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Table of Contents
Preface; Contents; Part I: Network Formation and Modeling; Chapter 1: Role of Distributions in Binders and Curatives and Their Effect on Network Evolution and Structure; Introduction; Distributions-Description and Transformation; Distributions in Coatings Binders; Distributions in Commercial Starting Components; Functionality Distribution in Polyisocyanates; Functionality and Molecular Weight Distributions in Telechelics; Distributions Generated by Side Reactions; Two-Stage Reactive Systems-Preparation of a Precursor in the First Stage and Its Cross-Linking in the Second Stage
Functional CopolymersHyperbranched Polymers; Off-Stoichiometric (Highly Branched) Copolyadducts; Systems with Distributions of Groups of Different Reactivities; Chain-Extended Systems; Multistage Network Formation Processes; Conclusions; Appendix; Definitions of Distributions and Their Transform Using the Formalism of Probability Generating Functions; Probability Generating Functions; Degree of Polymerization and Molecular Weight Distributions; Functionality Distributions; Distribution of Reaction States of Building Units in the Branching Process; References
Chapter 2: Heterogeneity in Crosslinked Polymer Networks: Molecular Dynamics SimulationsIntroduction; Background; Model and Simulation Method; Heterogeneities in Network Polymers; Local-Scale Heterogeneities; Extended Heterogeneities; Swelling and Voids; Summary; References; Chapter 3: Rigidity Percolation Modeling of Modulus Development During Free-Radical Crosslinking Polymerization; Introduction; Network Load-Displacement Relationship; Modeling Method; Results and Discussion; Stress Distribution; Effect of Initiation Rate Constant; Effect of Primary Cyclization Rate Constant; Conclusions
Magnetic Microrheometer Designed for CoatingsCoating Viscosity as a Function of Time and Position; Magnetic Microrheology of a Coating Used in Tissue Making; Experimental Methods; Magnetic Microrheometer Setup; Coating Formulations; Probe Particles; Imaging, Data Collection, and Analysis; Comparison with Traditional Rheology; Results and Discussion; Noncrosslinking PAE (NX PAE) Solutions; Plasticizer Concentration in NX PAE; Effect of Crosslinking Potential; Summary; References; Chapter 6: CryoSEM: Revealing Microstructure Development in Drying Coatings; Introduction
Functional CopolymersHyperbranched Polymers; Off-Stoichiometric (Highly Branched) Copolyadducts; Systems with Distributions of Groups of Different Reactivities; Chain-Extended Systems; Multistage Network Formation Processes; Conclusions; Appendix; Definitions of Distributions and Their Transform Using the Formalism of Probability Generating Functions; Probability Generating Functions; Degree of Polymerization and Molecular Weight Distributions; Functionality Distributions; Distribution of Reaction States of Building Units in the Branching Process; References
Chapter 2: Heterogeneity in Crosslinked Polymer Networks: Molecular Dynamics SimulationsIntroduction; Background; Model and Simulation Method; Heterogeneities in Network Polymers; Local-Scale Heterogeneities; Extended Heterogeneities; Swelling and Voids; Summary; References; Chapter 3: Rigidity Percolation Modeling of Modulus Development During Free-Radical Crosslinking Polymerization; Introduction; Network Load-Displacement Relationship; Modeling Method; Results and Discussion; Stress Distribution; Effect of Initiation Rate Constant; Effect of Primary Cyclization Rate Constant; Conclusions
Magnetic Microrheometer Designed for CoatingsCoating Viscosity as a Function of Time and Position; Magnetic Microrheology of a Coating Used in Tissue Making; Experimental Methods; Magnetic Microrheometer Setup; Coating Formulations; Probe Particles; Imaging, Data Collection, and Analysis; Comparison with Traditional Rheology; Results and Discussion; Noncrosslinking PAE (NX PAE) Solutions; Plasticizer Concentration in NX PAE; Effect of Crosslinking Potential; Summary; References; Chapter 6: CryoSEM: Revealing Microstructure Development in Drying Coatings; Introduction