000838744 000__ 05609cam\a2200529Ii\4500 000838744 001__ 838744 000838744 005__ 20230306144651.0 000838744 006__ m\\\\\o\\d\\\\\\\\ 000838744 007__ cr\un\nnnunnun 000838744 008__ 180424t20182018sz\\\\\\ob\\\\001\0\eng\d 000838744 019__ $$a1034549784$$a1038405937 000838744 020__ $$a9783319896120$$q(electronic book) 000838744 020__ $$a3319896121$$q(electronic book) 000838744 020__ $$z9783319896106 000838744 0247_ $$a10.1007/978-3-319-89612-0$$2doi 000838744 035__ $$aSP(OCoLC)on1032070703 000838744 035__ $$aSP(OCoLC)1032070703$$z(OCoLC)1034549784$$z(OCoLC)1038405937 000838744 040__ $$aN$T$$beng$$erda$$epn$$cN$T$$dGW5XE$$dN$T$$dEBLCP$$dAZU$$dUPM$$dUAB$$dOCLCF$$dOCLCQ 000838744 049__ $$aISEA 000838744 050_4 $$aQD569 000838744 08204 $$a541/.395$$223 000838744 1001_ $$aAlonso-Vante, Nicolas,$$eauthor. 000838744 24510 $$aChalcogenide materials for energy conversion :$$bpathways to oxygen and hydrogen reactions /$$cNicolas Alonso-Vante. 000838744 264_1 $$aCham, Switzerland :$$bSpringer,$$c2018. 000838744 300__ $$a1 online resource. 000838744 336__ $$atext$$btxt$$2rdacontent 000838744 337__ $$acomputer$$bc$$2rdamedia 000838744 338__ $$aonline resource$$bcr$$2rdacarrier 000838744 347__ $$atext file$$bPDF$$2rda 000838744 4901_ $$aNanostructure science and technology 000838744 504__ $$aIncludes bibliographical references and index. 000838744 5050_ $$aIntro; Preface; Contents; About the Author; 1 Introduction; 1.1 Basic Concepts of Electrochemical Kinetics; 1.1.1 The Interfacial Charge Transfers Kinetic Model; 1.1.2 At Equilibrium; 1.1.3 Far from Equilibrium; 1.1.3.1 Far from Equilibrium and Charge Transfer; 1.1.3.2 Far from Equilibrium and Mass Overpotential; 1.2 Chalcogens and Metal Chalcogenides; 1.2.1 The Bond Ionicity or Covalency; 1.2.2 The 2D, 3D Compounds; 1.3 Chalcogenide Cluster Compounds (Chevrel Phase); 1.3.1 Structural Description; 1.3.2 Electronic Properties; 1.3.3 The Cluster-Chevrel Phase as Electron Reservoir 000838744 5058_ $$a1.4 Soft Chemistry Synthesis of Chalcogen-Like Materials1.4.1 The Carbonyl Chemical Route; 1.4.1.1 Ruthenium-Based Alloy Materials; 1.4.1.2 Ruthenium-Based Chalcogenide Materials; 1.4.2 Toward Chalcogenide Cluster Surface Coordination; 1.5 Other Chalcogenide Systems; 1.5.1 Amorphous-Glassy Chalcogenides; 1.5.2 Amorphous-Gel Chalcogenide: Chalcogels; References; 2 Fuel Cell Electrocatalysis; 2.1 Generalities; 2.2 Thermodynamics and Kinetics; 2.2.1 Hydrogen Evolution/Oxidation Reaction (HER/HOR); 2.2.2 Oxygen Reduction Reaction/Evolution Reaction (ORR/OER); 2.3 H2/O2 Fuel Cell Electrochemistry 000838744 5058_ $$a2.3.1 Fuel Cell Efficiency2.3.2 Fuel Cell Parameters; 2.3.3 Electrode Reactions; 2.4 H2/O2 Anode and Cathode Electrochemistry; 2.4.1 Turn Over Frequency; 2.4.2 Electrochemical Evaluation of HOR-HER Electrodes; 2.4.3 Electrochemical Evaluation of ORR Electrodes; References; 3 Environmental Catalysis; 3.1 Introduction; 3.2 The Basics of Semiconductor Photoelectrochemistry; 3.2.1 Semiconductor Properties; 3.2.2 Semiconductor/Electrolyte Junction; 3.2.2.1 The Fluctuating Energy Model at the Semiconductor/Electrolyte Junction; 3.2.3 Photoelectrolysis of Water 000838744 5058_ $$a3.3 Environmental Remediation Principle3.4 Energy-Driving Water Splitting Systems; 3.4.1 Photocatalysis on Some Selected Oxides; 3.4.2 Photocatalysis on Some Selected Transition Metal Chalcogenides; 3.4.2.1 Photocatalytic Hydrogen Evolution; 3.4.2.2 Photocatalysis and Charge Storage and Transfer via Chalcogenides in Colloidal Solution; References; 4 Precious Versus Non-precious Electrocatalyst Centers; 4.1 Introduction; 4.2 Precious Metal Center Chalcogenides; 4.2.1 Materials for HER/HOR; 4.2.2 Materials for ORR/OER; 4.2.2.1 Ruthenium-Based Chalcogenide Materials 000838744 5058_ $$a4.2.2.2 Platinum-, Rhodium-, Iridium-, Palladium-Chalcogenide-Based Materials4.3 Non-precious Metal Center Chalcogenides; 4.3.1 Materials for HER/HOR; 4.3.1.1 Hydrogen Evolution Reaction (HER); 4.3.1.2 Hydrogen Oxidation Reaction (HOR); 4.3.2 Materials for ORR/OER; 4.3.2.1 Oxygen Reduction Reaction (ORR); 4.3.2.2 Oxygen Evolution Reaction (OER); 4.3.2.3 Bifunctional Chalcogenides (ORR/OER); References; 5 Effect of Supports on Catalytic Centers; 5.1 Introduction; 5.2 The Effects Encountered Between the Catalytic Center and the Oxide Support; 5.3 Carbon-Supports 000838744 506__ $$aAccess limited to authorized users. 000838744 520__ $$aThis book addresses electrocatalysis based on chalcogenides, particularly in the nanoscale domain. Special attention is paid to the hydrogen evolution reaction (HER) and the oxygen reduction reaction (ORR). The book provides an introduction to materials synthesis; the basic principles of electrocatalysis; related precious metal versus non-precious metal catalytic center chalcogenides as well as supports; and the role of such supports in stabilizing the catalytic centers. In short: pursuing a bottom-up approach, it covers the properties of this class of electrocatalysts and examines their applications in low-temperature fuel systems such as microfluidic fuel cells for portable devices. Accordingly, it is ideally suited for all professionals and researchers interested in electrochemistry, renewable energy and electrocatalysis, and non-precious metal centers for chemical energy conversion. 000838744 588__ $$aOnline resource; title from PDF title page (SpringerLink, viewed April 25, 2018). 000838744 650_0 $$aElectrocatalysis. 000838744 650_0 $$aChalcogenides. 000838744 77608 $$iPrint version: $$z9783319896106 000838744 830_0 $$aNanostructure science and technology. 000838744 852__ $$bebk 000838744 85640 $$3SpringerLink$$uhttps://univsouthin.idm.oclc.org/login?url=http://link.springer.com/10.1007/978-3-319-89612-0$$zOnline Access$$91397441.1 000838744 909CO $$ooai:library.usi.edu:838744$$pGLOBAL_SET 000838744 980__ $$aEBOOK 000838744 980__ $$aBIB 000838744 982__ $$aEbook 000838744 983__ $$aOnline 000838744 994__ $$a92$$bISE