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000827170 020__ $$a9783319758107$$q(electronic book)
000827170 020__ $$a3319758101$$q(electronic book)
000827170 020__ $$z9783319758091
000827170 0247_ $$a10.1007/978-3-319-75810-7$$2doi
000827170 035__ $$aSP(OCoLC)on1029759062
000827170 035__ $$aSP(OCoLC)1029759062
000827170 040__ $$aGW5XE$$beng$$erda$$epn$$cGW5XE$$dN$T$$dEBLCP$$dUPM$$dOCLCF$$dMERER
000827170 049__ $$aISEA
000827170 050_4 $$aQD506.A1
000827170 08204 $$a541/.33$$223
000827170 1112_ $$aInternational Workshop On-Surface Synthesis$$d(2016 :$$cSan Sebastián, Spain)
000827170 24510 $$aOn-surface synthesis II :$$bproceedings of the International Workshop On-Surface Synthesis, San Sebastián, 27-30 June 2016 /$$cDimas G. de Oteyza, Celia Rogero, editors.
000827170 2463_ $$aOn-surface synthesis 2
000827170 264_1 $$aCham, Switzerland :$$bSpringer,$$c2018.
000827170 300__ $$a1 online resource (viii, 227 pages)
000827170 336__ $$atext$$btxt$$2rdacontent
000827170 337__ $$acomputer$$bc$$2rdamedia
000827170 338__ $$aonline resource$$bcr$$2rdacarrier
000827170 4901_ $$aAdvances in atom and single molecule machines,$$x2193-9691
000827170 5050_ $$aIntro; Preface; Contents; 1 Mechanistic Insights into Surface-Supported Chemical Reactions; Abstract; 1 Introduction; 2 Imaging and Counting Intermediates; 3 Why Are Intermediates Stabilized?; 4 Bringing It All Together; 5 Outlook; Acknowledgements; References; 2 Kinetic and Thermodynamic Considerations in On-Surface Synthesis; Abstract; 1 Introduction; 2 Dehydrogenation Reactions; 3 Entropy of Desorbed Hydrogen Molecules; 4 Electrocyclic Ring-Closure Reaction; 5 C-H Activation and Coupling of Porphyrins; 6 Reaction Intermediates Stabilized by Surface Dissipation and Translational Entropy
000827170 5058_ $$a7 Summary and OutlookReferences; 3 Reactivity on and of Graphene Layers: Scanning Probe Microscopy Reveals; Abstract; 1 Introduction; 2 Chemical Reactivity; 2.1 Synthesis of Imines; 2.2 Other Reactions; 3 Photochemical Reactivity; 4 Electrochemical Reactivity; 5 Tip-Induced Reactivity; 6 Graphene Manipulation and Grafting; 7 Summary and Conclusions; Acknowledgements; References; 4 Dehydrogenative and Dehalogenative Homocoupling Reactions of C-X Groups on Metal Surfaces; Abstract; 1 Introduction; 2 Results and Discussions; 2.1 On-Surface Dehalogenative Homocoupling
000827170 5058_ $$a2.2 On-Surface Dehydrogenative Homocoupling2.3 Sequential C-X Groups Activation; 3 Summary and Outlook; References; 5 On-Surface Ullmann Reaction for the Synthesis of Polymers and Macrocycles; Abstract; 1 Introduction; 2 Synthesis of Polymers via Surface Ullmann Reaction; 2.1 The Emergence of the On-Surface Ullmann Reaction; 2.2 Identification of Organometallic Intermediates on Surfaces; 2.3 Stabilization of Organometallic Chains; 2.4 Dynamics of the Formation of Organometallic Chains; 2.5 Formation of Covalent Polymers; 3 Synthesis of Macrocycles via Surface Ullmann Reaction
000827170 5058_ $$a3.1 Cyclisation via Ring-Closure on a Surface3.2 Formation of Organometallic Macrocycles; 3.3 Formation of Covalent Macrocycles; 4 Summary; References; 6 Bottom-Up Fabrication of Atomically Precise Graphene Nanoribbons; Abstract; 1 Introduction; 2 Synthesis; 3 Characterization Tools and Associated Insight; 3.1 Electronic Properties Determination; 3.2 Chemical Structure; 3.3 Detection of Vibrational Modes; 4 Tuning the Electronic Properties; 4.1 Tuning Through Edge Orientation; 4.2 Tuning Through Width Control; 4.3 Tuning Through Doping; 4.4 Tuning Through Strain
000827170 5058_ $$a4.5 Tuning Through Heterostructure Formation5 Applications; Acknowledgements; References; 7 Aryl-Aryl Covalent Coupling on Rutile TiO2 Surfaces; Abstract; 1 Introduction; 2 TiO2 Properties; 2.1 General; 2.2 Comparison Between Rutile Faces; 2.3 Crystal Reduction and Surface Defects; 3 Aryl Halide Coupling on the Rutile (011) Surface; 3.1 First Successful C-C Coupling on a Rutile Surface; 3.2 Insight into Aryl Halide Coupling on the Rutile (011) Surface (Adapted from Ref. [18] with Permission from the Royal Chemical Society); 4 Aryl Halide Coupling on the Rutile (110) Surface
000827170 506__ $$aAccess limited to authorized users.
000827170 520__ $$aOn-surface synthesis is appearing as an extremely promising strategy to create organic nanoarchitectures with atomic precision. Molecular building blocks holding adequate functional groups are dosed onto surfaces that support or even drive their covalent linkage. The surface confinement and the frequent lack of solvents (most commonly being performed under vacuum conditions) create a completely new scenario fully complementary to conventional chemistry.  In a pedagogical way and based on the most recent developments, this volume presents our current understanding in the field, addressing fundamental reaction mechanisms, synthetic strategies to influence the reactions according to our needs, as well as the ultimate growth and characterization of functional materials. Verging on chemistry, physics and materials science, the book is aimed at students and researchers interested in nanochemistry, surface science, supramolecular materials and molecular devices. Chapters "Mechanistic insights into surface-supported chemical reactions", "Reactivity on and of Graphene Layers: Scanning Probe Microscopy Reviels" and "Bottom-up fabrication of atomically precise graphene nanoribbons" of this book are available open access under a CC BY 4.0 license at link.springer.com.
000827170 588__ $$aOnline resource; title from PDF title page (SpringerLink, viewed March 29, 2018).
000827170 650_0 $$aSurface chemistry$$vCongresses.
000827170 650_0 $$aSelf-assembly (Chemistry)$$vCongresses.
000827170 650_0 $$aNanochemistry$$vCongresses.
000827170 650_0 $$aNanostructured materials$$vCongresses.
000827170 7001_ $$aOteyza, Dimas G. de,$$eeditor.
000827170 7001_ $$aRogero, Celia,$$eeditor.
000827170 830_0 $$aAdvances in atom and single molecule machines.
000827170 852__ $$bebk
000827170 85640 $$3SpringerLink$$uhttps://univsouthin.idm.oclc.org/login?url=http://link.springer.com/10.1007/978-3-319-75810-7$$zOnline Access$$91397441.1
000827170 909CO $$ooai:library.usi.edu:827170$$pGLOBAL_SET
000827170 980__ $$aEBOOK
000827170 980__ $$aBIB
000827170 982__ $$aEbook
000827170 983__ $$aOnline
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