000840809 000__ 05749cam\a2200673\a\4500 000840809 001__ 840809 000840809 005__ 20210515151716.0 000840809 006__ m\\\\\o\\d\\\\\\\\ 000840809 007__ cr\cn\nnnunnun 000840809 008__ 120913s2012\\\\nyua\\\foab\\\001\0\eng\d 000840809 020__ $$a9781606503522$$q(electronic book) 000840809 020__ $$a1606503529$$q(electronic book) 000840809 020__ $$z9781606503508 (print) 000840809 020__ $$z1606503502 (print) 000840809 0247_ $$a10.5643/9781606503522$$2doi 000840809 035__ $$a(OCoLC)809804677 000840809 035__ $$a(CaBNvSL)swl00401257 000840809 035__ $$a(MiAaPQ)EBC954643 000840809 035__ $$a(Au-PeEL)EBL954643 000840809 035__ $$a(CaPaEBR)ebr10588196 000840809 035__ $$a(CaONFJC)MIL420849 000840809 035__ $$a(OCoLC)830170650 000840809 040__ $$aMiAaPQ$$cMiAaPQ$$dMiAaPQ 000840809 050_4 $$aQD96.N8$$bA668 2012 000840809 08204 $$a543.0877$$223 000840809 1001_ $$aApperley, David C. 000840809 24510 $$aSolid-state NMR$$h[electronic resource] :$$bbasic principles & practice /$$cDavid C. Apperley, Robin K. Harris & Paul Hodgkinson. 000840809 260__ $$a[New York, N.Y.] (222 East 46th Street, New York, NY 10017) :$$bMomentum Press,$$c2012. 000840809 300__ $$a1 electronic text (xiv, 276 p.) :$$bill., digital file. 000840809 504__ $$aIncludes bibliographical references and index. 000840809 5050_ $$aPreface -- About the authors -- 000840809 5058_ $$a1. Introduction -- 1.1 The utility of NMR -- 1.2 A preview of solid-state NMR spectra -- 1.3 The solid state -- 1.4 Polymorphism, solvates, co-crystals & host:guest systems -- 1.5 NMR of solids & the periodic table -- 000840809 5058_ $$a2. Basic NMR concepts for solids -- 2.1 Nuclear spin magnetization -- 2.2 Tensors -- 2.3 Shielding -- 2.4 Indirect coupling -- 2.5 Dipolar coupling -- 2.6 Quadrupolar coupling -- 2.7 Magic-angle spinning -- 2.8 Relaxation -- 000840809 5058_ $$a3. Spin-1/2 nuclei: a practical guide -- 3.1 Introduction -- 3.2 The vector model & the rotating frame of reference -- 3.3 The components of an NMR experiment -- 3.4 Cross polarization -- 3.5 High-resolution spectra from 1H (& 19F) -- 000840809 5058_ $$a4. Quantum mechanics of solid-state NMR -- 4.1 Introduction -- 4.2 The Hamiltonians of NMR -- 4.3 The density matrix -- 4.4 Density operator treatments of simple NMR experiments -- 4.5 The density matrix for coupled spins -- 4.6 Euler angles & spherical tensors -- 4.7 Additional analytical tools -- 000840809 5058_ $$a5. Going further with spin-1/2 solid-state NMR -- 5.1 Introduction -- 5.2 Linewidths in solid-state NMR -- 5.3 Exploiting indirect (J) couplings in solids -- 5.4 Spectral correlation experiments -- 5.5 Homonuclear decoupling -- 5.6 Using correlation experiments for spectral assignment -- 5.7 Further applications -- 000840809 5058_ $$a6. Quadrupolar nuclei -- 6.1 Introduction -- 6.2 Characteristics of first-order quadrupolar spectra -- 6.3 First-order energy levels & spectra -- 6.4 Second-order zero-asymmetry cases -- 6.5 Spectra for cases with non-zero asymmetry: central transition -- 6.6 Recording one-dimensional spectra of quadrupolar nuclei -- 6.7 Manipulating the quadrupolar effect -- 6.8 Spectra for integral spins -- 000840809 5058_ $$a7. Relaxation, exchange & quantitation -- 7.1 Introduction -- 7.2 Relaxation -- 7.3 Exchange -- 7.4 Quantitative NMR -- 7.5 Paramagnetic systems -- 000840809 5058_ $$a8. Analysis & interpretation -- 8.1 Introduction -- 8.2 Quantitative measurement of anisotropies -- 8.3 Measurement of dipolar couplings -- 8.4 Quantifying indirect (J) couplings -- 8.5 Tensor interplay -- 8.6 Effects of quadrupolar nuclei on spin-1/2 spectra -- 8.7 Quantifying relationships between tensors -- 8.8 NMR crystallography -- 000840809 5058_ $$aAppendices -- A. The spin properties of spin-1/2 nuclides -- B. The spin properties of quadrupolar nuclides -- C. Liouville space, relaxation & exchange -- C.1 Introduction to Liouville space -- C.2 Application to relaxation -- C.3 Application to chemical exchange -- D. Introduction to solid-state NMR simulation -- D.1 Specifying the spin system -- D.2 Specifying the powder sampling -- D.3 Specifying the pulse sequence -- D.4 Efficiency of calculation -- Index. 000840809 506__ $$aAccess limited to authorized users. 000840809 5203_ $$aNuclear magnetic resonance (NMR) has proved to be a uniquely powerful and versatile spectroscopy, and no modern university chemistry department or industrial chemistry laboratory is complete without a suite of NMR spectrometers. The phenomenon of nuclear spin may seem an odd basis for an analytical tool, but it is the relative isolation of the nuclear spin from its surroundings that makes it an ideal noninterfering probe of the electronic environment. Different sites are clearly identified by their chemical shifts, while J couplings in 1H spectra provide connectivity information. The combination of these two complementary interactions, plus the formidable array of different NMR experiments developed since the arrival of Fourier transform NMR in 1966, has revolutionized the practice of chemistry. 000840809 530__ $$aAlso available in print. 000840809 538__ $$aMode of access: World Wide Web. 000840809 538__ $$aSystem requirements: Adobe Acrobat reader. 000840809 588__ $$aTitle from PDF t.p. (viewed on September 13, 2012). 000840809 650_0 $$aNuclear magnetic resonance spectroscopy. 000840809 653__ $$aSolid-state NMR 000840809 653__ $$aMagic-angle spinning 000840809 653__ $$aSolid-state structure 000840809 653__ $$aNMR crystallography 000840809 653__ $$aCross polarization 000840809 653__ $$aQuadrupolar nuclei 000840809 7001_ $$aHarris, Robin K.$$q(Robin Kingsley) 000840809 7001_ $$aHodgkinson, Paul. 000840809 77608 $$iPrint version:$$z1606503502$$z9781606503508 000840809 852__ $$bebk 000840809 85640 $$3ProQuest Ebook Central Academic Complete$$uhttps://univsouthin.idm.oclc.org/login?url=https://ebookcentral.proquest.com/lib/usiricelib-ebooks/detail.action?docID=954643$$zOnline Access 000840809 909CO $$ooai:library.usi.edu:840809$$pGLOBAL_SET 000840809 980__ $$aEBOOK 000840809 980__ $$aBIB 000840809 982__ $$aEbook 000840809 983__ $$aOnline