Organic-inorganic composite polymer electrolyte membranes : preparation, properties, and fuel cell applications / Inamuddin, Ali Mohammad, Abdullah M. Asiri, editors.
Inamuddin, 1980- editor.; Mohammad, Ali (Professor of applied chemistry), editor.; Ai, Abdullah M., editor.
2017
TP159.M4
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Title Organic-inorganic composite polymer electrolyte membranes : preparation, properties, and fuel cell applications / Inamuddin, Ali Mohammad, Abdullah M. Asiri, editors.
ISBN 9783319527390 (electronic book)
3319527398 (electronic book)
9783319527383
331952738X
DOI https://doi.org/10.1007/978-3-319-52739-0
Published Cham, Switzerland : Springer, 2017.
Language English
Description 1 online resource (xx, 460 pages) : illustrations.
Item Number 10.1007/978-3-319-52739-0 doi
Call Number TP159.M4
Dewey Decimal Classification 660/.2842
540
Summary This volume explores the latest developments in the area of polymer electrolyte membranes (PEMs) used for high-temperature fuel cells. Featuring contributions from an international array of researchers, it presents a unified viewpoint on the operating principles of fuel cells, various methodologies used for the fabrication of PEMs, and issues related to the chemical and mechanical stabilities of the membranes. Special attention is given to the fabrication of electrospun nanocomposite membranes. The editors have consciously placed an emphasis on developments in the area of fast-growing and promising PEM materials obtained via hygroscopic inorganic fillers, solid proton conductors, heterocyclic solvents, ionic liquids, anhydrous H3PO4 blends, and heteropolyacids. This book is intended for fuel cell researchers and students who are interested in a deeper understanding of the organic-inorganic membranes used in fuel cells, membrane fabrication methodologies, properties and clean energy applications.
Note Includes index.
Access Note Access limited to authorized users.
Digital File Characteristics text file PDF
Source of Description Online resource; title from PDF title page (SpringerLink, viewed May 23, 2017).
Added Author Inamuddin, 1980- editor.
Mohammad, Ali (Professor of applied chemistry), editor.
Ai, Abdullah M., editor.
Available in Other Form Organic-inorganic composite polymer electrolyte membranes.
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Preface; Acknowledgements; Contents; Editors and Contributors; 1 Organic-Inorganic Membranes Impregnated with Ionic Liquid; Abstract; 1 Introduction; 2 Ionic Liquids: General Properties and Applications; 3 Ionic Liquids as Electrolytes in Fuel Cells; 4 Ionic Liquid Polymer Membranes for Fuel Cells; 4.1 Ionic Liquid/Polymer Membranes; 4.2 Polymerized Ionic Liquid Membranes; 4.3 IL Gel and Composite Polymer Membranes; 5 Conclusions; Acknowledgements; References; 2 Organic/TiO2 Nanocomposite Membranes: Recent Developments; Abstract; 1 Introduction; 2 TiO2-Polymer Electrolyte Membranes (PEMs).

2.1 Perfluorinated Organic-Inorganic Nanocomposite Polymer Electrolyte Membranes (PEMs)2.2 Acid-Base Polymer Complex-Based Organic-Inorganic Nanocomposite PEMs; 2.3 TiO2-Modified Polytetrafluoroethylene Membranes; 2.4 Poly(ether ether ketone)-Based Nanocomposite PEMs; 2.5 PANI Based Membranes; 2.6 PES Based Membranes; 2.7 Polysulfone-Based Membranes; 2.8 TiO2 Solar Cells; 2.9 Carbon Materials and Metal-Carbon Nanotube (CNTs)-TiO2 Composites; 2.9.1 Carbon-TiO2 Composites; 2.9.2 Graphene (GN)-TiO2 Composites; 3 Conclusions; Acknowledgements; References; 3 Organic/Silica Nanocomposite Membranes.

Abstract1 Introduction; 2 Silica Nanoparticle-Based Membranes; 3 Conclusion; References; 4 Organic/Zeolites Nanocomposite Membranes; Abstract; 1 Introduction; 2 Basic Concepts About Zeolites; 3 Polymer-Zeolite Composite Membranes: The Role of the Zeolite; 3.1 Influence of Si/Al Ratio; 3.2 Proton Mobility in Zeolites; 3.3 Internal and External Surface Area; 3.4 Configurational Diffusion; 3.5 Crystallite Size [17, 18]; 3.6 Functionalization of Zeolite Surface; 3.7 Selectivity, Proton Conductivity, and Permeability; 4 Techniques for Producing Organic/Zeolite Nanocomposite Membranes.

5 Synthetic Polymers/Zeolite Nanocomposite Membranes for PEMFCs5.1 Route 1: Zeolite + Organic Monomers; 5.2 Route 3: Inorganic Precursor + Organic Polymer; 5.3 Route 4: Zeolite + Organic Polymer; 6 Natural Polymers/Zeolite Nanocomposite Membranes for PEMFCs; 7 Conclusions; Acknowledgements; References; 5 Composite Membranes Based on Heteropolyacids and Their Applications in Fuel Cells; Abstract; 1 Introduction; 2 Heteropolyacids Types and Structures; 3 HPAs and Proton Transport in Fuel Cells; 4 HPAs in PEM Fuel Cell; 5 HPAs in High-Temperature and Low-Humidity PEMFC; 6 HPAs in DMFC.

7 Concluding Remarks and Future PerspectivesAcknowledgements; References; 6 Organic/Montmorillonite Nanocomposite Membranes; Abstract; 1 Introduction; 2 Membrane Fabrication Methods; 2.1 Phase Inversion; 2.2 Immersion Precipitation; 2.3 Evaporation-Induced Phase Separation; 3 Montmorillonite-Based Nanocomposites Membranes; 4 Conclusion; References; 7 Electrospun Nanocomposite Materials for Polymer Electrolyte Membrane Methanol Fuel Cells; Abstract; 1 Introduction; 2 Methanol Crossover and Low Proton Conductivity; 3 Composite SPEEK; 4 SPEEK-Clay Nanocomposite as PEM for DMFC.

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