, length and unsaturation of the fatty acids are carefully considered, as well as the inhibitory potential of highly unsaturated complex fatty acid structures. The brief also addresses acyl migration and the use of adsorbents, taking into account the most recent literature and presenting the problem in an industrial context. It discusses experimental and analytical problems concerning, e.g. the lab scale and the scaling up to bench and pilot plants. Several examples are presented, and their successes and failures are assessed. Biocatalysts based on lipases are analyzed with regard to problems of immobilization, stability on storage time and activity after multiple uses. The need for specific Sn-2 lipases is presented and strategies for optimizing Sn-2 esterification are discussed. Lastly, practical aspects are examined, e.g. lipase “leaching” with loss of activity, taking into account the latest findings on continuous and batch reactor configurations and presenting the advantages and disadvantages of each.
000779878 588__ $$aVendor-supplied metadata.
000779878 650_0 $$aTriglycerides.
000779878 650_0 $$aDiglycerides.
000779878 650_0 $$aEnzymes$$xSynthesis.
000779878 7001_ $$aTonetto, Gabriela Marta,$$eauthor.
000779878 77608 $$iPrint version:$$z331951573X$$z9783319515731$$w(OCoLC)964380299
000779878 830_0 $$aSpringerBriefs in molecular science.
000779878 852__ $$bebk
000779878 85640 $$3SpringerLink$$uhttps://univsouthin.idm.oclc.org/login?url=http://link.springer.com/10.1007/978-3-319-51574-8$$zOnline Access$$91397441.1
000779878 909CO $$ooai:library.usi.edu:779878$$pGLOBAL_SET
000779878 980__ $$aEBOOK
000779878 980__ $$aBIB
000779878 982__ $$aEbook
000779878 983__ $$aOnline
000779878 994__ $$a92$$bISE