Insights into the chemistry of organic structure-directing agents in the synthesis of zeolitic materials / Luis Gómez-Hortigüela, editor ; with contributions by B. Bernardo-Maestro [and more].
Gómez-Hortigüela, Luis, editor.
2018
TP245.S5
Available Online

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Title Insights into the chemistry of organic structure-directing agents in the synthesis of zeolitic materials / Luis Gómez-Hortigüela, editor ; with contributions by B. Bernardo-Maestro [and more].
ISBN 9783319742892 (electronic book)
3319742892 (electronic book)
9783319742885
DOI https://doi.org/10.1007/978-3-319-74289-2
Published Cham, Switzerland : Springer, 2018.
Language English
Description 1 online resource (vii, 250 pages).
Item Number 10.1007/978-3-319-74289-2 doi
Call Number TP245.S5
Dewey Decimal Classification 549/.68
Summary This edited volume focuses on the host-guest chemistry of organic molecules and inorganic systems during synthesis (structure-direction). Organic molecules have been used for many years in the synthesis of zeolitic nanoporous frameworks. The addition of these organic molecules to the zeolite synthesis mixtures provokes a particular ordering of the inorganic units around them that directs the crystallization pathway towards a particular framework type; hence they are called structure-directing agents. Their use has allowed the discovery of an extremely large number of new zeolite frameworks and compositions. This volume covers the main aspects of the use of organic molecules as structure-directing agents for the synthesis of zeolites, including first an introduction of the main concepts, then two chapters covering state-of-the-art techniques currently used to understand the structure-directing phenomenon (location of molecules by XRD and molecular modeling techniques). The most recent trends in the types of organic molecules used as structure-directing agents are also presented, including the use of metal-complexes, the use of non-ammonium-based molecules (mainly phosphorus-based compounds) and the role of supramolecular chemistry in designing new large organic structure-directing agents produced by self-aggregation. In addition the volume explores the latest research attempting to transfer the asymmetric nature of organic chiral molecules used as structure-directing agents to the zeolite lattice to produce chiral enantioselective frameworks, one of the biggest challenges today in materials chemistry. This volume has interdisciplinary appeal and will engage scholars from the zeolite community with a general interest in microporous materials, which involves not only zeolite scientists, but also researchers working on metal-organic framework materials. The concepts covered will also be of interest for researchers working on the application of materials after encapsulation of molecules of interest in post-synthetic treatments. Further the work explores the main aspects of host-guest chemistry in hybrid organo-inorganic templated materials, which covers all types of materials where organic molecules are used as templates and are confined within framework-structured inorganic materials (intercalation compounds). Therefore the volume is also relevant to the wider materials chemistry community.
Note Includes index.
Access Note Access limited to authorized users.
Source of Description Online resource; title from PDF title page (SpringerLink, viewed April 4, 2018).
Added Author Gómez-Hortigüela, Luis, editor.
Series Structure and bonding ; 175.
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Record Appears in Online Resources > Ebooks
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Introduction of structure-directing phenomenon by organic molecules: general aspects
Location of organic structure-directing agents by diffraction techniques
Molecular modelling of organic structure-direction phenomena
Beyond nitrogen organic structure-directing agents
Role of supramolecular chemistry during templating phenomenon in zeolite synthesis
Metal Complexes as structure directing agents for zeolites and related microporous materials
Chiral organic structure-directing agents.

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