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Preface; Contents; 1 Recent Advances in Rare Earth Metal Asymmetric Catalysis Toward Practical Synthesis of Therapeutics; Abstract; 1 Introduction; 2 La-based Catalysis: Catalytic Asymmetric Amination; 3 Nd-Based Catalysis: Catalytic Asymmetric Nitroaldol Reaction; 4 Conclusion; References; 2 Metal Catalyzed Synthetic Reactions via Aerobic Oxidation as a Key Step; Abstract; 1 Introduction; 2 Aerobic Cu-Catalyzed Acylation-Wittig Reaction Under Neutral Conditions; 2.1 Acylation-Wittig Reaction Under Neutral Conditions; 2.2 Cu(II)-Catalyzed Acylation-Wittig Reaction [3]
2.3 Cu(II) Catalyzed Dissymmetrization of Dithiomalonates [14]3 Heterogeneous Metal-Catalyzed Aerobic Oxidative Biaryl Coupling; 3.1 Aerobic Oxidative Homo-Coupling of Aryl Amines [26]; 3.2 Aerobic C-H/C-H Cross-Coupling of Aryl Amines [42]; 4 Conclusion; Acknowledgements; References; 3 Heterogeneous Platinum Metal Catalyzed Deuterium Generation and Labeling Methods Using Hydrogen Gas and Deuterium Oxide as Key Reagents; Abstract; 1 Heterogeneous Platinum Metal Catalyzed Post-synthetic Deuterium Labeling Method Using D2O as the Deuterium Source in the Presence of Hydrogen Gas
2 Replacement of Hydrogen Gas by Deuterium Gas via Pd/C-Catalyzed H2-D2 Exchange Reaction Between H2 and D2OReferences; 4 Pd on Spherical Carbon (Pd/SC)-Catalyzed Chemoselective Hydrogenation; Abstract; 1 Introduction; 2 Results and Discussion; 2.1 Catalytic Activity of Pd/SC for Hydrogenation Reactions; 2.2 Reuse of Pd/SC; 3 Conclusions; Acknowledgements; References; 5 Environment-Friendly Iron-Catalyzed Reactions; Abstract; 1 Use of Siloxy and Alkoxy Groups as Leaving Groups; 1.1 Nucleophilic Substitutions of Benzylic Silyl Ethers; 1.1.1 Azidation; 1.1.2 Friedel-Crafts Benzylation
1.2 Site-Selective Nucleophilic Substitution of Secondary/Tertiary Benzylic Methyl or Benzyl Ethers1.3 Deprotection of Methoxyphenylmethyl Type-Protected Alcohols and Carboxylic Acids; 2 Ring-Opening Substitutions; 3 Application of Ring-Opening Reaction and Elimination of Siloxy Group to Form Naphthoquinone Methides; References; 6 Tetranuclear Zinc Cluster-Catalyzed Transesterification; Abstract; 1 Introduction; 2 Tetranuclear Zinc Cluster; 3 Transesterification; 3.1 Introduction; 3.2 Scope and Limitations; 4 Chemoselective Acylation of Alcohols Over Amines; 4.1 Introduction
4.2 Optimization of Reaction Conditions4.3 Scope and Limitations; 5 Activation by N-Heteroaromatics; 5.1 DMAP; 5.2 Bis(imidazole) Ligand (2nd Generation Zn Catalyst); 5.3 Polystyrene Resin-Supported Imidazole Ligand (3rd Generation Zn Catalyst); 6 Mechanistic Studies; 7 Conclusion; Acknowledgements; References and Notes; 7 Vinyl Ruthenium Carbenes: Valuable Intermediates in Catalysis; Abstract; 1 Introduction; 2 Intramolecular Ruthenium Catalyzed Redox, Neutral [1,n]-Hydride Transfer/Cyclization Processes
2.3 Cu(II) Catalyzed Dissymmetrization of Dithiomalonates [14]3 Heterogeneous Metal-Catalyzed Aerobic Oxidative Biaryl Coupling; 3.1 Aerobic Oxidative Homo-Coupling of Aryl Amines [26]; 3.2 Aerobic C-H/C-H Cross-Coupling of Aryl Amines [42]; 4 Conclusion; Acknowledgements; References; 3 Heterogeneous Platinum Metal Catalyzed Deuterium Generation and Labeling Methods Using Hydrogen Gas and Deuterium Oxide as Key Reagents; Abstract; 1 Heterogeneous Platinum Metal Catalyzed Post-synthetic Deuterium Labeling Method Using D2O as the Deuterium Source in the Presence of Hydrogen Gas
2 Replacement of Hydrogen Gas by Deuterium Gas via Pd/C-Catalyzed H2-D2 Exchange Reaction Between H2 and D2OReferences; 4 Pd on Spherical Carbon (Pd/SC)-Catalyzed Chemoselective Hydrogenation; Abstract; 1 Introduction; 2 Results and Discussion; 2.1 Catalytic Activity of Pd/SC for Hydrogenation Reactions; 2.2 Reuse of Pd/SC; 3 Conclusions; Acknowledgements; References; 5 Environment-Friendly Iron-Catalyzed Reactions; Abstract; 1 Use of Siloxy and Alkoxy Groups as Leaving Groups; 1.1 Nucleophilic Substitutions of Benzylic Silyl Ethers; 1.1.1 Azidation; 1.1.2 Friedel-Crafts Benzylation
1.2 Site-Selective Nucleophilic Substitution of Secondary/Tertiary Benzylic Methyl or Benzyl Ethers1.3 Deprotection of Methoxyphenylmethyl Type-Protected Alcohols and Carboxylic Acids; 2 Ring-Opening Substitutions; 3 Application of Ring-Opening Reaction and Elimination of Siloxy Group to Form Naphthoquinone Methides; References; 6 Tetranuclear Zinc Cluster-Catalyzed Transesterification; Abstract; 1 Introduction; 2 Tetranuclear Zinc Cluster; 3 Transesterification; 3.1 Introduction; 3.2 Scope and Limitations; 4 Chemoselective Acylation of Alcohols Over Amines; 4.1 Introduction
4.2 Optimization of Reaction Conditions4.3 Scope and Limitations; 5 Activation by N-Heteroaromatics; 5.1 DMAP; 5.2 Bis(imidazole) Ligand (2nd Generation Zn Catalyst); 5.3 Polystyrene Resin-Supported Imidazole Ligand (3rd Generation Zn Catalyst); 6 Mechanistic Studies; 7 Conclusion; Acknowledgements; References and Notes; 7 Vinyl Ruthenium Carbenes: Valuable Intermediates in Catalysis; Abstract; 1 Introduction; 2 Intramolecular Ruthenium Catalyzed Redox, Neutral [1,n]-Hydride Transfer/Cyclization Processes