000857347 000__ 04775cam\a2200517Ii\4500 000857347 001__ 857347 000857347 005__ 20230306145158.0 000857347 006__ m\\\\\o\\d\\\\\\\\ 000857347 007__ cr\cn\nnnunnun 000857347 008__ 151110t20152016gw\\\\\\ob\\\\001\0\eng\d 000857347 019__ $$a930041268$$a936857542 000857347 020__ $$a9783662468319$$q(electronic book) 000857347 020__ $$a366246831X$$q(electronic book) 000857347 020__ $$z9783662468302 000857347 020__ $$z3662468301 000857347 035__ $$aSP(OCoLC)ocn928626000 000857347 035__ $$aSP(OCoLC)928626000$$z(OCoLC)930041268$$z(OCoLC)936857542 000857347 040__ $$aN$T$$beng$$erda$$epn$$cN$T$$dIDEBK$$dCDX$$dN$T$$dYDXCP$$dOCLCF$$dGW5XE$$dEBLCP$$dIDB$$dJG0$$dOCLCQ$$dESU$$dKSU$$dOCLCQ 000857347 049__ $$aISEA 000857347 050_4 $$aQD181.C1 000857347 08204 $$a546/.6812$$223 000857347 1001_ $$aAresta, Michele,$$d1940-$$eauthor. 000857347 24510 $$aReaction mechanisms in carbon dioxide conversion /$$cMichele Aresta, Angela Dibenedetto, Eugenio Quaranta. 000857347 264_1 $$aHeidelberg :$$bSpringer,$$c[2015] 000857347 264_4 $$c©2016 000857347 300__ $$a1 online resource 000857347 336__ $$atext$$btxt$$2rdacontent 000857347 337__ $$acomputer$$bc$$2rdamedia 000857347 338__ $$aonline resource$$bcr$$2rdacarrier 000857347 504__ $$aIncludes bibliographical references and index. 000857347 5050_ $$aPreface; Contents; About the Authors; Chapter 1: The Carbon Dioxide Molecule; 1.1 Introduction; 1.2 Electronic Properties of CO2; 1.2.1 Ground State of Carbon Dioxide; 1.2.2 Lowest Excited States of Carbon Dioxide; 1.3 Main Features of Carbon Dioxide Reactivity; 1.3.1 Carbon Dioxide as O-Nucleophile; 1.3.2 Carbon Dioxide as C-Electrophile; 1.3.3 Amphoteric Reactivity of Carbon Dioxide; 1.4 Carbon Dioxide Radical Anion, CO2-; 1.5 Carbon Dioxide Radical Cation, CO2+; 1.6 Spectroscopic Techniques Applied to the CO2 States; 1.6.1 IR Spectroscopy; 1.6.2 UV Spectrum of Carbon Dioxide. 000857347 5058_ $$a1.6.3 Nuclear Magnetic Resonance (NMR) SpectroscopyReferences; Chapter 2: CO2 Coordination to Metal Centres: Modes of Bonding and Reactivity; 2.1 Mode of Bonding of Carbon Dioxide to Transition-Metal Centres; 2.2 XRD Structure of eta2-C, O Mononuclear Metal Complexes; 2.3 XRD Structural Data for eta1-C Metal Complexes; 2.4 XRD Structural Characterization of O-End-On Complexes; 2.5 Multinuclear Complexes; 2.5.1 Side-On Bonded Complexes; 2.5.2 O-End-On Bonded Complexes; 2.6 Spectroscopic (IR and 13C-NMR) Data for the Complexes Correlated to the Various Modes of Bonding of CO2. 000857347 5058_ $$a2.6.1 Infrared Data Relevant to Transition Metal Complexes2.6.2 NMR Data for Transition Metal Complexes; 2.7 Fluxionality of the CO2 Molecule Coordinated to Transition Metal Systems; 2.8 Interaction of CO2 with Metal Atoms in Low-Temperature Solid-Inert-Gas Matrices; 2.9 Interaction of Metal Cations with CO2 in the Gas Phase; 2.10 Reactions of Coordinated CO2; 2.10.1 Reaction of Coordinated CO2 with Electrophiles and O-Transfer from CO2 to Produce CO; 2.10.2 Reactions of Coordinated CO2 with Nucleophiles; 2.11 Conclusions; References; Chapter 3: Interaction of CO2 with Electron-Rich Moieties. 000857347 5058_ $$a3.1 Reaction with the Hydride Ion3.2 Reaction with Hydroxide and Alkoxide Species; 3.3 Reaction with Carbanions; 3.4 Reaction with Amines; References; Chapter 4: Insertion of CO2 into E-X Bonds; 4.1 Carbon Dioxide Insertion into M-H Bonds; 4.2 CO2 Insertion into M-OH Bonds; 4.3 CO2 Insertion into M-C Bonds; 4.4 CO2 Insertion into M-OR Bonds; 4.5 Insertion into M-O2 Bonds; 4.6 CO2 Insertion into M-N Bonds; 4.6.1 Insertion into Transition Metal Amides; 4.6.2 Insertion into Main Group and Post-Transition Metal Amides; 4.6.3 Insertion into Amides of Non-Metallic Elements. 000857347 5058_ $$a4.7 CO2 Insertion into M-P Bonds4.8 CO2 Insertion into C-C Bonds; 4.9 CO2 Insertion into C-N Bonds; 4.10 Insertion into Other E-X Bonds; 4.10.1 Insertion into M-M Bonds; 4.10.2 Insertion into Si-H Bonds; 4.10.3 Insertion into C-H Bonds; 4.11 Conclusions; References; Chapter 5: Interaction of CO2 with C-C Multiple Bonds; 5.1 Introduction; 5.2 Oxidative Coupling with CO2; 5.3 Carboxylation of Olefins; 5.4 Carboxylation of Alkynes; 5.5 Carboxylation of Allenes; 5.6 Carboxylation of Conjugated Dienes; References. 000857347 506__ $$aAccess limited to authorized users. 000857347 588__ $$aOnline resource; title from PDF title page (viewed on November 24, 2015). 000857347 650_0 $$aCarbon dioxide. 000857347 650_0 $$aReaction mechanisms (Chemistry) 000857347 7001_ $$aDibenedetto, Angela,$$eauthor. 000857347 7001_ $$aQuaranta, Eugenio,$$eauthor. 000857347 77608 $$iPrint version:$$aAresta, Michele, 1940-$$tReaction mechanisms in carbon dioxide conversion.$$dHeidelberg : Springer, [2015]$$z3662468301$$z9783662468302$$w(OCoLC)904812160 000857347 852__ $$bebk 000857347 85640 $$3SpringerLink$$uhttps://univsouthin.idm.oclc.org/login?url=http://link.springer.com/10.1007/978-3-662-46831-9$$zOnline Access$$91397441.1 000857347 909CO $$ooai:library.usi.edu:857347$$pGLOBAL_SET 000857347 980__ $$aEBOOK 000857347 980__ $$aBIB 000857347 982__ $$aEbook 000857347 983__ $$aOnline 000857347 994__ $$a92$$bISE